1,1-二(二苯膦基)二茂铁二氯化钯DPPF二氯化钯

1,1-二(二苯膦基)二茂铁二氯化钯DPPF二氯化钯 - Names and Identifiers

Name	[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride
Synonyms	PDCL2(DPPF) 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) 1,1'-Bis(diphenylphosphino)ferrocenedichloropalladium(II) 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add
CAS	72287-26-4
EINECS	460-040-3
InChI	InChI=1/2C17H15P.2ClH.Fe.Pd/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h21-13H,14H2;2*1H;;/q;;;;;+2/p-2

1,1-二(二苯膦基)二茂铁二氯化钯DPPF二氯化钯 - Physico-chemical Properties

Molecular Formula	C34H22Cl2FeP2Pd
Molar Mass	725.66
Melting Point	275-280°C(lit.)
Solubility	Soluble in dichloromethane.
Appearance	Dark brown powder
Color	red to very dark red
Storage Condition	Keep in dark place,Inert atmosphere,Room temperature
Sensitive	Sensitive to air and easy to absorb moisture
MDL	MFCD00015757
Physical and Chemical Properties
Use	Applications: carbonylation reaction, cross-coupling reaction, Suzuki reaction

1,1-二(二苯膦基)二茂铁二氯化钯DPPF二氯化钯 - Risk and Safety

Risk Codes	R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. R40 - Limited evidence of a carcinogenic effect
Safety Description	S23 - Do not breathe vapour. S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 - Wear suitable protective clothing and gloves.
WGK Germany	3
TSCA	No
HS Code	28439000
Hazard Class	IRRITANT

1,1-二(二苯膦基)二茂铁二氯化钯DPPF二氯化钯 - Introduction

Insoluble in water, soluble in chloroform, slightly soluble in dichloromethane.

Last Update：2022-10-16 17:28:10

1,1-二(二苯膦基)二茂铁二氯化钯DPPF二氯化钯 - Reference Information

Introduction	DPPF Palladium dichloride {[1,1 '-bis (diphenylphosphine) ferrocene] palladium (II) dichloride} is a palladium complex of an iron-containing ligand, dppf. This is a commercially available reagent commonly used in palladium-catalyzed coupling reactions. As a catalyst, DPPF Palladium dichloride can be widely used in the fields of organic chemistry, pharmaceutical chemistry and the synthesis of liquid crystal materials.
appearance	DPPF Palladium dichloride was orange-red powder.
Use	[1,1 '-bis (diphenylphosphino) ferrocene] Palladium dichloride (PdCl2(dppf)) as a catalyst, it is mainly used to catalyze cross-coupling reactions. Similar to other Pd(II) and Ni(II) complexes, PdCl2(dppf) can effectively catalyze halogenated olefins, the formation of carbon-carbon bond is realized by the cross-coupling reaction between halogenated aromatic hydrocarbon or trifluoromethylsulfonic arene and Grignard reagent. [1,1 '-bis (diphenylphosphino) ferrocene] palladium (II) dichloride is a palladium catalyst used in the chemical synthesis of various compounds. For the preparation of nucleosides as exonuclease inhibitors. catalyst for carbonylation reaction, cross-coupling reaction, Suzuki reaction. C-C and C- N catalysts for coupling reaction
preparation	A 1,1 '-bis (diphenylphosphino) ferrocene Palladium dichloride II(dppfPdCl2) the preparation method comprises the following steps:(a) adding palladium chloride to concentrated hydrochloric acid, heating to 40-80 ° C to dissolve, the amount of hydrochloric acid is 0.2-1.0 times the mass of palladium chloride, and adding ethanol to dilute, the amount of ethanol is 10-50 times the mass of palladium chloride; (B) 3.0-5.0 times the mass of palladium chloride BIS diphenylphosphinoferrocene (dppf) is added to the tetrahydrofuran solution, heated to 40-80 deg C, until dissolved, the amount of tetrahydrofuran is 20-30 times the mass of palladium chloride;(c) the solution obtained in step (a) is added dropwise to the solution obtained in step (B), after completion of the dropwise addition, the mixture was maintained at 45-80 ° C. For 0.5-3H, then cooled, filtered, washed and dried under vacuum to give red crystals of 1,1'-bis (diphenylphosphino) ferrocene Palladium II dichloride.
Storage Conditions	DPPF Palladium dichloride should be stored in a sealed, cool and dry place.

Last Update：2024-04-10 22:29:15

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