Name | Allylmagnesium bromide |
Synonyms | Allylmagnesium bromide bromo(prop-2-en-1-yl)magnesium prop-2-en-1-ylmagnesium(1+) bromide |
CAS | 1730-25-2 |
EINECS | 217-046-4 |
InChI | InChI=1/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1/rC3H5Mg.BrH/c1-2-3-4;/h2H,1,3H2;1H/q+1;/p-1 |
InChIKey | FEMBXICCJNZMMC-UHFFFAOYSA-M |
Molecular Formula | C3H5BrMg |
Molar Mass | 145.281 |
Density | 0.851 g/mL at 25 °C |
Flash Point | −40 °F |
Appearance | Yellow-green or gray solution |
Storage Condition | Refrigerator |
Stability | air sensitive, moisture sensitive |
Use | Allylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize: 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine tarchonanthuslactone (+)-preussin polyhydroxylated quinolizidine alkaloids |
Risk Codes | R12 - Extremely Flammable R14 - Reacts violently with water R15 - Contact with water liberates extremely flammable gases R19 - May form explosive peroxides R22 - Harmful if swallowed R34 - Causes burns R66 - Repeated exposure may cause skin dryness or cracking R67 - Vapors may cause drowsiness and dizziness R11 - Highly Flammable |
Safety Description | S9 - Keep container in a well-ventilated place. S16 - Keep away from sources of ignition. S29 - Do not empty into drains. S33 - Take precautionary measures against static discharges. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
UN IDs | UN 3399 4.3/PG 1 |
WGK Germany | 1 |
FLUKA BRAND F CODES | 1-3-10 |
HS Code | 29319090 |
Hazard Class | 8 |
Packing Group | III |
density 0.851g/mL at 25 c
Flash point & minus;40 °F
Storage condition Refrigerator
Morphological Solution
Color Yellow-green or gray
Sensitivity air sensitive, moisture sensitive
BRN 969335
InChIKey FEMBXICCJNZMMC-UHFFFAOYSA-M
Use Grignard reagent
security information
Dangerous goods mark f, c, f
Hazard category code 12-14/15-19-22-34-66-67-11
Safety instructions 9-16-29-33-43-45-36/37/39-26
Dangerous goods transportation number UN 3399 4.3/PG 1
WGK Germany 1
F 1-3-10
HazardClass 8
PackingGroup III
Customs code 29319090