101-77-9
4,4'-Methylenedianiline
CAS: 101-77-9
Molecular Formula: C13H16N2
101-77-9 - Names and Identifiers
| Name | 4,4'-Methylenedianiline |
| Synonyms | MDA DADPM 4,4'-diaminoditan 4,4-Methylenedianiline 4,4'-Methylenedianiline 4,4'-Methylenebisaniline 4,4'-methanediyldianiline 3,3'-methanediyldianiline 2,2'-methanediyldianiline 4,4'-diaminodiphenylmethan 1,1-diphenylmethanediamine 4,4'-methanediyldianilinium N,N'-diphenylmethanediamine 4-(4-Aminobenzyl)phenylamine 4,4'-methylenebis-benzenamin 4,4'-methylenebisbenzenamine 4,4'-Diamino diphenyl methane |
| CAS | 101-77-9 |
| EINECS | 202-974-4 |
| InChI | InChI=1/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,14-15H2/p+2 |
101-77-9 - Physico-chemical Properties
| Molecular Formula | C13H16N2 |
| Molar Mass | 200.278 |
| Melting Point | 88-92℃ |
| Boling Point | 398°C at 760 mmHg |
| Flash Point | 226.3°C |
| Water Solubility | Slightly soluble. <0.1 g/100 mL at 19℃ |
| Solubility | water: soluble |
| Vapor Presure | 1.52E-06mmHg at 25°C |
| Merck | 14,2980 |
| BRN | v |
| pKa | 5.32±0.25(Predicted) |
| Physical and Chemical Properties | Appearance: light yellow crystal, turned black when exposed to light. |
| Use | For the production of insulating materials, dyes, diisocyanate, polyurethane rubber, H-class adhesives, epoxy resin curing agent; Epoxy resin curing agent, rubber antioxidant and antioxidant, intermediates for the synthesis of MDI, it is also used for the determination of tungsten and sulfate. |
101-77-9 - Risk and Safety
| Hazard Symbols | T - Toxic N - Dangerous for the environment  |
| Risk Codes | R43 - May cause sensitization by skin contact R45 - May cause cancer R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S53 - Avoid exposure - obtain special instructions before use. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | UN 2651 |
| WGK Germany | 3 |
| RTECS | BY5425000 |
| TSCA | Yes |
| HS Code | 29215900 |
| Hazard Class | 6.1 |
| Packing Group | III |
101-77-9 - Upstream Downstream Industry
| Raw Materials | Aniline Formaldehyde Sodium hydroxide Hydrochloric acid |
| Downstream Products | flunarizine dihydrochloride |
101-77-9 - Introduction
Chemical properties White to yellowish brown flake crystals. Soluble in hot water, ethanol, ether, benzene.
Use as an analytical reagent and also used in organic synthesis
Uses are mainly used in rubber products such as tires, sidewalls, plies, inner tubes, conveying tubes, hoses, and V-belts
Uses used in the production of insulating materials, dyes, diisocyanates, polyurethane rubber, H-grade adhesives, epoxy resin curing agents, etc.; epoxy resin curing agents, rubber antioxidants and antioxidants, synthetic MDI intermediates, It is also used to determine tungsten and sulfate.
Uses are mainly used to manufacture polymer materials such as epoxy resin, polycarbonate, polysulfone resin, phenolic unsaturated resin, polyetherimide, etc., and can also be used to manufacture polyvinyl chloride heat stabilizers, Plasticizers, rubber antioxidants, agricultural fungicides, paints, ultraviolet absorbers
Use to manufacture dyes, determine tungsten and sulfate, rubber antioxidants and antioxidants.
Category Toxic
Toxic graded poisoning
acute toxicity oral-rat LD50: 662 mg/kg; Oral-mouse LD50: 745 mg/kg
stimulation data eye-rabbit 100 mg/24 hours moderate
Flammability hazard characteristics Open flame is flammable; heated to release toxic nitrogen oxide gas
Storage and transportation characteristics The warehouse is ventilated and dry at low temperature; stored and transported separately from food raw materials
Extinguishing agent water, carbon dioxide, sand, foam
occupational standard TWA 0.8 mg/m3; STEL 4.0 mg/m3
Last Update：2024-05-07 14:21:06
101-77-9 - Introduction
Nature:
1. It is a solid compound that appears white to light yellow.
2. It is a relatively stable compound with high melting and boiling points.
3. It has low solubility in water, but good solubility in organic solvents.
Usage:
1. Mainly used as an intermediate in polyimide resins.
2. This compound is commonly used as a crosslinking agent for hard polyurea formaldehyde resins in industry, for the preparation of high-temperature and corrosion-resistant industrial coatings, adhesives, and plastics.
Method:
Usually formed by the reaction of aniline and formaldehyde under alkaline conditions. Firstly, aniline is oxidized to resorcinol in alkaline solution. Then, resorcinol undergoes a condensation reaction with formaldehyde to produce the target product 4,4 '- diaminodiphenylmethane. The reaction process should be carried out under appropriate temperature and pH conditions.
Security information:
1. Has high toxicity and carcinogenicity.
2. Long term exposure or inhalation of this compound may pose a health hazard.
3. During use, it is necessary to strictly follow safety operating procedures, wear personal protective equipment, and ensure good ventilation.
4. Avoid contact with skin and avoid inhaling its vapors.
5. When storing and handling this compound, it should be kept away from fire and heat sources to avoid fire and explosion accidents.
Last Update：2024-05-07 14:21:53
Supplier List
Spot supply
Product Name: 4,4'-Methylenedianiline Request for quotationCAS: 101-77-9
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3787852685
Multiple SpecificationsSpot supply
Product Name: 4,4'-Methylenedianiline Request for quotationCAS: 101-77-9
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Product Name: 4,4'-Methylenedianiline Request for quotation
CAS: 101-77-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
CAS: 101-77-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Spot supply
Product Name: 4,4'-Methylenedianiline Request for quotationCAS: 101-77-9
Tel: 86+027-83389957
Email: 1024042217@qq.com
Mobile: 86+18627766980
QQ: 1024042217
Wechat: 18627766980
Spot supply
Product Name: 4,4'-Methylenedianiline Request for quotationCAS: 101-77-9
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3787852685
Multiple SpecificationsSpot supply
Product Name: 4,4'-Methylenedianiline Request for quotationCAS: 101-77-9
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Product Name: 4,4'-Methylenedianiline Request for quotation
CAS: 101-77-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
CAS: 101-77-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Spot supply
Product Name: 4,4'-Methylenedianiline Request for quotationCAS: 101-77-9
Tel: 86+027-83389957
Email: 1024042217@qq.com
Mobile: 86+18627766980
QQ: 1024042217
Wechat: 18627766980
View History
Raw Materials for 101-77-9
Downstream Products for 101-77-9