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12042-91-0

ALUMINUM CHLOROHYDRATE

CAS: 12042-91-0

Molecular Formula: AlClH5O-

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12042-91-0 - Names and Identifiers

Name ALUMINUM CHLOROHYDRATE
Synonyms aluminum
pentahydrate
CHLORHYDROL(R)
chloroaluminum
MACROSPHERICAL(R) 95
POLYALUMINUM CHLORIDE
aluminum hydrochloride
ALUMINUM CHLOROHYDRATE
aluminum chloride oxide
BASIC ALUMINUM CHLORIDE
Aluminum hydroxychloride
ALUMINUM CHLOROHYDROXIDE
aluminum chloride hydroxide
ALUMINUM HYDROXYCHLORIDE, DIHYDRATE
ALUMINUM CHLOROHYDROXIDE, DIHYDRATE
CAS 12042-91-0
EINECS 234-933-1
InChI InChI=1/Al.ClHO/c;1-2/h;2H/q+3

12042-91-0 - Physico-chemical Properties

Molecular FormulaAlClH5O-
Molar Mass83.47
Density1.95[at 20℃]
Vapor Presure0.001Pa at 20℃
Storage ConditionRT, dry
Physical and Chemical PropertiesIt is an inorganic polymer compound, which is a product between aluminum chloride and aluminum hydroxide. It is bridged by hydroxyl groups, and the number of hydroxyl groups in the molecule is different. Colorless or yellow resinous solid. Its solution is a colorless or yellow-brown transparent liquid, sometimes containing impurities and gray-black mucus. The alumina content in the liquid product is more than 8%, and the alumina content in the solid product is 20% ~ 40%. It has strong bridging adsorption performance and is soluble in water. The hydrolysis process is accompanied by electrochemical, coagulation, adsorption and precipitation and other physical and chemical processes. Corrosive.
UseIs a flocculant, mainly used for the purification of drinking water and water special water quality treatment, such as iron, fluoride, cadmium, in addition to radioactive pollution, in addition to floating oil. Also used for industrial wastewater treatment, such as printing and dyeing wastewater. In addition, it is also used for precision casting, medicine, paper rubber, leather, petroleum, chemical, dye.

12042-91-0 - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
Overview Hydroxyl chloride (ACH) is a complex basic aluminum chloride, which is widely used as an antiperspirant active substance in axillary products, especially aerosol-type products.
use is a flocculant, which is mainly used for purifying drinking water and special water quality treatment of water supply, such as iron removal, fluorine removal, cadmium removal, radioactive pollution removal, floating oil removal, etc. It is also used for industrial wastewater treatment, such as printing and dyeing wastewater. In addition, it is also used in precision casting, medicine, papermaking rubber, leather making, petroleum, chemical industry, and dyes.
production method aluminum ash hydrochloric acid aluminum ash is the slag and floating skin produced during the smelting and refining process of smelting alloy or waste aluminum, and its main components are aluminum oxide and metal aluminum. First, the washing water is added to the reactor, then aluminum ash is added according to a certain ratio, hydrochloric acid is slowly added under stirring for polycondensation reaction, and the curing polymerization is made to pH4.2 ~ 4.5. When the relative density of the solution is about 1.2, the liquid polymeric aluminum chloride is prepared. Liquid products are diluted and filtered, evaporated and concentrated, and dried to produce solid polyaluminum chloride products. Its A12O3 + 6HCI + 3H2O → 2 AlC13 · 6H2O2A12C13 · 6H2O → A12(OH)nC16-n +(12-n)H2O + nHClmAl2(OH)nC16-n + mxH2O →[A12(OH)nC16-n · xH2O]m boiling pyrolysis method carries out boiling pyrolysis of crystalline aluminum chloride at 170 ℃, the released hydrogen chloride is absorbed with water to make 20% hydrochloric acid recovery, and then water is added to carry out curing polymerization above 60 ℃, after curing, drying and crushing, a solid polyaluminum chloride finished product is produced. Its 2A1C13 · 6H2O → A12(OH)nC16-n +(12-n)H2O + nHClmAl2(OH)nC16-n + mxH2O →[A12(OH)nC16-n · xH2O]m
category toxic substances
stimulation data skin-human 150 mg/3 days mild
flammability hazard characteristics Decomposition of toxic chloride smoke when heated
storage and transportation characteristics warehouse ventilation and low temperature drying
fire extinguishing agent dry powder, foam, sand, carbon dioxide; mist water
occupational standard TWA 2 mg (aluminum)/m3
Last Update:2024-04-10 22:41:30
12042-91-0
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Tel: 18301782025
Email: 3008007409@qq.com
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