(1,5-环辛二烯)氯化铑(I)二聚体
Chloro(1,5-cyclooctadiene)rhodium(I) dimer
CAS: 12092-47-6
Molecular Formula: C16H24Cl2Rh2
(1,5-环辛二烯)氯化铑(I)二聚体 - Names and Identifiers
| Name | Chloro(1,5-cyclooctadiene)rhodium(I) dimer |
| Synonyms | chlororhodium (1Z,5Z)-cycloocta-1,5-diene Chloro(1,5-cyclooctadiene)rhodium dimer Dichloro-bis-1,5-cyclooctadiene dirhodium Bis(cycloocta-1,5-diene)dichlorodirhodium Rhodium 1,5-cyclooctadiene chloride dimer Rhodium chloro(cycloocta-1,5-diene) dimer Chloro(1,5-cyclooctadiene)rhodium(I) dimer Chloro(1,5-Cyclooctadiene)Rhodium (I) Dimer Di-mu-chlorobis(1,5-cyclooctadiene)dirhodium Bis(1,5-cyclohexadiene)-mu,mu'-dichlorodirhodium 1,5-cyclooctadiene, chloride, (1Z,5Z)-, dirhodium salt di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-rhodiu |
| CAS | 12092-47-6 |
| EINECS | 235-157-6 |
| InChI | InChI=1/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;/r2C8H12.2ClRh/c2*1-2-4-6-8-7-5-3-1;2*1-2/h2*1-2,7-8H,3-6H2;;/b2*2-1-,8-7-; |
(1,5-环辛二烯)氯化铑(I)二聚体 - Physico-chemical Properties
| Molecular Formula | C16H24Cl2Rh2 |
| Molar Mass | 493.08 |
| Density | 1.94[at 20℃] |
| Melting Point | 243 °C (dec.) (lit.) |
| Boling Point | 153.5℃ at 760mmHg |
| Water Solubility | 1.56g/L at 20℃ |
| Solubility | Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents. |
| Vapor Presure | 0Pa at 25℃ |
| Appearance | Orange yellow to orange brown powder or crystal |
| Color | Orange to orange-brown |
| Exposure Limit | ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| Storage Condition | Inert atmosphere,Room Temperature |
| Stability | hygroscopic |
| Sensitive | Air Sensitive & Hygroscopic |
| MDL | MFCD00012415 |
| Use | Catalyst for the reaction of 1, 3-diene and activated hydrocarbons and preparation of chiral complexes. Coupling reaction; asymmetric hydrogenation reaction; borohydride reaction. |
(1,5-环辛二烯)氯化铑(I)二聚体 - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 - Wear suitable gloves and eye/face protection |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 3 |
| TSCA | Yes |
| HS Code | 28439000 |
(1,5-环辛二烯)氯化铑(I)二聚体 - Introduction
Easy to absorb moisture. Slightly soluble in most common solvents. Insoluble in water.
Last Update：2022-10-16 17:12:44
(1,5-环辛二烯)氯化铑(I)二聚体 - Reference Information
| LogP | 3.16 at 20℃ |
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| Uses | (1, 5-cyclooctadiene) rhodium chloride (I) dimer is used to synthesize metal ligands for catalytic reactions. 1, 3-diene and activated hydrocarbon reaction catalyst and preparation of chiral complexes. Coupling reaction; asymmetric hydrogenation reaction; borohydride reaction. |
Last Update：2024-04-09 20:52:54
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View History
(1,5-环辛二烯)氯化铑(I)二聚体
Sodium n-butoxide
5-chloro-2-{[2-(dimethylamino)ethyl]thio}pyrimidine-4-carboxylic acid
methyl 3-[(5-nitropyridin-2-yl)oxy]benzoate
ISOPROPYL DIETHYL MALONATE
氯甲基三甲硅烷
4-((2,5-二氧代-2,5-二氢-1H-吡咯-1-基)甲基)-N-(丙-2-炔-1-基)环己烷甲
2-MORPHOLINO-4H-PYRIMIDO[2,1-A]ISOQUINOLIN-4-ONE 2-吗啉基-4H-嘧啶并[2,1-A]异喹啉-4-酮
TRIMETHYLSILYL CYANIDE
Bis(2-methylpropyl) disulphide
Sodium n-butoxide
5-chloro-2-{[2-(dimethylamino)ethyl]thio}pyrimidine-4-carboxylic acid
methyl 3-[(5-nitropyridin-2-yl)oxy]benzoate
ISOPROPYL DIETHYL MALONATE
氯甲基三甲硅烷
4-((2,5-二氧代-2,5-二氢-1H-吡咯-1-基)甲基)-N-(丙-2-炔-1-基)环己烷甲
2-MORPHOLINO-4H-PYRIMIDO[2,1-A]ISOQUINOLIN-4-ONE 2-吗啉基-4H-嘧啶并[2,1-A]异喹啉-4-酮
TRIMETHYLSILYL CYANIDE
Bis(2-methylpropyl) disulphide