(1R,2S,3R,4S)-1,7,7-Trimethylnorbornane-2,3-diol
(+|-)-EXO EXO-2 3-CAMPHANEDIOL
CAS: 56614-57-4
Molecular Formula: C10H18O2
(1R,2S,3R,4S)-1,7,7-Trimethylnorbornane-2,3-diol - Names and Identifiers
(1R,2S,3R,4S)-1,7,7-Trimethylnorbornane-2,3-diol - Physico-chemical Properties
| Molecular Formula | C10H18O2 |
| Molar Mass | 170.25 |
| Density | 1.117±0.06 g/cm3(Predicted) |
| Melting Point | 262-268°C |
| Boling Point | 261.7±8.0 °C(Predicted) |
| pKa | 14.80±0.70(Predicted) |
| Storage Condition | 2-8°C |
| Refractive Index | 1.535 |
(1R,2S,3R,4S)-1,7,7-Trimethylnorbornane-2,3-diol - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 41 - Risk of serious damage to eyes |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39 - Wear eye / face protection. |
| WGK Germany | 2 |
(1R,2S,3R,4S)-1,7,7-Trimethylnorbornane-2,3-diol - Introduction
(|-)-EXO EXO-2 3-CAMPHANEDIOL, also known as (|-)-EXO EXO-2, 3-camphordiol, is a dihydric alcohol compound. It has a chemical formula of C10H16O2 and a molecular weight of 168.23g/mol. It had the appearance of a white crystalline solid.
( |-)-EXO EXO-2 3-CAMPHANEDIOL can be used for asymmetric catalytic reactions in organic synthesis, such as catalysts or ligands in the synthesis of chiral molecules and intermediates. It may exhibit enantioselectivity in some catalytic reactions, and has a wide range of applications, such as medicine, materials science and the synthesis of natural products.
The method of preparing (|-)-EXO EXO-2 3-CAMPHANEDIOL can be prepared by dissolving E-camphorene in dichloromethane in an aqueous sodium carbonate solution, and adding a nitric acid sulfuric acid solution under high-speed stirring to generate the nitrate of the substrate. The nitrate is then reduced to the diol by a reduction reaction.
Regarding safety information,( |-)-EXO EXO-2 3-CAMPHANEDIOL is a chemical, and attention should be paid to safe operation and storage. It may be irritating to the eyes, skin and respiratory tract, so it is necessary to pay attention to protective measures when using it, such as wearing protective glasses, gloves and masks. In storage, it should be kept in a cool, dry, well-ventilated place, away from fire and combustibles.
In addition, for laboratory use, the operation should be carried out in accordance with the relevant safety procedures and comply with local laws and regulations.
( |-)-EXO EXO-2 3-CAMPHANEDIOL can be used for asymmetric catalytic reactions in organic synthesis, such as catalysts or ligands in the synthesis of chiral molecules and intermediates. It may exhibit enantioselectivity in some catalytic reactions, and has a wide range of applications, such as medicine, materials science and the synthesis of natural products.
The method of preparing (|-)-EXO EXO-2 3-CAMPHANEDIOL can be prepared by dissolving E-camphorene in dichloromethane in an aqueous sodium carbonate solution, and adding a nitric acid sulfuric acid solution under high-speed stirring to generate the nitrate of the substrate. The nitrate is then reduced to the diol by a reduction reaction.
Regarding safety information,( |-)-EXO EXO-2 3-CAMPHANEDIOL is a chemical, and attention should be paid to safe operation and storage. It may be irritating to the eyes, skin and respiratory tract, so it is necessary to pay attention to protective measures when using it, such as wearing protective glasses, gloves and masks. In storage, it should be kept in a cool, dry, well-ventilated place, away from fire and combustibles.
In addition, for laboratory use, the operation should be carried out in accordance with the relevant safety procedures and comply with local laws and regulations.
Last Update：2024-04-09 20:52:54
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