25549-16-0
n,n-diisooctyl-isooctanamin
CAS: 25549-16-0
Molecular Formula: C24H51N
25549-16-0 - Names and Identifiers
| Name | n,n-diisooctyl-isooctanamin |
| Synonyms | TIOA Adogen 381 Alamine 330 Hostarex 324 AZamine T 8B Tris(6-methylheptyl) forextractionofuthetc. n,n-diisooctyl-isooctanamin N,N-diisooctyl-Isooctanamine TriisooctylaMine technical grade 6-methyl-N,N-bis(6-methylheptyl)heptan-1-amine |
| CAS | 25549-16-0 |
| EINECS | 247-092-0 |
| InChI | InChI=1/C24H51N/c1-22(2)16-10-7-13-19-25(20-14-8-11-17-23(3)4)21-15-9-12-18-24(5)6/h22-24H,7-21H2,1-6H3 |
25549-16-0 - Physico-chemical Properties
| Molecular Formula | C24H51N |
| Molar Mass | 353.67 |
| Density | 0.816 g/mL at 25 °C (lit.) |
| Boling Point | >204°C |
| Flash Point | >230°F |
| Vapor Presure | 0.001Pa at 20℃ |
| Vapor Density | >1 (vs air) |
| Storage Condition | Store below +30°C. |
| Refractive Index | n20/D 1.4501(lit.) |
25549-16-0 - Risk and Safety
| Risk Codes | R36/37/38 - Irritating to eyes, respiratory system and skin. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R22 - Harmful if swallowed |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | UN 3082 9/PG 3 |
| WGK Germany | 2 |
| RTECS | YF7175000 |
| HS Code | 2921 19 99 |
| Hazard Class | 8 |
| Packing Group | III |
25549-16-0 - Reference Information
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| overview | amine extractants have high chemical stability, low price and easy availability, and can overcome phosphorus-containing and oxygen-containing extractants The shortcomings of high water solubility or poor selectivity. The amine extractant triisooctylamine has been widely used as an extractant. In addition, it can also be used as an intermediate in organic synthesis. |
| Application area | High molecular weight amines were first used as extractants by Smith and Page in the 1980s. Triisooctylamine is mainly used as extractant and organic synthesis intermediate. 1. Extraction of uranium and plutonium [4] The nuclear industry wastewater often coexists with uranium and bad, and most of them are monitored by a single determination method. However, if combined determination can be used, the number of pretreated samples can be reduced, thus saving a lot of manpower and material resources and improving monitoring efficiency. The liquid anion exchanger TIOA (triisooctylamine) has the advantages of large partition coefficient and small impurity influence ability, so it is widely used in the extraction of radioactive metal elements in nuclear waste. 2. Extraction of trace platinum [9] Studies have shown that Pd(II),Rh(III), Ir(III), Au(III) and Pt(IV) are extracted from hydrochloric acid and hydrobromic acid with 5% carbon tetrachloride solution of triisooctylamine. The extract of gold from hydrochloric acid is yellow and absorbed at 325nm. The palladium compound is red and absorbs at 290nm and 467nm. Platinum compounds are blood red and absorb at 268nm. Finally, the quantitative results show that triisooctylamine can extract platinum from waste liquid and separate it from other metals. 3. extraction of free mercury [2] Zheng Haijin et al. studied the behavior and mechanism of microemulsion separation of mercury (II) composed of nonylphenol polyoxyethylene ether (OP-10), isoamyl alcohol, cyclohexane and NaOH aqueous solution with triisooctylamine (TIOA) as carrier. The effects of carrier triisooctylamine, external phase hydrochloric acid, KBr and internal phase NaOH on the extraction rate of mercury (II) at different concentrations were investigated respectively. Studies have shown that Hg(II) can be completely separated from them in the presence of coexisting ions and the extraction behavior of each ion is basically the same as when it exists alone, so their extraction behavior in the mixture can be estimated according to the single extraction behavior of each ion. 4. extraction of gold [1,9] triisooctylamine has the advantages of strong extraction ability, low solubility in water, high enough chemical stability and gold in TIOA-toluene solution has a large distribution ratio, so it can be used to extract gold in acidic system. At the same time, TIOA-toluene system has high selectivity and good stability, so it can be used for quantitative analysis of gold content in waste liquid. |
| production method | there is no preparation process of triisooctylamine in the current public literature. |
| storage and transportation conditions | the substance is stable at normal temperature and pressure, and contact with strong oxidants is avoided during storage. Dangerous goods are packaged independently, with more than 5 liters of liquid or more than 5 kilograms of solid. EHS mark must be found on the outer package after the combination of each independent package outside and independent inner package. |
| first aid measures | inhalation: if inhaled, please move the patient to fresh air. If breathing stops, perform artificial respiration. Consult a doctor. Rinse with soap and plenty of water. Consult a doctor. Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a doctor. Intake: Never feed anything to the unconscious, rinse your mouth with water and consult a doctor. |
| References | [1] Zijinling. Extraction of Au(Ⅲ) from Hydrochloric Acid by Triisooctylamine [J]. Chemical Research and Application, 1999(02) [2] Zheng Haijin, Guan Xia, Li Quanmin, Liu Guoguang. Microemulsion Separation of Mercury (Ⅱ) with Triisooctylamine as Carrier [J]. Applied Chemistry, 2005(06) [3] Li Quanmin, Ma Quanshun, Zhang Qingfen, Liu Qi. Study on Migration and Separation of Mercury (Ⅱ) by Emulsion Membrane with Triisooctylamine as Carrier [J]. Journal of Henan Normal University (Natural Science Edition),1999(01) [4] Tan Longhua, Chen Ying, Tan Mingchun, Mou Hua. Separation and Determination of Trace Gold in Ores by High Performance Liquid Chromatography with Triisooctylamine-Silica Gel Column [J]. Analytical Chemistry, 1999(05) [5] Li Jing, Wei Xianjun, Guan Xia, Li Quanmin, Liu Guoguang. Determination of Cadmium (Ⅱ) by Microemulsion Extraction and Separation Spectrophotometry with Triisooctylamine as Carrier [J]. Physical and Chemical Examination (Chemistry Volume),2009(08) [6] Mohamed Fathi El-Shahat,Hisham Mohamed Kamal,Reda Abd El-Gawad Ghazalla,Walid Mohamed Morsy. Recovery of Uranium from High Concentration Uranium Solution with Triisooctylamine by Pulsed Extraction Column [J]. Journal of Inorganic Chemistry, 2016(08) [7] Zhao Puxiu. Determination of Gold Content by X-ray Fluorescence Spectrometry with Triisooctylamine Loaded Polyurethane Foam Enrichment [J]. Physical and chemical inspection (chemistry fascicle),2012(06) [8] Han Kai, Wang Shuzhen. Determination of Trace Zinc in Large Nickels by Triisooctylamine Extraction-Square Wave Polarography [J]. Analytical Chemistry, 1977(06) [9] M • Y • MIRZA, Yu Zugen. Study on Extraction of Platinum Group Metals from Hydrochloric Acid and Bromohydroic Acid with Triisooctylamine-Separation and Determination of Gold, Palladium and Platinum [J]. Gold, 1981(02) [10] M.Logeat, Korea Light. Complete separation of copper from cobalt by solvent extraction with triisooctylamine [J]. Hydrometallurgy, 1983(04) [11] Han Kai, Wang Shuzhen. Determination of Trace Zinc in Large Nickels by Triisooctylamine Extraction-Square Wave Polarography [J]. Chemical Metallurgy, 1983(04) |
| use | extractant. Intermediates in organic synthesis. |
Last Update：2024-04-09 20:52:54
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CAS: 25549-16-0
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Mobile: 18021002903
QQ: 3008007409
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