Name | Glutaric anhydride |
Synonyms | utaric anhydride Glutamic Anhydride Glutaric anhydride GLUTARIC ANHYDRIDE pure Dihydro-pyran-2,6-dione 1,5-Glutaric anhydride TETRAHYDROPYRAN-2,6-DIONE Tetrahydropyran-2,6-dione Tetrahydro-2H-pyran-2,6-dione Dihydro-2H-pyran-2,6(3H)-dione 3,4-Dihydro-2H-pyran-2,6(5H)-dione |
CAS | 108-55-4 |
EINECS | 203-593-6 |
InChI | InChI=1/C5H6O3/c6-4-2-1-3-5(7)8-4/h1-3H2 |
InChIKey | VANNPISTIUFMLH-UHFFFAOYSA-N |
Molecular Formula | C5H6O3 |
Molar Mass | 114.1 |
Density | 1,411 g/cm3 |
Melting Point | 50-55 °C (lit.) |
Boling Point | 150 °C/10 mmHg (lit.) |
Flash Point | >230°F |
Water Solubility | hydrolysis |
Solubility | Soluble in ether, ethanol, chloroform, benzene, toluene, acetone and tetrahydrofuran. |
Vapor Presure | 0.05 hPa (50 °C) |
Appearance | White crystal |
Color | White to off-white |
BRN | 110051 |
Storage Condition | Store below +30°C. |
Sensitive | Moisture Sensitive |
Refractive Index | 1.4630 (estimate) |
MDL | MFCD00006679 |
Physical and Chemical Properties | character needle-like crystals. |
Use | Mainly used for the production and preparation of rubber, plastic, resin, medicine, etc |
Hazard Symbols | Xn - Harmful |
Risk Codes | R21/22 - Harmful in contact with skin and if swallowed. R37/38 - Irritating to respiratory system and skin. R41 - Risk of serious damage to eyes R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/39 - S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S36 - Wear suitable protective clothing. |
UN IDs | 3261 |
WGK Germany | 3 |
RTECS | MA3850000 |
FLUKA BRAND F CODES | 2-21 |
TSCA | Yes |
HS Code | 29171990 |
Hazard Class | 8 |
Packing Group | Ⅲ |
Reference Show more | 1. [IF=7.514] Ting Zhang et al."Anhydride structures affect the acylation modification and emulsion stabilization ability of mammalian and fish gelatins."Food Chem. 2022 May;375:131882 |
needle-like crystals. Melting point 41~56 deg C. Boiling point 287 °c. The relative density was 1.429. Soluble in ether, ethanol and tetrahydrofuran. Glutaric acid is formed after water absorption.
used in the production of plastics, rubber, gums, pharmaceuticals and the preparation of amides.
NIST chemical information | Information provided by: webbook.nist.gov (external link) |
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
use | mainly used for the production and preparation of rubber, plastic, resin, medicine, etc. used for the production of plastic, rubber, resin, medicine, etc. and the preparation of amide. Valeric anhydride is oxidized with hydrogen peroxide to obtain glutaric acid peroxide. Stir and mix 420ml of distilled water with 221.7g of 30% hydrogen peroxide, add 342g of glutaric anhydride, stir vigorously, maintain the reaction at 15 ℃, add 7.6g of hydrogen peroxide, continue to keep the temperature for 1 hour, stand for 24 hours, filter out crystals, wash with water, and dry with an infrared lamp to obtain white powder, peroxidation to diacid, melting point 89-90 ℃ (decomposition starts at 90 ℃). |
production method | 1. dehydrating glutaric acid with dehydrating agent such as hepatitis B. 2. Heat and mix dicarboxylic acids (succinic acid, glutaric acid, adipic acid) to directly dehydrate succinic acid and glutaric acid, and take a fraction at a certain temperature to obtain glutaric anhydride. |
spontaneous combustion temperature | 320°C |