162291-02-3

162291-02-3 - Names and Identifiers

Name	(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenylethyl]dicyclohexylphosphine
Synonyms	(S)-(R)-Josiphos JOSIPHOS SL-J001-2 (S)1[(1R)2(diphenylphosphino)ferrocenyl] et-dicyclohexylphos (S)-1-[(1R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine (S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenylethyl]dicyclohexylphosphine (2S)-1-[(1S)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene cyclopentane,dicyclohexyl-[(1S)-1-(2-diphenylphosphanylcyclopentyl)ethyl]phosphane,iron (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct (S)-(R)-JOSIPHOS
CAS	162291-02-3
InChI	InChI=1/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m0../s1

162291-02-3 - Physico-chemical Properties

Molecular Formula	C36H44FeP210*
Molar Mass	594.53
Specific Rotation(α)	+360° (c 0.5, CHCl3)
Appearance	Powder
Color	orange
Storage Condition	under inert gas (nitrogen or Argon) at 2-8°C
Stability	store cold
MDL	MFCD00800285

162291-02-3 - Risk and Safety

Risk Codes	36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany	3
FLUKA BRAND F CODES	10
HS Code	29319090

162291-02-3 - Preparation solution concentration reference

	1mg	5mg	10mg
1 mM	1.682 ml	8.41 ml	16.82 ml
5 mM	0.336 ml	1.682 ml	3.364 ml
10 mM	0.168 ml	0.841 ml	1.682 ml
5 mM	0.034 ml	0.168 ml	0.336 ml

Last Update：2024-01-02 23:10:35

162291-02-3 - Reference Information

Use

(S)-( )-1-[(R)-2-(diphenylphosphine) ferrocene] ethyl dicyclic hexylphosphine is a kind of Josiphos chiral ferrocene phosphine ligand, is a very practical and important ligand, its pioneering is second only to BINAP ligand, it can be used in asymmetric organic synthesis reactions such as asymmetric hydroamination of olefins and Michael addition. It has been widely used in industrial production and plays an important role in the synthesis of many drugs and fine chemicals.

Last Update：2024-04-10 22:29:15