Name | Diacetone acrylamide |
Synonyms | DAA DAAM Diacetoneacrylamide DIACETONE ACRYLAMIDE Diacetone acrylamide Diacetone Acrylamide Diacetonyl acrylamide CmcSodiumSalt(EdifasB) N-(1,1-Dimethyl-3-oxobutyl)acrylamide N-(1,1-DIMETHYL-3-OXOBUTYL)ACRYLAMIDE N-(2-(2-Methyl-4-oxopentyl))acrylamide 2-Propenamide,N-(1,1-dimethyl-3-oxobutyl)- N-(2-methyl-4-oxopentan-2-yl)prop-2-enamide |
CAS | 2873-97-4 |
EINECS | 220-713-2 |
InChI | InChI=1/C9H15NO2/c1-5-8(12)10-9(3,4)6-7(2)11/h5H,1,6H2,2-4H3,(H,10,12) |
InChIKey | OMNKZBIFPJNNIO-UHFFFAOYSA-N |
Molecular Formula | C9H15NO2 |
Molar Mass | 169.22 |
Density | 1.0873 (rough estimate) |
Melting Point | 54-56 °C (lit.) |
Boling Point | 120 °C (8 mmHg) |
Flash Point | >230°F |
Water Solubility | soluble |
Vapor Presure | 0.109Pa at 20℃ |
Appearance | Crystallization |
Color | White to cream |
Merck | 14,2963 |
BRN | 1928444 |
pKa | 14.12±0.46(Predicted) |
Storage Condition | Inert atmosphere,Room Temperature |
Sensitive | Hygroscopic |
Refractive Index | 1.4200 (estimate) |
MDL | MFCD00008788 |
Physical and Chemical Properties | Melting point 53-57°C boiling point 120°C (8 mmHg) flash point> 110°C water-soluble soluble |
Use | Mainly used as homopolymer, widely used in coatings, good moisture resistance perm resin and spray fixative, photosensitive resin and its additives |
Hazard Symbols | Xn - Harmful |
Risk Codes | 22 - Harmful if swallowed |
Safety Description | S23 - Do not breathe vapour. S24/25 - Avoid contact with skin and eyes. |
WGK Germany | 1 |
RTECS | AS3475000 |
FLUKA BRAND F CODES | 3 |
TSCA | Yes |
HS Code | 29241990 |
Toxicity | LD50 orally in mice: 7.7 mmol/kg (Hashimoto) |
LogP | 0.321 at 21℃ |
NIST chemical information | Information provided by: webbook.nist.gov (external link) |
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
use | important vinyl monomer. The homopolymer produced by polymerization is insoluble in water, but has "water respiration". The water absorption rate can reach 20-25% of the resin's own weight, and when the ambient humidity is lower than 60%, the water absorbed by the polymer is released again, and the water plays a role of plasticizer for the polymer. Taking advantage of this peculiar nature, many uses can be developed. (1) Perm resin with good moisture resistance Japan uses it for perm resin with moisture resistance. The hairstyle is kept for a long time without deformation due to rain and washing. (2) The photosensitive resin is used as a part of the photosensitive resin raw material, which can have the following characteristics: fast photosensitive speed; After exposure, the non-image part can be easily removed and clear images can be obtained; The layout with good strength, solvent resistance and water resistance can be obtained. In addition, it can also be used as a crosslinking agent for unsaturated polyester resins, a crosslinking agent for diallyl phthalate, and a curing agent for epoxy resins, such as "water breathing" resins (contact glasses, prevent glass Fogging, boat bottom coating, etc.), pressure-sensitive adhesives, adhesive improvers, non-woven fabric adhesives, water-absorbing films, leather finishing agents and modifiers, paper strength enhancers, anti-static polymers, inks, etc. Mainly used as a homopolymer, widely used in coatings, perm resins with good moisture resistance, spray styling agents, photosensitive resins and their additives, etc. |
production method | is obtained by reacting acrylonitrile and acetone in concentrated sulfuric acid. |
toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |