203714-71-0
dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1)
CAS: 203714-71-0
Molecular Formula: C28H45Cl2OPRu
203714-71-0 - Names and Identifiers
203714-71-0 - Physico-chemical Properties
| Molecular Formula | C28H45Cl2OPRu |
| Molar Mass | 600.61 |
| Melting Point | 195-197°C(lit.) |
| Boling Point | 383.4°C at 760 mmHg |
| Flash Point | 195.6°C |
| Vapor Presure | 9.7E-06mmHg at 25°C |
| Storage Condition | 2-8°C |
203714-71-0 - Risk and Safety
| Hazard Symbols | F - Flammable |
| Risk Codes | 11 - Highly Flammable |
| UN IDs | UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all |
| WGK Germany | 3 |
203714-71-0 - Introduction
dichloro{[2-(1-methylethoxy)phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) is an organic compound with the chemical formula [LICLIZOTH (CCHI) OCH?) C (H? CH? P(C? H)] Ru. The following is a detailed description of the properties, uses, preparation and safety information of the compound:
Nature:
-Appearance: Colorless to light yellow solid
-Density: 1.31g/cm³
-Melting point: 130-132 ° C
-Solubility: Soluble in organic solvents such as dimethylformamide and dichloromethane
Use:
- dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) is a hydrogenation catalyst, which is often used to catalyze the hydrogenation of olefins in organic synthesis.
-It can also be used as a homogeneous catalyst to play a catalytic role in reactions such as the Heterocyclic Synthesis of alkenes and indole.
-In addition, it can also catalyze the manganese carbonyl reduction reaction and benzene ring carbonylation reaction of alkynes.
Method:
dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) it is possible to combine RuCl3 · 3H ₂ O and [cl₂ (c≡halready (CH) och₂) in methylene chloride. The C (C (H)) reaction is obtained.
Safety Information:
- dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) is stable at room temperature, but contact with strong oxidants should be avoided.
-It is an organic catalyst and should be avoided by inhalation or skin contact. Wear appropriate protective equipment such as gloves and eye protection during operation.
-In case of contact, flush the affected area immediately with plenty of water and seek medical help.
-When storing and using, please follow the safety procedures and chemical storage requirements.
Nature:
-Appearance: Colorless to light yellow solid
-Density: 1.31g/cm³
-Melting point: 130-132 ° C
-Solubility: Soluble in organic solvents such as dimethylformamide and dichloromethane
Use:
- dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) is a hydrogenation catalyst, which is often used to catalyze the hydrogenation of olefins in organic synthesis.
-It can also be used as a homogeneous catalyst to play a catalytic role in reactions such as the Heterocyclic Synthesis of alkenes and indole.
-In addition, it can also catalyze the manganese carbonyl reduction reaction and benzene ring carbonylation reaction of alkynes.
Method:
dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) it is possible to combine RuCl3 · 3H ₂ O and [cl₂ (c≡halready (CH) och₂) in methylene chloride. The C (C (H)) reaction is obtained.
Safety Information:
- dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) is stable at room temperature, but contact with strong oxidants should be avoided.
-It is an organic catalyst and should be avoided by inhalation or skin contact. Wear appropriate protective equipment such as gloves and eye protection during operation.
-In case of contact, flush the affected area immediately with plenty of water and seek medical help.
-When storing and using, please follow the safety procedures and chemical storage requirements.
Last Update：2024-04-10 22:29:15
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