Name | N,N,N',N'-Tetramethyl-p-phenylenediamine |
Synonyms | 1,4-BIS(DIMETHYLAMINO)BENZENE 1,4-bis(dimethylamino)-benzen Benzene, 1,4-bis(dimethylamino)- N,N,N',N'-Tetramethyl-p-fenylendiamin N,N,N',N'-Tetramethyl-p-phenylenediamine N,N,N',N'-tetramethylbenzene-1,4-diamine N,N,N',N'-TETRAMETHYL-P-PHENYLENEDIAMINE 4-Benzenediamine,N,N,N',N'-tetramethyl-1 N,N,N',N'-Tetramethyl-1,4-Benzenediamine N,N,N',N'-TETRAMETHYL-1,4-PHENYLENEDIAMINE 1,4-Bis(dimethylamino)benzene~Wursters Blue N,N,N,N-tetramethyl-P-*phenylenediamine free ba N,N,N?N?Tetramethyl-p-phenylene- diamine, [1,4-Bis(dimethylamino)benzene |
CAS | 100-22-1 |
EINECS | 202-831-6 |
InChI | InChI=1/C10H16N2/c1-11(2)9-5-7-10(8-6-9)12(3)4/h5-8H,1-4H3 |
Molecular Formula | C10H16N2 |
Molar Mass | 164.25 |
Density | 0.9743 (rough estimate) |
Melting Point | 49-51°C(lit.) |
Boling Point | 260°C(lit.) |
Flash Point | >230°F |
Water Solubility | slightly in cold, more in hot water |
Vapor Presure | 0.0121mmHg at 25°C |
Appearance | powder |
Color | off-white to gray |
Merck | 14,9228 |
BRN | 1564025 |
pKa | 5.92±0.12(Predicted) |
Storage Condition | Store below +30°C. |
Stability | Stable, but may be air or light sensitive. Combustible. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents. |
Sensitive | Air & Light Sensitive |
Refractive Index | 1.5700 (estimate) |
MDL | MFCD00008309 |
Use | Used as a curing agent |
Hazard Symbols | Xn - Harmful |
Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R40 - Limited evidence of a carcinogenic effect R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S28 - After contact with skin, wash immediately with plenty of soap-suds. S28A - S36 - Wear suitable protective clothing. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S22 - Do not breathe dust. |
UN IDs | UN 2811 6.1/PG 3 |
WGK Germany | 1 |
RTECS | ST4200000 |
FLUKA BRAND F CODES | 10 |
TSCA | Yes |
HS Code | 29215190 |
Hazard Class | 6.1(a) |
Packing Group | II |
Toxicity | LD50 oral in bird - wild: 23700ug/kg |
is a bright plate-like crystal precipitated from petroleum ether. Slightly soluble in cold water, soluble in hot water, easily soluble in ethanol, chloroform, ether and petroleum ether. Easy to volatile, easy sublimation.
phenyldiamine is used as a raw material to react with chloroacetic acid to form phenyldiaminotetraacetic acid, and then decarboxylation reaction is carried out to obtain a finished product.
It can be used as an oxygen scavenger for boiler water in the field of water treatment. Its oxygen scavenging capacity is better than that of hydroquinone. Not only can be used in the boiler water, can also be added to the operation of the boiler water. Due to its high volatility, it can also be used for oxygen removal in boiler condensate water systems. It is also used as a developing aid for color photography and as a reagent for measuring the formaldehyde content in the air.
pure N,N,N,N-tetramethylp-phenylenediamine, or its intermediate oxidation products, are toxic. Production, use of the product staff, should be protected.
NIST chemical information | Information provided by: webbook.nist.gov (external link) |
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
use | as curing agent |
category | toxic substances |
toxicity classification | highly toxic |
acute toxicity | oral-rat LDL0: 500 mg/kg; Oral-wild bird LD50: 23.7 mg/kg |
flammability hazard characteristics | combustible; combustion produces toxic nitrogen oxide smoke |
storage and transportation characteristics | warehouse ventilation and low temperature drying; separate from food raw materials |
fire extinguishing agent | dry powder, foam, sand, carbon dioxide, mist water |