103-50-4
Benzyl Ether
CAS: 103-50-4
Molecular Formula: C14H14O
103-50-4 - Names and Identifiers
| Name | Benzyl Ether |
| Synonyms | benzyl oxide Benzyl Ether Dibenzyl Ether plastikator ba ba (plasticizer) BA (Plasticizer) Tribenoside impurity D [(Benzyloxy)methyl]benzene 1,1'-oxybis(methylene-benzen 1,1-oxybismethylene, bisbenzene 1,1'-(oxydimethanediyl)dibenzene 1,1'-(oxybis(methylene))bis-benzen 1,1'-[oxybis(methylene)]bis-benzen 1,1-[oxybis(methylene)]bis[benzene] 1,1'-[oxybis(methylene)]bis-Benzene 1,1'-(Oxybis (methylene))bis-benzene |
| CAS | 103-50-4 |
| EINECS | 203-118-2 |
103-50-4 - Physico-chemical Properties
| Molecular Formula | C14H14O |
| Molar Mass | 198.26 |
| Density | 1.043g/mLat 25°C(lit.) |
| Melting Point | 1.5-3.5°C(lit.) |
| Boling Point | 298°C(lit.) |
| Flash Point | 275°F |
| JECFA Number | 1256 |
| Water Solubility | insoluble |
| Solubility | 42mg/l insoluble |
| Appearance | Liquid |
| Color | Clear colorless to pale yellow |
| Merck | 14,1132 |
| BRN | 1911156 |
| Storage Condition | 2-8°C |
| Stability | Stable. Combustible. Incompatible with strong acids, strong oxidizing agents. |
| Refractive Index | n20/D 1.562 |
| Physical and Chemical Properties | Colorless to light yellow oily liquid, with light almond aroma and mushroom aroma and earthen flavor. Unstable. Melting point 5 °c. Boiling point 298 °c. Flash point 135 °c. Soluble in most organic solvents, very soluble in ethanol, insoluble in water. |
| Use | It is used as a plasticizer for gas chromatography and nitrocellulose, and also used for the preparation of spices |
103-50-4 - Risk and Safety
| Risk Codes | R36/37/38 - Irritating to eyes, respiratory system and skin. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S23 - Do not breathe vapour. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | UN 3082 9/PG 3 |
| WGK Germany | 2 |
| RTECS | DQ6125000 |
| FLUKA BRAND F CODES | 9 |
| TSCA | Yes |
| HS Code | 2909 30 90 |
| Hazard Class | 9 |
| Packing Group | III |
| Toxicity | LD50 orally in Rabbit: 2500 mg/kg |
103-50-4 - Reference Information
| FEMA | 2371 | DIBENZYL ETHER |
| relative polarity | 3.3 |
| LogP | 3.31 |
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Application | dibenzyl ether can be used as a toughening agent for nitrocellulose and a solvent for the preparation of flavors, it can also be used as a medium-level antioxidant. It can also be used as a solvent for cellulose nitrate, a plasticizer for cellulose acetate, a resin, a rubber, a wax, an artificial musk, and the like. The mixture of dibenzyl ether and zinc oxide is a repellent for mosquitoes, flies, flies and fleas. |
| preparation method | dibenzyl ether can be obtained from the reaction of benzyl chloride with concentrated alkali, and is also a by-product in the production of benzyl alcohol. |
| content analysis | The measurement was performed by a method using a non-polarized column in gas chromatography (GT-10-4). |
| toxicity | GRAS(FEMA). LD502500 mg/kg (rat, oral). |
| usage limit | FEMA(mg/kg): Soft drink 8.3; Cold drink 5.6; Candy 23; Baked goods 25; pectin 85~160. Moderate limits (FDA § 172.515,2000). |
| Use | flavor. Mainly used for the preparation of mushrooms and cherry flavor. used as gas chromatography stationary liquid and nitrocellulose plasticizer, also used in the preparation of spices used as a medium level antioxidant, mainly used in the manufacture of sponge rubber products, can also be used for the preparation of spices |
| production method | a by-product from the hydrolysis of benzyl chloride to produce benzyl alcohol, such as the replacement of carbonate with concentrated alkali in this reaction, the yield can then be increased to 50% or more. |
| category | flammable liquid |
| toxicity grade | poisoning |
| Acute toxicity | oral-rat LD50: 2500 mg/kg |
| stimulation data | Skin-rabbits 500 mg/24 h mild; eye-rabbit 500 mg/24 h mild |
| explosive hazard characteristics | reactive with oxidant; Self-explosive |
| flammability hazard characteristics | flammability under heat and open fire; Combustion-induced smoke; the high concentration of steam on human anesthesia |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; It is stored separately from the oxidant |
| extinguishing agent | dry powder, carbon dioxide |
| spontaneous combustion temperature | 470°C |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 15:16:45
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