Molecular Formula | Cu2S |
Molar Mass | 159.16 |
Density | 5.6 g/mL at 25 °C (lit.) |
Melting Point | 1100°C |
Water Solubility | Slightly soluble in hydrochloric acid, ammonium hydroxide. Insoluble in water. |
Appearance | powder |
Specific Gravity | 5.6 |
Color | Black |
Exposure Limit | ACGIH: TWA 1 mg/m3NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
Solubility Product Constant(Ksp) | pKsp: 47.6 |
Merck | 14,2667 |
Storage Condition | Keep in dark place,Inert atmosphere,Room temperature |
MDL | MFCD00016062 |
Physical and Chemical Properties | Cuprous sulfide, chemical formula Cu2S. Molecular weight 159.15. Black orthogonal crystals. The specific gravity was 5.60. Melting point 1,100 °c. Insoluble in water, acetone, ammonium sulfide solution, insoluble in hydrochloric acid, slightly soluble in ammonia, soluble in potassium cyanide solution. Decomposition in nitric acid and concentrated sulfuric acid. Copper and Copper sulfide are generated by heating in the absence of air, and copper oxide, copper sulfate, and sulfur dioxide are generated in the presence of air. |
Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R40 - Limited evidence of a carcinogenic effect |
Safety Description | S7 - Keep container tightly closed. S22 - Do not breathe dust. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
WGK Germany | 3 |
RTECS | GL8910000 |
TSCA | Yes |
surface tension | 72.2mN/m at 18mg/L and 20 ℃ |
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
Main use | In nature, it exists in the form of chalcocite (also called pyroite). Used as anti-fouling paint, solid lubricant, catalyst, solar cell, etc. Copper in cuprous sulfide is monovalent, and sulfur is -2. |
solubility in water (g/100ml) | dissolved grams per 100ml of water: 1.361 × 10-15/20 ℃ |
production method | 1. copper powder and sulfur are mixed in a molar ratio of 2:1, sealed in a heat-resistant glass tube under vacuum, and heated at 450 ℃ for about 1h. 2. Cu2S can be prepared by heating copper powder or copper foil to 1000 ℃ in an atmosphere with a sulfur partial pressure of 1 33 × 10-5Pa. |
category | toxic substances |
flammability hazard characteristics | non-combustible; toxic copper and sulfur oxide smoke from the fire site |
storage and transportation characteristics | warehouse low temperature, ventilation, drying |
fire extinguishing agent | water, carbon dioxide, dry powder, sand |
occupational standard | TWA 0.1 mg (copper)/m3; STEL 0.2 mg (copper)/m3 |