Name | 1,2-O-Isopropylidene-D-glucofuranose |
Synonyms | MONOACETONGLUCOSE MONOACETONE GLUCOSE 1,2-O-Isopropylidene Monoacetone-D-glucose 1,2-O-Isopropylidene-D-glucofuranose 1,2-O-ISOPROPYLIDENE-D-GLUCOFURANOSE ISOPROPYLIDENE-D-GLUCOFURANOSE, 1,2-O- 1,2-O-(1-methylethylidene)hexofuranose 1,2-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE 1,2-O-ISOPROPYLIDENE-D-GLUCOFURANOSIDE 1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE 1,2-O-Isopropylidene-alpha-D-glucofuranose 1,2-O-(1-methylethylidene)-β-L-idofuranose 1,2-O-(1-methylethylidene)-alpha-D-glucofuranose |
CAS | 18549-40-1 |
EINECS | 242-420-9 |
InChI | InChI=1/C9H16O6/c1-9(2)14-7-5(12)6(4(11)3-10)13-8(7)15-9/h4-8,10-12H,3H2,1-2H3/t4-,5-,6+,7+,8+/m0/s1 |
InChIKey | BGGCXQKYCBBHAH-HEIBUPTGSA-N |
Molecular Formula | C9H16O6 |
Molar Mass | 220.22 |
Density | 1.2560 (rough estimate) |
Melting Point | 159-160°C(lit.) |
Boling Point | 321.15°C (rough estimate) |
Specific Rotation(α) | -13 º (c=1, H2O) |
Flash Point | 209.3°C |
Solubility | Methanol (Slightly), Water (Slightly) |
Vapor Presure | 6.62E-09mmHg at 25°C |
Appearance | White Crystalline Solid |
Color | White |
BRN | 82670 |
pKa | 13.19±0.60(Predicted) |
Storage Condition | -20°C |
Refractive Index | 1.6000 (estimate) |
MDL | MFCD00063244 |
Use | For biochemical reactions and pharmaceutical intermediates |
Hazard Symbols | Xn - Harmful |
Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S24/25 - Avoid contact with skin and eyes. S36 - Wear suitable protective clothing. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
WGK Germany | 3 |
FLUKA BRAND F CODES | 21 |
TSCA | Yes |
HS Code | 29329990 |
NIST chemical information | Information provided by: webbook.nist.gov (external link) |
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
overview | monoacetone glucose can be used as an intermediate in pharmaceutical synthesis. If you inhale monoacetone glucose, please move the patient to fresh air; if the skin is in contact, remove the contaminated clothes, rinse the skin thoroughly with soapy water and water, and see a doctor if you feel uncomfortable; if you are in contact with clear eyes, separate the eyelids, rinse with flowing water or normal saline, and see a doctor immediately; if you eat, rinse your mouth immediately, prohibit vomiting, and see a doctor immediately. |
Uses | Used for biochemical reactions and pharmaceutical intermediates Monoacetone glucose D-furan glucose partially protected by pharmaceutical intermediates, an important chiral block, can be selectively derivatized at the 6-OH primary hydroxyl position, or oxidize to remove divalerose derivatives; directly converted to 5,6-anhydride compound (Mitsunobu reaction); preparation of 3, 5-O-phenylmethylene derivatives |