2-(DIPHENYLPHOSPHINO)PYRIDINE
Diphenyl-2-pyridylphosphine
CAS: 37943-90-1
Molecular Formula: C17H14NP
2-(DIPHENYLPHOSPHINO)PYRIDINE - Names and Identifiers
| Name | Diphenyl-2-pyridylphosphine |
| Synonyms | DPPPy DPPPy 2-Pyridyldiphenylphosphine DIPHENYL-2-PYRIDYLPHOSPHINE Diphenyl-2-pyridylphosphine 2-(DIPHENYLPHOSPHINO)PYRIDINE 2-(Diphenylphosphino)pyridine 2-(diphenylphosphanyl)pyridine Diphenyl(2-pyridinyl)phosphine |
| CAS | 37943-90-1 |
| EINECS | 629-049-1 |
| InChI | InChI=1/C17H14NP/c1-3-9-15(10-4-1)19(16-11-5-2-6-12-16)17-13-7-8-14-18-17/h1-14H |
| InChIKey | SVABQOITNJTVNJ-UHFFFAOYSA-N |
2-(DIPHENYLPHOSPHINO)PYRIDINE - Physico-chemical Properties
| Molecular Formula | C17H14NP |
| Molar Mass | 263.27 |
| Melting Point | 82-84 °C (dec.) (lit.) |
| Boling Point | 163 °C(Press: 0.05 Torr) |
| Flash Point | 182.1°C |
| Solubility | Soluble in toluene. (almost transparency) |
| Vapor Presure | 1.46E-05mmHg at 25°C |
| Appearance | Yellow to or orange crystalline powder |
| Color | White to yellow to tan |
| pKa | 2.37±0.12(Predicted) |
| Storage Condition | Inert atmosphere,Room Temperature |
| MDL | MFCD00192108 |
2-(DIPHENYLPHOSPHINO)PYRIDINE - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. |
| WGK Germany | 3 |
| HS Code | 29333990 |
2-(DIPHENYLPHOSPHINO)PYRIDINE - Introduction
Diphenyl-2-pyridylphosphine is an organophosphorus compound with the chemical formula C17H14NP. It is a colorless crystalline solid, soluble in organic solvents. Here are some of its properties and uses:
Nature:
1. Diphenyl-2-pyridylphosphine is an inorganic alkaline molecule, which can provide a lone pair of electrons as a ligand to form a complex with metal ions.
2. It is unstable to moisture and air, and long-term exposure to the air should be avoided.
Use:
1. Diphenyl-2-pyridylphosphine is a ligand commonly used in organic synthesis, especially for metal-catalyzed reactions. It can form stable coordination compounds with transition metals and participate in a variety of catalytic reactions, such as hydrogenation, hydrogen transfer, coupling, carbonylation and so on.
2. It can also be used in the research and synthesis of metal organic chemistry.
Preparation Method:
Diphenyl-2-pyridylphosphine are usually synthesized by the following steps:
1. First, acetophenone reacts with H3PO2 to generate an alcohol intermediate.
2. Subsequently, the alcohol intermediate reacts with phosgene in the presence of hydrochloric acid to generate Diphenyl-2-pyridylphosphine.
Safety Information:
1. Diphenyl-2-pyridylphosphine should be careful to avoid contact with air and moisture during operation and storage to avoid oxidation and degradation.
2. it may be toxic and irritating to the human body, when in use should wear protective gloves, glasses and clothing, to ensure good ventilation conditions.
3. waste should be handled in accordance with the provisions of the general chemical waste treatment, to avoid pollution to the environment.
Nature:
1. Diphenyl-2-pyridylphosphine is an inorganic alkaline molecule, which can provide a lone pair of electrons as a ligand to form a complex with metal ions.
2. It is unstable to moisture and air, and long-term exposure to the air should be avoided.
Use:
1. Diphenyl-2-pyridylphosphine is a ligand commonly used in organic synthesis, especially for metal-catalyzed reactions. It can form stable coordination compounds with transition metals and participate in a variety of catalytic reactions, such as hydrogenation, hydrogen transfer, coupling, carbonylation and so on.
2. It can also be used in the research and synthesis of metal organic chemistry.
Preparation Method:
Diphenyl-2-pyridylphosphine are usually synthesized by the following steps:
1. First, acetophenone reacts with H3PO2 to generate an alcohol intermediate.
2. Subsequently, the alcohol intermediate reacts with phosgene in the presence of hydrochloric acid to generate Diphenyl-2-pyridylphosphine.
Safety Information:
1. Diphenyl-2-pyridylphosphine should be careful to avoid contact with air and moisture during operation and storage to avoid oxidation and degradation.
2. it may be toxic and irritating to the human body, when in use should wear protective gloves, glasses and clothing, to ensure good ventilation conditions.
3. waste should be handled in accordance with the provisions of the general chemical waste treatment, to avoid pollution to the environment.
Last Update：2024-04-10 22:29:15
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View History
2-(DIPHENYLPHOSPHINO)PYRIDINE
Octan-3-One
三乙基氢硼化钾
(2-溴-5-氯苯基)(甲基)硫烷
4-(TRIBUTYLSTANNYL)TOLUENE
YF-PI 907
POTASSIUM ANTIMONATE, HYDRATED
[(2-氯-5-硝基苯基)甲基](甲基)胺盐酸盐
3-Nitro-4-chlorobenzoic acid chloride
Octan-3-One
三乙基氢硼化钾
(2-溴-5-氯苯基)(甲基)硫烷
4-(TRIBUTYLSTANNYL)TOLUENE
YF-PI 907
POTASSIUM ANTIMONATE, HYDRATED
[(2-氯-5-硝基苯基)甲基](甲基)胺盐酸盐
3-Nitro-4-chlorobenzoic acid chloride