赤霉烯酮
玉米烯酮(zearalenone)
CAS: 17924-92-4
化学式: C18H22O5
| 中文名 | 玉米烯酮 |
| 英文名 | zearalenone |
| 别名 | 赤霉烯酮 玉米烯酮 玉米赤霉烯酮 玉米烯酮 溶液 玉米烯酮 标准品 玉米烯酮 来源于赤霉菌 玉米烯酮,来源于玉米赤霉菌 赤霉烯酮, 来源于赤霉菌属菌 玉米赤霉烯酮溶液,100PPM |
| 英文别名 | FES ZON Zenone ZENONE Toxin F2 CCRIS 623 F-2 toxin HSDB 4208 NCI-C50226 zearalenone ZEARALENONE Zearalenone BRN 1350216 Compound F-2 Mycotoxin F2 (-)-Zearalenone (s)-zearalenone (S)-Zearalenone trans-Zearalenone (10s)-zearalenone (e)--methyl-7-oxo (10S)-Zearalenone (s-(e))-xy-3-methyl (S)-(-)-Zearalenone 6-(10-Hydroxy-6-oxo-trans-1-undecenyl)-beta-resorcylic acid lactone Resorcylic acid, 6-(10-hydroxy-6-oxo-1-undecenyl)-, mu-lactone, trans- Benzoxacyclotetradec-11-en-1-one, 14,16-dihydroxy-3-methyl-7-oxo-, trans- (11Z)-14,16-dihydroxy-3-methyl-3,4,5,6,9,10-hexahydro-1H-2-benzoxacyclotetradecine-1,7(8H)-dione (S-(E))-3,4,5,6,9,10-Hexahydro-14,16-dihydroxy-3-methyl-1H-2-benzoxacyclotetradecin-1,7(8H)-dione (E)-(S)-2,4-DIHYDROXY-7-METHYL-7,8,9,10,13,14-HEXAHYDRO-12H-6-OXA-BENZOCYCLOTETRADECENE-5,11-DIONE (3S,11E)-14,16-dihydroxy-3-methyl-3,4,5,6,9,10-hexahydro-1H-2-benzoxacyclotetradecine-1,7(8H)-dione (3S,11E)-13,15-dihydroxy-3-methyl-3,4,5,6,9,10-hexahydro-1H-2-benzoxacyclotetradecine-1,7(8H)-dione 1H-2-Benzoxacyclotetradecin-1,7(8H)-dione, 3,4,5,6,9,10-hexahydro-14,16-dihydroxy-3-methyl-, (S)-(-)- 1H-2-Benzoxacyclotetradecin-1,7(8H)-dione, 3,4,5,6,9,10-hexahydro-14,16-dihydroxy-3-methyl-, (3S,11E)- |
| CAS | 17924-92-4 |
| EINECS | 241-864-0 |
| 化学式 | C18H22O5 |
| 分子量 | 318.36 |
| InChI | InChI=1/C18H22O5/c1-12-6-5-9-14(19)8-4-2-3-7-13-10-15(20)11-16(21)17(13)18(22)23-12/h3,7,10-12,20-21H,2,4-6,8-9H2,1H3/b7-3- |
| InChIKey | MBMQEIFVQACCCH-QBODLPLBSA-N |
| 密度 | 1.1270 (rough estimate) |
| 熔点 | 164-165°C |
| 沸点 | 377.53°C (rough estimate) |
| 比旋光度 | 25546 -170.5° (c = 1.0 in CH3OH) |
| 闪点 | 6°C |
| 蒸汽压 | 0mmHg at 25°C |
| 溶解度 | 可溶于乙醇、DMSO。 |
| 折射率 | 1.6120 (estimate) |
| 酸度系数 | 7.58±0.40(Predicted) |
| 存储条件 | 2-8°C |
| 外观 | 整洁 |
| Merck | 13,10169 |
| BRN | 1350216 |
| 物化性质 | 熔点 164-165°C 闪点 6 °C 储存条件 −20°C Merck 13,10169 |
| MDL号 | MFCD00133085 |
| 体内研究 | Zearalenone is frequently implicated in reproductive disorders of farm animals and occasionally in hyperoestrogenic syndromes in humans. There is evidence that ZEA and its metabolites possess oestrogenic activity in pigs, cattle and sheep. However, ZEA is of a relatively low acute toxicity after oral or interperitoneal administration in mice, rat and pig. |
| 危险品标志 | C - 腐蚀性物品 Xn - 有害物品  F - 易燃物品  |
| 风险术语 | R34 - 引起灼伤。 R62 - 有损害生育能力的危险。 R63 - 可能有对胎儿造成伤害的危险。 R36 - 刺激眼睛。 R20/21/22 - 吸入、皮肤接触及吞食有害。 R11 - 高度易燃。 |
| 安全术语 | S26 - 不慎与眼睛接触后，请立即用大量清水冲洗并征求医生意见。 S36/37/39 - 穿戴适当的防护服、手套和护目镜或面具。 S45 - 若发生事故或感不适，立即就医(可能的话，出示其标签)。 S36 - 穿戴适当的防护服。 S16 - 远离火源。 S36/37 - 穿戴适当的防护服和手套。 |
| 危险品运输编号 | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| RTECS | DM2550000 |
| FLUKA BRAND F CODES | 10 |
| 海关编号 | 29322090 |
| 下游产品 | Β-玉米赤霉烯醇 ALPHA-玉米赤霉烯醇 |
| 参考资料 展开查看 | 1. 时从来 刘明江 方国庆 等. 一种转化后的玉米赤霉烯酮产物对小鼠毒性研究[J]. 畜牧与兽医(12). 2. 陈伟,谷新晰,李广靖,徐冉,谷子林,陈宝江,卢海强.玉米赤霉烯酮降解酶ZHD101的表达优化及在玉米浆脱毒中的应用[J].河北农业大学学报,2020,43(06):26-34. 3. Zhiming Sun, Ankang Song, Bin Wang, Gaofeng Wang, Shuilin Zheng,Adsorption behaviors of aflatoxin B1 and zearalenone by organo-rectorite modified with quaternary ammonium salts,Journal of Molecular Liquids,Volume 264,2018,Pages 645-651,ISSN 0167-7322 4. He, Baoshan, and Xiaoze Dong. "Hierarchically porous Zr-MOFs labelled methylene blue as signal tags for electrochemical patulin aptasensor based on ZnO nano flower." Sensors and Actuators B: Chemical 294 (2019): 192-198.https://doi.org/10.1016/j.snb.2019.0 5. Baoshan He, Xiaohai Yan, A “signal-on” voltammetric aptasensor fabricated by hcPt@AuNFs/PEI-rGO and Fe3O4NRs/rGO for the detection of zearalenone, Sensors and Actuators B: Chemical, Volume 290, 2019, Pages 477-483, ISSN 0925-4005, https://doi.org/10.1016/j 6. He, Baoshan, and Xiaoze Dong. "Aptamer based voltammetric patulin assay based on the use of ZnO nanorods." Microchimica Acta 185.10 (2018): 1-8.https://doi.org/10.1007/s00604-018-3006-0 7. Baoshan He, Xiaoze Dong, Nb.BbvCI powered DNA walking machine-based Zr-MOFs-labeled electrochemical aptasensor using Pt@AuNRs/Fe-MOFs/PEI-rGO as electrode modification material for patulin detection, Chemical Engineering Journal, Volume 405, 2021, 126642, 8. [IF=5.833] He Baoshan et al."Aptamer based voltammetric patulin assay based on the use of ZnO nanorods."Microchim Acta. 2018 Oct;185(10):1-8 9. [IF=13.273] Baoshan He et al."Nb.BbvCI powered DNA walking machine-based Zr-MOFs-labeled electrochemical aptasensor using Pt@AuNRs/Fe-MOFs/PEI-rGO as electrode modification material for patulin detection."Chem Eng J. 2021 Feb;405:126642 10. [IF=7.46] Baoshan He et al."A “signal-on” voltammetric aptasensor fabricated by hcPt@AuNFs/PEI-rGO and Fe3O4NRs/rGO for the detection of zearalenone."Sensor Actuat B-Chem. 2019 Jul;290:477 11. [IF=7.46] Long Wang et al."A DNAzyme-assisted triple-amplified electrochemical aptasensor for ultra-sensitive detection of T-2 toxin."Sensor Actuat B-Chem. 2021 Feb;328:129063 12. [IF=5.833] He Baoshan et al."An amperometric zearalenone aptasensor based on signal amplification by using a composite prepared from porous platinum nanotubes, gold nanoparticles and thionine-labelled graphene oxide."Microchim Acta. 2019 Jun;186(6):1-10 13. [IF=5.467] Zhiming Sun et al."Hydrothermal fabrication of rectorite based biocomposite modified by chitosan derived carbon nanoparticles as efficient mycotoxins adsorbents."Appl Clay Sci. 2020 Jan;184:105373 14. [IF=3.223] Min Wei et al."Electrochemical Aptasensor for Zearalenone Based on DNA Assembly and Exonuclease III as Amplification Strategy."Electroanal. 2021 Jul;33(7):1691-1698 15. [IF=1.967] Chenling Qu et al."A homogeneous electrochemical aptasensor based on DNA assembly for zearalenone detection."J Chin Chem Soc-Taip. 2021 Oct;68(10):1998-2005 16. [IF=0.892] Jinping Wu et al."Effects of dietary zearalenone on the serum biochemistry, hepatic and intestinal histology, and intestinal microbiota of juvenile Dabry′s sturgeon (Acipenser dabryanus)."Journal Of Applied Ichthyology. 2021 Oct 04 17. [IF=3.591] Liangrui Lv et al."A switchable electrochemical hairpin-aptasensor for ochratoxin A detection based on the double signal amplification effect of gold nanospheres."New J Chem. 2022 Jan;: 18. [IF=4.932] Weifeng Zhu et al."Hyperoside Attenuates Zearalenone-induced spleen injury by suppressing oxidative stress and inhibiting apoptosis in mice."Int Immunopharmacol. 2022 Jan;102:108408 19. [IF=10.588] Feng Hong et al."A universal, portable, and ultra-sensitive pipet immunoassay platform for deoxynivalenol detection based on dopamine self-polymerization-mediated bioconjugation and signal amplification."JOURNAL OF HAZARDOUS MATERIALS. 2022 May;:129257 20. [IF=7.514] Supan Cheng et al."Surface-anchored liquid crystal droplets for the semi-quantitative detection of Aflatoxin B1 in food samples."FOOD CHEMISTRY. 2022 Oct;390:133202 |
赤霉烯酮 - 简介
玉米烯酮（也称为2,3-己二烯-1-酮）是一种有机化合物。以下是关于玉米烯酮的性质、用途、制法和安全信息的简介：
性质：
- 玉米烯酮是一种无色液体，具有特殊的气味。
- 它可以与许多常见的溶剂相溶，如醇、醚和酮。
用途：
- 玉米烯酮是有机合成中的重要原料，可用于合成多种有机化合物。
- 它还可用作香料添加剂和工业溶剂。
制法：
- 玉米烯酮的制备通常通过3-己烯氧化反应得到，反应条件一般为高温下进行。
安全信息：
- 玉米烯酮对皮肤、眼睛和呼吸道有刺激性。
- 长期接触或暴露于高浓度的玉米烯酮可能对健康造成危害。
- 使用时应佩戴适当的防护装备，确保通风良好。
- 在使用或储存时应避免与氧化剂和火源接触。
性质：
- 玉米烯酮是一种无色液体，具有特殊的气味。
- 它可以与许多常见的溶剂相溶，如醇、醚和酮。
用途：
- 玉米烯酮是有机合成中的重要原料，可用于合成多种有机化合物。
- 它还可用作香料添加剂和工业溶剂。
制法：
- 玉米烯酮的制备通常通过3-己烯氧化反应得到，反应条件一般为高温下进行。
安全信息：
- 玉米烯酮对皮肤、眼睛和呼吸道有刺激性。
- 长期接触或暴露于高浓度的玉米烯酮可能对健康造成危害。
- 使用时应佩戴适当的防护装备，确保通风良好。
- 在使用或储存时应避免与氧化剂和火源接触。
最后更新：2024-04-09 02:00:07
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