10311-61-2
N,N'-Di-(4-methyl-phenyl)-benzidine
CAS: 10311-61-2
Molecular Formula: C26H24N2
10311-61-2 - Names and Identifiers
| Name | N,N'-Di-(4-methyl-phenyl)-benzidine |
| Synonyms | K0067 N,N'-Di-p-tolylbenzidine N,N'-Bis(4-methylphenyl)benzidine N'-Di-(4-methyl-phenyl)-benzidine N,N'-Di-(4-methyl-phenyl)-benzidine N,N'-bis(4-methylphenyl)biphenyl-4,4'-diamine N4,N4'-Di-p-tolyl-[1,1'-biphenyl]-4,4'-diaMine N,N'-Bis(4-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine |
| CAS | 10311-61-2 |
| EINECS | 1312995-182-4 |
| InChI | InChI=1/C26H24N2/c1-19-3-11-23(12-4-19)27-25-15-7-21(8-16-25)22-9-17-26(18-10-22)28-24-13-5-20(2)6-14-24/h3-18,27-28H,1-2H3 |
10311-61-2 - Physico-chemical Properties
| Molecular Formula | C26H24N2 |
| Molar Mass | 364.48 |
| Density | 1.141 |
| Melting Point | 240 °C |
| Boling Point | 562.5±45.0 °C(Predicted) |
| Flash Point | 355.6°C |
| Vapor Presure | 1.12E-12mmHg at 25°C |
| Appearance | powder to crystal |
| Color | White to Light yellow |
| pKa | 1.83±0.50(Predicted) |
| Storage Condition | Keep in dark place,Inert atmosphere,Room temperature |
| Refractive Index | 1.669 |
| MDL | MFCD09833311 |
10311-61-2 - Reference Information
| Use | N,N'-di-p-tolylbenzidine is used as a research compound. It is a commonly used hole transport layer material in organic electroluminescent devices. |
| Preparation | Using p-methylaniline and p-iodide biphenyl as starting materials, the organic electroluminescent material N,N'-dim-tolylbenzidine was synthesized through a two-step reaction. Through the optimization experiment, the best synthesis process was obtained as follows: p-methylaniline was reacted at 20 ℃ with (glacial acetic acid):(water) = 1:4 as solvent, potassium dichromate was added for reaction, after separation and purification, l8-crown_6 phase transfer catalyst was added, o-dichlorobenzene was used as solvent to carry out Ullman reaction with p-iodide biphenyl under nitrogen protection, and the product was reacted under reflux for 20h. The product was purified by column chromatography and recrystallization. The preparation reaction formula of N,N'-di-m-toluidine is as follows: fig. 1N,N'-di-m-toluidine preparation reaction formula experimental operation main reagents and instruments p-methylaniline, p-iodide biphenyl, potassium dichromate, electrolytic copper powder, 18-crown-I5, thin layer chromatography test paper, etc. are all commercially available AR or CP. Italian CARLOERBA1106 element analyzer, Japanese Ricoh 200SXV Fourier infrared spectrometer, Japanese JEOLFx-90Q nuclear magnetic resonance instrument, American Waters515HPLCPump series high pressure liquid chromatograph, Sichuan University XRC-1 micro melting point tester, DF-101 heat-collecting constant temperature magnetic stirrer, reflux reaction device, column chromatography device, etc. |
Last Update：2024-04-10 22:29:15
Supplier List
Product Name: N,N'-Di-p-tolylbenzidine Visit Supplier Webpage Request for quotation
CAS: 10311-61-2
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
CAS: 10311-61-2
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
Product Name: N,N'-Di-p-tolylbenzidine Visit Supplier Webpage Request for quotation
CAS: 10311-61-2
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
CAS: 10311-61-2
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
View History