2-Benzothiazolyl-N-morpholinosulfide
2-(4-Morpholinothio)-benzothiazole
CAS: 102-77-2
Molecular Formula: C22H22N4O2S3
2-Benzothiazolyl-N-morpholinosulfide - Names and Identifiers
2-Benzothiazolyl-N-morpholinosulfide - Physico-chemical Properties
| Molecular Formula | C22H22N4O2S3 |
| Molar Mass | 252.36 |
| Density | 1.4g/cm3 |
| Melting Point | 78-80℃ |
| Boling Point | 449.2°C at 760 mmHg |
| Flash Point | 225.5°C |
| Vapor Presure | 2.92E-08mmHg at 25°C |
| pKa | 1.05±0.10(Predicted) |
| Storage Condition | Sealed in dry,2-8°C |
| Refractive Index | 1.703 |
| MDL | MFCD00022870 |
| Physical and Chemical Properties | Density 1.34-1.40 melting point 78-80°C |
| Use | It is used as a fast vulcanization accelerator with good aftereffect, with long burning time and good operation safety. |
2-Benzothiazolyl-N-morpholinosulfide - Risk and Safety
| Risk Codes | R22 - Harmful if swallowed R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R43 - May cause sensitization by skin contact R36/38 - Irritating to eyes and skin. |
| Safety Description | S20/21 - S36 - Wear suitable protective clothing. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S37 - Wear suitable gloves. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S24 - Avoid contact with skin. S24/25 - Avoid contact with skin and eyes. |
| UN IDs | 3077 |
| RTECS | DL5950000 |
| HS Code | 29342000 |
| Hazard Class | 9 |
| Packing Group | III |
| Toxicity | LD50 orl-rat: 1980 mg/kg IPSTB3 3,93,76 |
2-Benzothiazolyl-N-morpholinosulfide - Upstream Downstream Industry
| Raw Materials | Sodium hypochlorite 2-Mercaptobenzothiazole Chlorine Morpholine Sodium hydroxide Hydrochloric acid |
| Downstream Products | 4-(2-BENZOTHIAZOLYLDITHIO)MORPHOLINE |
2-Benzothiazolyl-N-morpholinosulfide - Nature and use
Chemical properties light yellow to brown flake crystals. Soluble in dichloromethane, acetone, soluble in benzene, carbon tetrachloride, ethyl acetate, ethanol, slightly soluble in gasoline, insoluble in water.
Use after-effect rapid vulcanization accelerator.
Use as a quick after-effect vulcanization accelerator, long scorching time, good operation safety
It is used as a aftereffect vulcanization accelerator, with low activity, large deductility, short vulcanization time, excellent scorch resistance, safe processing, easy to disperse, no frost spraying, slight discoloration, and suitable for natural rubber and synthetic rubber. Mainly used in the manufacture of industrial rubber products such as tires, hoses, rubber shoes, and conveyor belts.
Last Update：2024-04-10 22:29:15
2-Benzothiazolyl-N-morpholinosulfide - Production methods and safety information
| production method | The accelerator M is added to the morpholine aqueous solution, and sodium hypochlorite is added dropwise at 23-56°C for oxidation reaction to obtain the semi-finished product, and then filtered, washed with water, and dried to obtain the finished product. Raw material consumption (kg/t) accelerator m (97%) 840 morpholine (60%) 700 chlorine (95%) 478 caustic soda (40%) 4251 sulfuric acid (95%) 1170 |
| category | toxic substances |
| toxicity classification | Poisoning |
| acute toxicity | oral-rat LD50: 1980 mg/kg; Oral-mouse LD50: 1870 mg/kg |
| Stimulus data | eyes-rabbit 100 mg/24 hours moderate |
| flammability hazard characteristics | Combustible; combustion produces toxic nitrogen oxides and sulfide smoke |
| storage and transportation characteristics | ventilated low temperature drying |
| fire extinguishing agent | Dry powder, foam, sand, carbon dioxide, mist water |
Last Update：2024-04-10 22:29:15
2-Benzothiazolyl-N-morpholinosulfide - Security information
| dangerous goods mark | Xi,N |
| hazard category code | 22-51/53-43-36/38 |
| safety instructions | 20/21-36-61-37-26-24-24/25 |
| dangerous goods transport number | 3077 |
| RTECS number | DL5950000 |
| HazardClass | 9 |
| PackingGroup | III |
| customs code | 29342000 |
| toxic substance data | 102-77-2(Hazardous Substances Data) |
| Toxicity | LD50 orl-rat: 1980 mg/kg IPSTB3 3,93,76 |
Last Update：2024-04-10 22:29:15
2-Benzothiazolyl-N-morpholinosulfide - Nature
| melting point | 78-80°C |
| boiling point | 413.1±55.0 °C(Predicted) |
| density | 1.34-1.40 |
| refractive index | 1.5650 (estimate) |
| storage conditions | Sealed in dry,2-8°C |
| acidity coefficient (pKa) | 1.05±0.10(Predicted) |
| EPA chemical information | Benzothiazole, 2-(4-morpholinylthio)- (102-77-2) |
Last Update：2024-04-09 20:52:54
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Product Name: 2-(4-Morpholinothio)-benzothiazole Request for quotationCAS: 102-77-2
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Spot supply
Product Name: Zileuton Impurity 10 Visit Supplier Webpage Request for quotationCAS: 102-77-2
Tel: 0714-3999186
Email: 2853786052@qq.com
Mobile: 86+15671228036
QQ: 2853786052
Wechat: 15671228036
Multiple Specifications
Product Name: 2-(Morpholinothio)benzothiazole Request for quotationCAS: 102-77-2
Tel: +86 19849939632
Email: 2470479589@qq.com
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Product Name: 2-(4-Morpholinothio)-benzothiazole Request for quotation
CAS: 102-77-2
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
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Product List: View Catalog
CAS: 102-77-2
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
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Product List: View Catalog
Spot supply
Product Name: N-Oxydiethylene-2-Benzothiazolesulfenamide Visit Supplier Webpage Request for quotationCAS: 102-77-2
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Mobile: 18021002903
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View History
Raw Materials for 2-Benzothiazolyl-N-morpholinosulfide
Downstream Products for 2-Benzothiazolyl-N-morpholinosulfide