中文名 | 脱皮甾酮 |
英文名 | 20-Hydroxyecdysone |
别名 | 蜕皮甾酮 脱皮激素 脱皮甾酮 蜕皮甾醇 β-脱皮松 β-蜕皮激素 羟基蜕皮激素 beta-蜕皮甾酮 20-羟基蜕皮甾酮 beta-蜕皮激素 蜕皮激素(蜕皮甾醇) 20-羟基蜕皮酮, 来源于露水草 ECDYSTERONE 蜕皮激素 BETA-蜕皮甾酮,BETA-蜕皮激素,20-羟基蜕皮甾酮 蜕皮激素(Β-蜕皮激素,Β-蜕皮甾酮,Β-蜕皮甾酮,20-羟基蜕皮甾酮,20-羟基蜕皮素,20-羟基蜕皮酮,Β-脱皮松,脱皮甾酮) |
英文别名 | ecdysterone Beta Ecdysone BETA-ECDYSONE Hydroxyecdysone Beta Ecdysterone beta-Ecdysterone BETA-ECDYSTERONE 20-Hydroxyecdysone 2b,3b,14a,20b,22,25-hexahydroxycholest-7-en-6-one 2B,3B,14A,20,22[R],25-HEXAHYDROXY-7-CHOLESTEN-6-ONE BETA-ECDYSONE,2,3,14,20,22,25-HEXAHYDROXY-7-CHOLESTEN-6-ONE 2BETA,3BETA,14ALPHA,20BETA,22,25-HEXAHYDROXY-7-CHOLESTEN-6-ONE 7,(5B)-CHOLESTEN-2BETA, 3BETA, 14ALPHA, 20BETA, 22R, 25-HEXOL-6-ONE (2beta,3beta,5beta,22R)-2,3,14,20,22,25-hexahydroxycholest-7-en-6-one (2beta,3beta,9xi,17xi,22R)-2,3,14,20,22,25-hexahydroxycholest-7-en-6-one (2beta,3beta,5beta,20S,22R)-2,3,14,20,22,25-hexahydroxycholest-7-en-6-one (2S,3R,5R,10R,13R,14S,17S)-2,3,14-trihydroxy-10,13-dimethyl-17-[(2R)-1,2,5-trihydroxy-1,5-dimethyl-hexyl]-2,3,4,5,9,11,12,15,16,17-decahydro-1H-cyclopenta[a]phenanthren-6-one (2S,3R,5R,9R,10R,13R,14S,17S)-2,3,14-TRIHYDROXY-10,13-DIMETHYL-17-((1R,2R)-1,2,5-TRIHYDROXY-1,5-DIMETHYL-HEXYL)-1,2,3,4,5,9,10,11,12,13,14,15,16,17-TETRADECAHYDRO-CYCLOPENTA[A]PHENANTHREN-6-ONE |
CAS | 5289-74-7 |
EINECS | 811-097-1 |
化学式 | C27H44O7 |
分子量 | 480.64 |
InChI | InChI=1/C27H44O7/c1-23(2,32)9-8-22(31)26(5,33)21-7-11-27(34)16-12-18(28)17-13-19(29)20(30)14-24(17,3)15(16)6-10-25(21,27)4/h12,15,17,19-22,29-34H,6-11,13-14H2,1-5H3/t15?,17?,19-,20+,21?,22-,24-,25-,26-,27-/m1/s1 |
InChIKey | NKDFYOWSKOHCCO-YPVLXUMRSA-N |
密度 | 1.0760 (rough estimate) |
熔点 | 242-244°C |
沸点 | 498.63°C (rough estimate) |
比旋光度 | +61.8 (CHCl3) |
闪点 | 392.3°C |
蒸汽压 | 8.7E-23mmHg at 25°C |
溶解度 | 酒精: 可溶 |
折射率 | 1.5800 (estimate) |
酸度系数 | 14.13±0.70(Predicted) |
存储条件 | Sealed in dry,Store in freezer, under -20°C |
外观 | 粉末 |
颜色 | white |
Merck | 13,3525 |
BRN | 1917578 |
物化性质 | 白色结晶粉末,易溶于乙醇,略溶于丙酮,微溶于热水、乙酸乙酯、氯仿,几乎不溶于乙醚,来源于漏芦、牛膝,珍珠露水草Cyanotis,arachnoidea,巴西人参(Pfaffia glomerata)。 |
MDL号 | MFCD00036740 |
危险品标志 | Xi - 刺激性物品 |
风险术语 | 36/37/38 - 刺激眼睛、呼吸系统和皮肤。 |
安全术语 | S22 - 切勿吸入粉尘。 S24/25 - 避免与皮肤和眼睛接触。 S36 - 穿戴适当的防护服。 S26 - 不慎与眼睛接触后,请立即用大量清水冲洗并征求医生意见。 |
WGK Germany | 2 |
RTECS | FZ8060000 |
FLUKA BRAND F CODES | 10 |
海关编号 | 29372900 |
上游原料 | 土克甾酮 |
参考资料 展开查看 | 1. 车奇涛 杨慧辛 王利丽 等. 不同采收期牛膝的质量分析[J]. 世界科学技术-中医药现代化 2019(12). 2. 王晓曦, 赵桂莹, 杨航,等. 蜕皮激素和有效霉素对粘虫几丁质合成酶B基因表达的影响[J]. 应用昆虫学报, 2019(5). 3. 刘志冲, 孙龙生, 杨家威,等. 饲料中添加β-蜕皮激素对罗氏沼虾生长性能的影响. 饲料与畜牧. 4. 吕子豪, 王春燕, 林同. 黄野螟中性肽链内切酶基因表达的时空动态[J]. 江苏农业学报, 2019. 5. 吕子豪, 李治兴, 林同. 黄野螟蜕皮激素受体基因HvEcR的鉴定及表达分析[J]. 西北农业学报, 2019, 028(007):1187-1194. 6. 刘明, 王慧森, 葛文静,等. 多指标正交试验法优选春花降压片水煎煮工艺[J]. 中医药导报, 2020, v.26;No.350(04):20-22+27. 7. 黄慧 王晓琴 杜月 等. HPLC法同时测定漏芦花中6个成分的含量[J]. 药物分析杂志 2017 037(006):956-961. 8. 严赟, 张赟赟. HPLC-ESI-MS/MS同时测定金果榄中5种成分含量[J]. 中药材, 2017, 40(002):395-398. 9. 张赟赟,李嘉.HPLC-ESI-MS/MS法同时测定金线风中7种有效成分[J].中华中医药杂志,2017,32(06):2762-2764. 10. 范小龙,陈冉,吴婉琴,刘国姣,黄坤,江丰.液相色谱串联质谱法测定食品中淫羊藿苷等20种功能成分[J].食品与机械,2021,37(01):86-93+98. 11. Li, Zhixing, et al. "Cloning, Expression Analysis, 20-Hydroxyecdysone Induction, and RNA Interference Study of Autophagy-Related Gene 8 from Heortia vitessoides Moore." Insects 11.4 (2020): 245.https://doi.org/10.3390/insects11040245 12. Wang, Chun-Yan, et al. "Chitin deacetylase 1 and 2 are indispensable for larval–pupal and pupal–adult molts in Heortia vitessoides (Lepidoptera: Crambidae)." Comparative Biochemistry and Physiology Part B: Biochemistry and Molecular Biology 237 (2019): 110 13. Zhang, Jing, et al. "Application of “spider-web” mode in discovery and identification of Q-markers from Xuefu Zhuyu capsule." Phytomedicine 77 (2020): 153273.https://doi.org/10.1016/j.phymed.2020.153273 14. [IF=4.242] Shun Zhou et al."Anthelmintic efficacy of 35 herbal medicines against a monogenean parasite, Gyrodactylus kobayashii, infecting goldfish (Carassius auratus)."Aquaculture. 2020 May;521:734992 15. [IF=3.935] Zhengchao Ji et al."Global identification and quantitative analysis of representative components of Xin-Nao-Kang Capsule, a traditional Chinese medicinal formula, by UHPLC-Q-TOF-MS and UHPLC-TQ-MS."J Pharmaceut Biomed. 2021 May;198:114002 16. [IF=2.769] Zhixing Li et al."Cloning, Expression Analysis, 20-Hydroxyecdysone Induction, and RNA Interference Study of Autophagy-Related Gene 8 from Heortia vitessoides Moore."Insects. 2020 Apr;11(4):245 17. [IF=2.231] Chun-Yan Wang et al."Chitin deacetylase 1 and 2 are indispensable for larval–pupal and pupal–adult molts in Heortia vitessoides (Lepidoptera: Crambidae)."Comp Biochem Phys B. 2019 Nov;237:110325 18. [IF=1.902] Ting Zhang et al."The influence of essential oils from ZhaLi NuSi Prescription on the pharmacokinetics of its non-volatile components in normal rats."Biomedical Chromatography. 2021 Oct 21 19. [IF=1.698] Zhixing Li et al."RNA interference of eclosion hormone gene reveals its roles in the control of ecdysis behavior in Heortia vitessoides Moore."Arch Insect Biochem. 2020 Sep;105(1):e21726 |
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