Name | 4-Methoxy-o-phenylenediamine |
Synonyms | 3,4-Diaminoanisole 3,4-Diamino Anisole 3,4-DIAMINO ANISOLE 3,4-Diaminoanisidine Methoxyophenylenediamine 2-amino-4-methoxyphenylamine 1,2-Diamino-4-methoxybenzene 4-METHOXY-O-PHENYLENEDIAMINE 4-Methoxy-o-phenylenediamine 4-methoxybenzene-1,2-diamine 4-METHOXY-BENZENE-1,2-DIAMINE |
CAS | 102-51-2 |
EINECS | 600-319-0 |
InChI | InChI=1/C7H10N2O/c1-10-5-2-3-6(8)7(9)4-5/h2-4H,8-9H2,1H3 |
Molecular Formula | C7H10N2O |
Molar Mass | 138.17 |
Density | 1.1315 (rough estimate) |
Melting Point | 46-48°C |
Boling Point | 253.57°C (rough estimate) |
Flash Point | 161.7°C |
Solubility | Soluble in dimethyl sulfoxide and methanol. |
Vapor Presure | 0.000994mmHg at 25°C |
Appearance | Solid |
Color | Dark Brown to Black Oil to Waxy to |
Storage Condition | Keep in dark place,Inert atmosphere,2-8°C |
Sensitive | Air Sensitive |
Refractive Index | 1.5200 (estimate) |
MDL | MFCD00047837 |
Hazard Symbols | Xi - Irritant |
Risk Codes | R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
UN IDs | 2811 |
RTECS | ST2690000 |
Hazard Note | Irritant |
Hazard Class | 6.1 |
Reference Show more | 1. Hemiti Xiao Helaiti, Gao Yiting, Abdu Aizezi Elken, et al. Design, Synthesis and Anti-tumor Activity of Novel 2-Arylbenzimidazole Derivatives [J]. Northwest Journal of Pharmacy, 2020(2). |
Production method | It is obtained by reducing 3-nitro-p-carbamyl ether with iron powder. 60% acetic acid and 3-nitrop-aminoanisole were added into the reduction kettle, stirred for 0.5h, and iron powder was added. Heating to 60 ℃, heat preservation reaction until the material liquid infiltration ring is colorless is the end point, and 4-methoxyo-phenylenediamine is reduced. |