138124-32-0

138124-32-0 - Names and Identifiers

Name	(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-Butylsalicylidene)-1,2-Cyclohexanediamino-manganese(III) chloride
Synonyms	(S,S)-Jacobsencat. JACOBSEN'S CATALYST (R,R)-JACOBSEN CATALYST (S,S)-JACOBSEN CATALYST (R,R)-JACOBSEN'S CATALYST (S,S)-JACOBSEN'S CATALYST (-)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- (R,R)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX (S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX (+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO-HEXANEDIAMINO-MN CL (+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL-IDENE)-1,2-Cyclohexanediamino-MN-CL (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL (S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco (S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo (R,R)-(-)-N,N'-BIS(3.5-DI-T-Butylsalicylidene)-1,2-CYCLOHEXANEDIAMINE-manganese (III) chloride (1R,2R)-(-)-[1,2-Cyclohexanediamino-N N'-BIS(3,5-DI-T-Butylsalicylidene)]MANGANESE(III)CHLORIDE (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-Butylsalicylidene)-1,2-Cyclohexanediamino-manganese(III) chloride (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-Butylsalicylidene)-1,2-Cyclohexanediamino-MANGANESE(III) CHLORIDE (S,S)-(+)-N,N'-Bis(3,5-Di-Tert-Butylsalicylidene)-1,2-Cyclohexanediamino-Manganese(Iii) Chloride (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]manganese (III) chloride (1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride (1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride (1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.
CAS	138124-32-0 135620-04-1
InChI	InChI=1/C36H54N2O2.3ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;;;/h17-22,29-30,39-40H,13-16H2,1-12H3;3*1H;/q;;;;+3/p-3/b37-21+,38-22+;;;;/t29-,30-;;;;/m0..../s1
InChIKey	VGAJDQCIDNCJQC-JINVCYSXSA-K

138124-32-0 - Physico-chemical Properties

Molecular Formula	C36H52ClMnN2O2
Molar Mass	635.2
Melting Point	330-332°C(lit.)
Appearance	Powder
Color	brown
Storage Condition	Inert atmosphere,Room Temperature
Physical and Chemical Properties	WGK Germany:3

138124-32-0 - Risk and Safety

Hazard Symbols	Xi - Irritant
Risk Codes	R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany	3
FLUKA BRAND F CODES	9
HS Code	29310099

138124-32-0 - Reference Information

Use

Salen(Mn)-catalyzed asymmetric epoxidation of non-functionalized olefins. High enantioselectivity and yields of various substrates, in particular cis-olefins, are obtained. Some uses include the synthesis of paclitaxel side chains and cis-1-amino-2-indanol. Jacobsen catalysts are also used for the asymmetric α-hydroxylation of silanol ethers. Catalysts for the asymmetric epoxidation of various olefins.

Last Update：2024-04-09 15:16:40