hexan-1-amine
hexylamine
CAS: 111-26-2
Molecular Formula: C6H15N
hexan-1-amine - Names and Identifiers
| Name | hexylamine |
| Synonyms | AMINE C6 Hexylamin hexylamine n-C6H13NH2 Hexyl amine aminohexane 1-HEXYLAMINE N-HEXYLAMINE 1-AMINOHEXANE hexan-1-amine hexan-1-aminium H**n-hexylamine 1-Amine-n-hexane NORMAL HEXYL AMINE hexylamine,[liquid] RARECHEM AL BW 0240 Hexan-1-amine, гексиламин, гексан-1-амин, 1-аминогексан, n-hexylamine, 1-Aminohexane гексиламин, гексан-1-амин, 1-аминогексан, hexan-1-amine, n-hexylamine, 1-Aminohexane |
| CAS | 111-26-2 |
| EINECS | 203-851-8 |
| InChI | InChI=1/C6H15N/c1-2-3-4-5-6-7/h2-7H2,1H3/p+1 |
| InChIKey | BMVXCPBXGZKUPN-UHFFFAOYSA-N |
hexan-1-amine - Physico-chemical Properties
| Molecular Formula | C6H15N |
| Molar Mass | 101.19 |
| Density | 0.766g/mLat 25°C(lit.) |
| Melting Point | −23°C(lit.) |
| Boling Point | 131-132°C(lit.) |
| Flash Point | 27 °C |
| JECFA Number | 1588 |
| Water Solubility | 14 g/L (20 ºC) |
| Solubility | 14g/l |
| Vapor Presure | 10.6 hPa (20 °C) |
| Appearance | Liquid |
| Color | Clear colorless to slightly yellow |
| BRN | 1731298 |
| pKa | 10.56(at 25℃) |
| PH | 11.6 (10g/l, H2O, 20℃) |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Incompatible with acids, acid anhydrides, acid chlorides, carbon dioxide, strong oxidizing agents. |
| Sensitive | Air Sensitive |
| Explosive Limit | 2.1-9.3%(V) |
| Refractive Index | n20/D 1.418(lit.) |
| Physical and Chemical Properties | Melting Point: -22.9 ℃ Boiling Point: 131.4 density: 0.77 solubility: slightly soluble in water, miscible in ethanol, ether appearance and properties: colorless liquid |
| Use | Mainly used in organic synthesis |
hexan-1-amine - Risk and Safety
| Risk Codes | R10 - Flammable R21/22 - Harmful in contact with skin and if swallowed. R35 - Causes severe burns R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S16 - Keep away from sources of ignition. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | UN 2734 8/PG 1 |
| WGK Germany | 1 |
| RTECS | MQ4540000 |
| FLUKA BRAND F CODES | 34 |
| TSCA | Yes |
| HS Code | 29159020 |
| Hazard Note | Irritant/Flammable/Corrosive/Air Sensitive |
| Hazard Class | 8 |
| Packing Group | II |
| Toxicity | LD50 orally in Rabbit: 240 mg/kg |
hexan-1-amine - Reference Information
| FEMA | 4243 | HEXYLAMINE |
| LogP | 2.06-2.31 at 25℃ |
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| uses | mainly used in organic synthesis this product is mainly used as dyes, pigments, surfactants and intermediates in pharmaceutical synthesis. Used as an intermediate in organic synthesis and biochemical reagent. |
| Production method | It is obtained by treating methyl n-hexyl ketone oxime with phosphorus pentachloride. Methyl n-hexyl ketone oxime is treated with phosphorus pentachloride in ether, then water is added to stir well and then stratified. The N-acetyl-n-ethylamine generated by rearrangement is dissolved in ether, and the ether layer is separated. Distillation recovers ether, the remaining oily liquid is hydrolyzed with a dilute solution of potassium hydroxide, and then distilled. Collect 130-133 ℃ fractions to obtain hexylamine. |
| category | flammable liquid |
| toxicity classification | poisoning |
| acute toxicity | oral-rat LD50: 670 mg/kg |
| stimulation data | skin-rabbit 10 mg/24 hours severe; Eye-rabbit 2 mg/24 hours severe |
| flammability hazard characteristics | flammable in case of open flame, high temperature and oxidant; toxic nitrogen oxide smoke from combustion |
| storage and transportation characteristics | warehouse ventilation and low temperature drying; Store separately from oxidants and acids |
| fire extinguishing agent | dry powder, dry sand, carbon dioxide, foam, 1211 fire extinguishing agent |
| spontaneous combustion temperature | 270°C |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 15:16:47
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