(1R)-2-hydroxy-1-phenylethanaminium
(R)-(-)-2-Phenylglycinol
CAS: 56613-80-0
Molecular Formula: C8H11NO
(1R)-2-hydroxy-1-phenylethanaminium - Names and Identifiers
| Name | (R)-(-)-2-Phenylglycinol |
| Synonyms | D-PHG-OL H-D-Phg-ol H-D-PHG-OL D-plenylglycinol D-PHENYLGLYCINOL D-Phenylglycinol d-plenylglycinol D-2-Phenylglycinol 2-(R)-Phenylglycinol D-(-)-A-PHENYLGLYCINOL (R)-(-)-2-Phenylglycinol (R)-(+)-2-Phenylglycinol D-minus-A-phenylglycinol D(-)-ALPHA-PHENYLGLYCINOL (R)-b-Aminophenethyl alcohol D-(-)2-AMINO-2-PHENYLETHANOL BENZENEETHANOL, B-AMINO-, (BR)- (R)-(-)-2-Amino-2-phenylethanol (1R)-2-hydroxy-1-phenylethanaminium (1S)-2-hydroxy-1-phenylethanaminium |
| CAS | 56613-80-0 |
| EINECS | 260-287-5 |
| InChI | InChI=1/C8H11NO/c9-8(6-10)7-4-2-1-3-5-7/h1-5,8,10H,6,9H2/p+1/t8-/m0/s1 |
| InChIKey | IJXJGQCXFSSHNL-QMMMGPOBSA-N |
(1R)-2-hydroxy-1-phenylethanaminium - Physico-chemical Properties
| Molecular Formula | C8H11NO |
| Molar Mass | 137.18 |
| Density | 1.0630 (rough estimate) |
| Melting Point | 76-79°C |
| Boling Point | 252.03°C (rough estimate) |
| Specific Rotation(α) | -25.5 º (c=6,MeOH) |
| Flash Point | 125.3°C |
| Water Solubility | Slightly soluble in water. |
| Solubility | Aqueous Acid (Slightly, Sonicated), Chloroform (Sparingly, Heated), Methanol (Sl |
| Vapor Presure | 0.00601mmHg at 25°C |
| Appearance | White to yellow crystals |
| Color | White to yellow |
| BRN | 2935848 |
| pKa | 12.51±0.10(Predicted) |
| Storage Condition | Keep in dark place,Inert atmosphere,2-8°C |
| Sensitive | Air Sensitive |
| Refractive Index | -29.5 ° (C=1, EtOH) |
| MDL | MFCD00008062 |
| Physical and Chemical Properties | Melting point 75-77°C specific optical rotation -25.5 ° (c = 6,MeOH) |
| Use | This product is for scientific research only and shall not be used for other purposes. |
(1R)-2-hydroxy-1-phenylethanaminium - Risk and Safety
| Risk Codes | R34 - Causes burns R36/37/38 - Irritating to eyes, respiratory system and skin. R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S22 - Do not breathe dust. S24/25 - Avoid contact with skin and eyes. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 2-10 |
| HS Code | 29221980 |
(1R)-2-hydroxy-1-phenylethanaminium - Reference Information
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| Use | for the preparation of chiral imine or oxazolidine from ethyl trifluoropyruvate; chiral β-amino alcohol used as a synthetic structural unit chiral β-amino alcohol used as a synthetic structural unit. The present amino alcohols can be used for the preparation of chiral imines or oxazolidines from ethyl trifluoropyruvate. These intermediates can then be used to synthesize both enantiomers of α-trifluoromethylproline. |
Last Update：2024-04-09 21:11:58
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