1,10-Phenanthroline-5,6-diaMine

Name	5,6-diamino-1,10-phenanthroline
Synonyms	5,6-diamino 1,10-Phenanthroline-5,6-diaMine 5,6-diamino-1,10-phenanthroline 1,10-phenanthroline-5,6-diamine 5,6-diaMino-1,10-phenanthroline 1,10-
CAS	168646-54-6
InChI	InChI=1/C12H10N4/c13-9-7-3-1-5-15-11(7)12-8(10(9)14)4-2-6-16-12/h1-6H,13-14H2

Molecular Formula	C12H10N4
Molar Mass	210.23
Density	1.414±0.06 g/cm3(Predicted)
Melting Point	155-156 °C
Boling Point	492.7±40.0 °C(Predicted)
Flash Point	283.784°C
Vapor Presure	0mmHg at 25°C
pKa	5.78±0.10(Predicted)
Storage Condition	Keep in dark place,Inert atmosphere,Room temperature
Refractive Index	1.853

Overview	5, 6-diamino-1, 10-phenanthroline is an organic intermediate that can be obtained by preparing 1,10-phenanthroline in three steps. 5, 6-diamino-1, 10-phenanthroline can be used to prepare an organic rare earth europium luminescent nylon with high efficiency and high luminous intensity under ultraviolet light irradiation or electroluminescent conditions.
application	5, 6-diamino-1, 10-phenanthroline is a heterocyclic organic substance and can be used as a pharmaceutical intermediate.
preparation	5,6-diamino -1,10-phenanthroline preparation: 6 mmol5,6-dioxime -1,10-phenanthroline is put into 40ml of anhydrous ethanol to obtain an alcohol solution, heated to 75 ℃ under inert gas protection, and 25mmol sodium hydrosulfite is dissolved in 20ml of ammonia water solution with 5% content, the second mixture is obtained, and 20ml of the second mixture is quickly added to the alcohol solution. After 45min, when yellow solid matter is precipitated, the same 20ml second mixed solution is added and reacted at 80 ℃ for 2 hours. Cooling to normal temperature, suction filtration, washing with distilled water for 3 times, then washing with ethanol for 3 times, vacuum drying, vacuum degree of 0.09MPa, drying temperature of 65 ℃; Drying time is 5h; Golden yellow solid product was obtained with 76.0% yield.

Last Update：2024-04-10 22:29:15