-3,5-heptanedionato)(1,5-cycL - Names and Identifiers
Name | Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II)
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Synonyms | -3,5-heptanedionato)(1,5-cycL bis[(Z)-1-tert-butyl-4,4-dimethyl-3-oxo-pent-1-enoxy]rutheni... RUTHENIUM(ll) CYCLOOCTADIENE BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) RUTHENIUM(II) CYCLOOCTADIENE BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)(1,5-CYCLOOCTADIENE)RUTHENIUM (II)
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CAS | 329735-79-7
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-3,5-heptanedionato)(1,5-cycL - Physico-chemical Properties
Molecular Formula | C30H50O4Ru4*
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Molar Mass | 575.79 |
Melting Point | 187-190°C |
Boling Point | 220°C |
Appearance | crystal |
Color | yellow-orange microcrystal |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
Sensitive | 4: no reaction with water under neutral conditions |
-3,5-heptanedionato)(1,5-cycL - Risk and Safety
Hazard Symbols | Xn - Harmful
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Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
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TSCA | No |
-3,5-heptanedionato)(1,5-cycL - Introduction
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cycloketadiene) ruthenium(II) is a transition metal complex with the formula Ru(COD)(TMHD)2, where COD means 1,5-cyclooctadiene and TMHD means 2,2,6,6-tetramethyl-3,5-dioxanone. The following is a description of its nature, use, preparation and safety information:
Nature:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclootadiene) ruthenium(II) is a solid yellow crystal.
-It is stable at room temperature, but it will decompose when heated.
-Soluble in common organic solvents such as ethanol and dimethylformamide.
Use:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) is commonly used as a catalyst in organic synthesis.
-It can be applied to the activation reaction of inert bonds, asymmetric catalysis and hydrogen transfer reactions.
-This complex can also be used to prepare other ruthenium complexes with catalytic activity.
Preparation Method:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) can be obtained by reacting ruthenate with 2,2,6,6-tetramethyl-3,5-heptadione and then with 1,5-cyclooctadiene.
Safety Information:
-specific hazard and safety information of Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) may require reference to relevant chemical substance safety information.
-When handling this substance, you need to pay attention to prevent contact with skin and eyes, and avoid inhaling its dust or gas.
-When using or handling the substance, follow relevant laboratory safety procedures and personal protective measures.
Last Update:2024-04-10 22:29:15