(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE - Names and Identifiers
Name | (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
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Synonyms | Bisdimethylphospholanobenzenecyclooctadienerhodium (+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4 (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (+)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-DUPHOS-Rh
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CAS | 205064-10-4
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(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE - Physico-chemical Properties
Molecular Formula | C26H40BF4P2Rh4*
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Molar Mass | 604.25 |
Appearance | crystal |
Color | red-orange |
Storage Condition | Room Temprature |
Sensitive | air sensitive |
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE - Risk and Safety
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | 24/25 - Avoid contact with skin and eyes.
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WGK Germany | 3 |
HS Code | 29310099 |
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE - Introduction
()-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene (1,5-cyclooacetadiene) rhodium(I) tetrafluoroborate is an organometallic compound having the chemical formula [C6H6(C8H12)(C16H32P2)Rh][BF4]. The following is a description of its nature, use, formulation and safety information:
Nature:
-Appearance: This compound is usually a colorless crystal or a powdery solid.
-Melting point: Its melting point range is 180-190°C.
-Solubility: It can be dissolved in some organic solvents, such as chloroform, carbon disulfide and dimethyl sulfoxide.
Use:
- ( )-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is an important coordination compound with important applications in organic synthesis and catalytic reactions. It can be used as a catalyst to promote various organic reactions, such as hydrogenation, hydroformylation, cyclization, and asymmetric catalytic reactions.
Preparation Method:
-A method for synthesizing ()-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is by mixing bromophenyl (1,5-cyclooctadiene)rhodium(I) heterocyclic pentane and (2S,5S)-2 in a suitable ratio, 5-dimethyl phospholane and tetrafluoroboric acid reaction.
Safety Information:
-Specific hazard and toxicity information for this compound is not readily available. However, as an organometallic compound, it may be dangerous to the human body and the environment. Therefore, when handling and handling, laboratory safety procedures should be followed and appropriate personal protective equipment should be used. During use and handling, strictly follow the safety regulations and avoid inhalation or skin contact.
Last Update:2024-04-10 22:29:15