104-03-0
4-Nitrophenyl acetic acid
CAS: 104-03-0
Molecular Formula: C8H7NO4
104-03-0 - Names and Identifiers
| Name | 4-Nitrophenyl acetic acid |
| Synonyms | RARECHEM AL BO 0237 4-Nitrobenzencacetic 4-NITRO-A-TOLUIC ACID (4-nitrophenyl)acetate LABOTEST-BB LT00032156 4-Nitrophenylessigsαure (p-Nitophenyl)aceticacid p-Nitrophenylacetic acid 4-NITROPHENYLACETIC ACID 4-nitro-benzeneaceticaci 4-Nitrophenylacetic acid (p-nitrophenyl)-aceticaci 4-Nitrophenyl acetic acid 4-NITROBENZENEACETIC ACID (4-nitrophenyl)acetic acid NITROPHENYLACETIC ACID(4-) 2-(p-nitrophenyl)aceticacid paraNitro Phenyl Acetic Acid 2-(4-NITROPHENYL)ACETIC ACID |
| CAS | 104-03-0 |
| EINECS | 203-168-5 |
| InChI | InChI=1/C8H7NO4/c10-8(11)5-6-1-3-7(4-2-6)9(12)13/h1-4H,5H2,(H,10,11)/p-1 |
| InChIKey | YBADLXQNJCMBKR-UHFFFAOYSA-N |
104-03-0 - Physico-chemical Properties
| Molecular Formula | C8H7NO4 |
| Molar Mass | 181.15 |
| Density | 1.4283 (rough estimate) |
| Melting Point | 150-155°C(lit.) |
| Boling Point | 314.24°C (rough estimate) |
| Flash Point | 171.6°C |
| Water Solubility | slightly soluble |
| Vapor Presure | 2.26E-06mmHg at 25°C |
| Appearance | yellowish-like powder |
| Color | Beige to yellow |
| Merck | 14,6621 |
| BRN | 1911801 |
| pKa | 3.85(at 25℃) |
| PH | 2.98 at 22.8℃ and 10g/L |
| Storage Condition | Sealed in dry,Room Temperature |
| Refractive Index | 1.5468 (estimate) |
| MDL | MFCD00007383 |
| Physical and Chemical Properties | Melting point 153-156°C water-soluble |
| Use | Mainly used in medicine and other organic synthesis, can also be used for biochemical research |
104-03-0 - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37/39 - Wear suitable gloves and eye/face protection |
| UN IDs | UN 3077 9 / PGIII |
| WGK Germany | 3 |
| RTECS | AJ1130010 |
| TSCA | Yes |
| HS Code | 29163900 |
| Hazard Note | Irritant |
| Toxicity | dnr-bcs 500 mg/disc MUREAV170,11,86 |
104-03-0 - Reference
| Reference Show more | 1. Jia, Bing Jie, et al. "Detection of chloramphenicol in meat with a chemiluminescence resonance energy transfer platform based on molecularly imprinted graphene." Analytica chimica acta 1063 (2019): 136-143.https://doi.org/10.1016/j.aca.2019.02.044 2. [IF=6.558] Bing Jie Jia et al."Detection of chloramphenicol in meat with a chemiluminescence resonance energy transfer platform based on molecularly imprinted graphene."Anal Chim Acta. 2019 Jul;1063:136 |
104-03-0 - Introduction
Soluble in hot water, ethanol, chloroform, ether and benzene, slightly soluble in water.
Last Update：2022-10-16 17:11:40
104-03-0 - Reference Information
| LogP | 0.3 at 30℃ and pH7.72 |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| use | for organic synthesis. Mainly used in medicine and other organic synthesis, and can also be used for biochemical research |
| production method | obtained by hydrolysis of p-nitrophenylacetonitrile. Mixed p-nitrophenylacetonitrile, concentrated sulfuric acid and water, heated and refluxed for 15min. Then pour the reactants into ice water, precipitate crystallization, filter, wash the filter cake with ice water, and then recrystallize with water to obtain p-nitrophenylacetic acid. The yield is over 92%. |
Last Update：2024-04-09 19:05:09
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