Name | (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) |
Synonyms | (S,S)TROST LIGAND(NAPHTHYL) (S,S)-DACH-naphthyl Trost Ligand 1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) N,N'-(1S,2S)-cyclohexane-1,2-diylbis[2-(diphenylphosphanyl)naphthalene-1-carboxamide] |
CAS | 205495-66-5 |
InChI | InChI=1/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m0/s1 |
Molecular Formula | C52H44N2O2P2 |
Molar Mass | 790.88 |
Melting Point | 232-237°C |
Specific Rotation(α) | -65.2° (c 1, CH3OH) |
Appearance | Powder |
Color | off-white |
pKa | 13.43±0.40(Predicted) |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
MDL | MFCD02684552 |
Use | Ligands for asymmetric allyl alkylation reactions. |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
WGK Germany | 3 |
use | ligand for asymmetric allylation reaction. |