2-bromo-1-(4-methoxyphenyl)ethanone
α-Bromo-4-methoxyacetophenone
CAS: 2632-13-5
Molecular Formula: C9H9BrO2
2-bromo-1-(4-methoxyphenyl)ethanone - Names and Identifiers
| Name | α-Bromo-4-methoxyacetophenone |
| Synonyms | PTP Inhibitor II AKOS BBS-00000817 4-methoxyphenacyl br 4-METHOXYPHENACYL BR 4-(bromoacetyl)anisole 4-(BROMOACETYL)ANISOLE 4-Methoxyphenacyl bromide 4-Methoxy Phenecyl Bromide 4'-methoxyphenacyl bromide 4-methoxy phenecyl bromide 4'-METHOXYPHENACYL BROMIDE a-bromo-p-methoxyacetophenone 2-bromo-4-methoxyacetophenone α-Bromo-4-methoxyacetophenone 2-bromo-4'-methoxyacetophenone 2-Bromo-4-Methoxy Acetophenone α-bromo-paramethoxylacetophenone Alpha-Bromo-4-methoxyacetophenone ALPHA-BROMO-4-METHOXYACETOPHENONE alpha-bromo-4'-methoxyacetophenone Bromomethyl 4-methoxyphenyl ketone ALPHA-BROMO-4'-METHOXYACETOPHENONE 2-bromo-1-(4-methoxyphenyl)ethanone 2-Bromo-1-(4-methoxyphenyl)ethan-1-one |
| CAS | 2632-13-5 |
| EINECS | 220-118-8 |
| InChI | InChI=1/C9H9BrO2/c1-12-8-4-2-7(3-5-8)9(11)6-10/h2-5H,6H2,1H3 |
| InChIKey | XQJAHBHCLXUGEP-UHFFFAOYSA-N |
2-bromo-1-(4-methoxyphenyl)ethanone - Physico-chemical Properties
| Molecular Formula | C9H9BrO2 |
| Molar Mass | 229.07 |
| Density | 1.4921 (rough estimate) |
| Melting Point | 69-71°C(lit.) |
| Boling Point | 215.8°C (rough estimate) |
| Flash Point | 139.3°C |
| Water Solubility | It is soluble in DMSO, water (partly miscible), most organic solvents, and methanol. |
| Solubility | Chloroform (Slightly), Methanol (Slightly) |
| Vapor Presure | 0.00076mmHg at 25°C |
| Appearance | Crystals or Crystalline Powder |
| Color | Off-white to light brown |
| BRN | 743112 |
| Storage Condition | 2-8°C |
| Refractive Index | 1.5500 (estimate) |
| MDL | MFCD00000201 |
| Physical and Chemical Properties | Appearance: yellow-brown crystal to powder |
| Use | Used as a raw material for organic synthesis |
| In vitro study | PTP inhibitor 1 exhibits anti-angiogenic activity with an IC 50 of 3.7 μM for HUVECs. |
2-bromo-1-(4-methoxyphenyl)ethanone - Risk and Safety
| Risk Codes | R34 - Causes burns R36/37 - Irritating to eyes and respiratory system. R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27 - Take off immediately all contaminated clothing. S28 - After contact with skin, wash immediately with plenty of soap-suds. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S37/39 - Wear suitable gloves and eye/face protection |
| UN IDs | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 8-9-19-21 |
| HS Code | 29147090 |
| Hazard Note | Corrosive |
| Hazard Class | 8 |
| Packing Group | III |
2-bromo-1-(4-methoxyphenyl)ethanone - Upstream Downstream Industry
| Downstream Products | Raloxifene |
2-bromo-1-(4-methoxyphenyl)ethanone - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| use | 2-bromo-4'-methoxyacetophenone is an α-halogenated acetophenone derivative, which has been tested to inhibit protein tyrosine phosphatase SHP-1 and PTP1B. Used as raw material for organic synthesis |
| Biological activity | PTP Inhibitor II (NSC 129010, 4-(Bromoacetyl)anisole) is a protein tyrosine phosphatase (protein tyrosine phosphatase,PTP) with cell permeability Inhibitor, can covalently bind to SHP-1(ΔSH2), Ki is 128 μM. |
| Target | Value |
| SHP-1(ΔSH2) (Cell-free) | 128 μM(Ki) |
Last Update：2024-04-10 22:29:15
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View History
2-bromo-1-(4-methoxyphenyl)ethanone
METHYL FURFURYL DISULPHIDE
辛二酸二乙酯
乙酸-N-琥珀酰亚胺酯(AC-OSU)
britesilh20
4-methylacethophenone oxime
Tetramethrine
828926-06-3
ALPHA-Ketoglutaric acid dimethyl ester
pdcl2[p(tBu)2ph]2
METHYL FURFURYL DISULPHIDE
辛二酸二乙酯
乙酸-N-琥珀酰亚胺酯(AC-OSU)
britesilh20
4-methylacethophenone oxime
Tetramethrine
828926-06-3
ALPHA-Ketoglutaric acid dimethyl ester
pdcl2[p(tBu)2ph]2
Downstream Products for 2-bromo-1-(4-methoxyphenyl)ethanone