Name | Tris(2,4-di-t-butylphenyl)phosphite |
Synonyms | IRGAFOS 168 Antioxidant 168 Antioxidant JX-168 Tris(2,4-di-t-butylphenyl)phosphite Tris(2,4-di-tert-butylphenyl) Phosphite |
CAS | 31570-04-4 |
EINECS | 250-709-6 |
InChI | InChI=1/C14H21O3P/c1-13(2,3)10-7-8-12(17-18(15)16)11(9-10)14(4,5)6/h7-9H,1-6H3/q-2 |
InChIKey | JKIJEFPNVSHHEI-UHFFFAOYSA-N |
Molecular Formula | C42H63O3P |
Molar Mass | 646.94 |
Melting Point | 181-184℃ |
Boling Point | 360.963°C at 760 mmHg |
Flash Point | 172.105°C |
Solubility | Acetonitrile (Slightly), Chloroform (Sparingly), Ethyl Acetate (Sparingly, Heate |
Vapor Presure | 0mmHg at 25°C |
Appearance | Powder |
Specific Gravity | 0.98 |
Color | white |
Storage Condition | 2-8°C |
Stability | moisture sensitive |
Sensitive | moisture sensitive |
MDL | MFCD00072706 |
Physical and Chemical Properties | White crystalline powder, melting point 180~186 ℃, soluble in benzene, toluene, gasoline, insoluble in water and alcohols. |
Use | Widely used in polypropylene, polyethylene, ABS, polycarbonate fiber and polyester resin and other types of plastic synthesis and processing |
TSCA | Yes |
HS Code | 2920900002 |
Reference Show more | 1. [IF=3.72] Jinlei Zeng et al."Synthesis, Monomer Removal, Modification, and Coating Performances of Biobased Pentamethylene Diisocyanate Isocyanurate Trimers."Ind Eng Chem Res. 2022;61(6):2403–2416 |
antioxidant 168 is an excellent phosphite antioxidant with white powder appearance, easily soluble in benzene, chloroform, cyclohexane and other organic solvents, slightly soluble in ethanol, acetone, insoluble in water, alcohol and other polar solvents, slightly soluble in esters. Low toxicity, low volatility, high thermal stability, excellent hydrolysis resistance, and can effectively decompose the hydroperoxide produced during the thermal processing of polymeric materials. It has good synergistic effect in 1010 and 1076 with hindered amine antioxidants and can improve the stability of polymeric materials during thermal processing. There are more than a dozen preparations compounded with phenolic antioxidants, which are widely used in polyolefins (such as polyethylene, polypropylene) and olefin copolymers, polyamide, polycarbonate, PS resin, PVC, engineering plastics, rubber and petroleum products, ABS resin and other polymer materials. The compound can also be used for adhesives, natural or synthetic adhesive resins, etc. The general dosage is 0.1% ~ 1.0%.
This product can still be fully recovered after soaking in hot water at 90±1 ℃ for 14 hours, and the quality is not affected.
Features & Uses
this product is a phosphite antioxidant, which has excellent synergistic effect when combined with the 1010 and 1076 of the main antioxidant. Its compound is widely used in polyethylene, polypropylene, polycarbonate, etc.
Store
Store in a dry and cool environment according to general chemicals. The recommended storage time is 12 months.
Stabilizer
In the storage, processing and use of polymer materials, due to the action of light, oxygen, heat and other factors, oxidative degradation often occurs, causing the material to deteriorate, causing the material to lose weather resistance and durability. In order to prolong the life of polymer materials and inhibit or delay the oxidative degradation of materials, antioxidants are usually used.
antioxidant 168 has good compatibility with resin, and has the characteristics of low volatility, high heat resistance, extraction resistance, no pollution and no discoloration. It is currently the best processing stabilizer in China. It can effectively prevent the thermal degradation of polymers (polyethylene, polypropylene, etc.) during the extrusion and injection molding process, so that the polymers maintain their original mechanical properties and aging resistance.
Antioxidant is an organic compound that can inhibit or delay the thermal oxidation of polymers and other organic compounds in the air. Usually, it is very effective to add only 1% tiny concentration of antioxidant. For example, foods are prone to oxidative deterioration, and a small amount of antioxidants can be added to extend their storage time. Polymer materials such as plastics, synthetic fibers and rubber are prone to thermal oxygen degradation reactions. Adding antioxidants can maintain the excellent performance of polymer materials and extend their service life. The antioxidant should be added closer to the aging cycle, for example, before the polymer is dried into powder.
antioxidant PL-440 is phosphite antioxidant with excellent performance. it can be used as antioxidant and heat stabilizer for polymer and is widely used in PVC, PET, ABS, polyolefin, nylon, PPO, PBT alloy, polystyrene and other polymers. It can effectively improve the light stability, processing stability, mechanical strength, color stability and transparency of the product, and extend the life of the product. PL-440 has the special effect of stabilizing the melt viscosity of polymers. This product is non-toxic and can be used for food packaging materials.
Antioxidant 565 Antioxidant 565 is a polymer multifunctional hindered phenolic antioxidant, which is mainly suitable for the post-processing and stable treatment of unsaturated rubber. It is very effective for elastomers and can protect the material from production, Processing and final use without thermal oxidation degradation. It is an excellent antioxidant and photothermal stabilizer for a variety of resins. It has the characteristics of small addition, low volatility, high color fastness, and can prevent the formation of gel.
antioxidant 1010 antioxidant 1010 is a macromolecular multifunctional hindered phenolic antioxidant, soluble in benzene, acetone, chloroform, insoluble in water. No pollution, no coloring, low volatility, good extraction resistance. It is widely used in polyethylene, polypropylene, polyoxymethylene, ABS resin, PS resin, PVC, engineering plastics, rubber and petroleum products, and has excellent oxidation resistance to polypropylene and polyethylene. It can effectively extend the service life of the product.
1.168 with auxiliary antioxidants DLTDP and antioxidants and used in polypropylene resin, it can significantly improve its thermal stability and is one of the most excellent varieties of phenolic antioxidants at present.
2. The general dosage is 0.1% ~ 0.5%. With the restriction of environmental protection laws and regulations in developed regions abroad, the original tin-containing products will gradually transition to Wuxi chemical products.
3. Non-toxic, non-flammable, non-explosive, non-corrosive, and good storage stability.
Antioxidant 264 Antioxidant 264 is an excellent general-purpose phenolic antioxidant, non-toxic, non-flammable, non-corrosive, good storage stability, can inhibit or delay the oxidation of plastic or rubber Degradation and prolong service life. The appearance is white or light yellow crystalline powder, soluble in benzene, toluene, methanol, ethanol, acetone, carbon tetrachloride, acetic acid, grease, ethyl ester and gasoline and other solvents, insoluble in water and dilute caustic soda solution. It is an excellent antioxidant additive for various petroleum products. It is widely used in various lubricating oils, gasoline, paraffin and various raw oils to prevent the acid value or viscosity of lubricating oils and fuel oils from rising. As a food antioxidant and stabilizer in food grade plastics and packaged foods, it can delay food rancidity. It can also be used in polyethylene (PE), polystyrene (PS), PP (polypropylene), polyvinyl chloride, ABS resin, polyester, cellulose resin and foam plastics (especially white or light-colored products), food grade Plastics, natural rubber, synthetic rubber (styrene-butadiene, nitrile, polyurethane, butadiene rubber, etc.), animal and vegetable oils, and food and cosmetics containing animal and vegetable oils. The reference dosage is generally 0.1%-1.0%.
Antioxidant N Antioxidant N is an antioxidant with no discoloration, no pollution, heat oxidation resistance, extraction resistance and excellent performance. Mainly used in polyamide polymer materials, can also be used as a stabilizer for rubber, polyolefin, etc. When applied in polyamide, it shows good initial chromaticity, and is often 168 with phosphorus-containing auxiliary antioxidants. The synergistic effect is remarkable and the anti-oxygen performance is improved. For nylon 6 and nylon 66, it can be added before monomer polymerization, or it can be added at the later stage of polymerization, or it can be dry mixed with nylon chips. This product can give various products good oxidation resistance and good processing performance.
Antioxidant 1076 Antioxidant 1076 is a non-polluting non-toxic hindered phenolic antioxidant with a white or yellowish solid powder appearance, easily soluble in benzene (57 grams), chloroform, cyclohexane, Acetone (19 grams) and esters and other organic solvents, slightly soluble in methanol, ethanol, mineral oil, insoluble in water, it has the advantages of stable light, not easy to change color, no pollution, no coloring, low volatility, water extraction resistance, good compatibility, and high antioxidant efficiency. It is widely used in polyethylene, polypropylene, polyoxymethylene, ABS resin, Polystyrene, polyvinyl chloride alcohol, engineering plastics, synthetic fibers, elastomers, adhesives, waxes, synthetic rubber and petroleum products. Prevent the thermal oxidative degradation of the substrate. It is suitable for addition at the polymerization, manufacture or final use stage of the product. It is often used with auxiliary antioxidants DLTP,168, etc. to exert synergistic effect, with better antioxidant performance, and the general dosage is 0.1% ~ 0.5%.
Antioxidant 1024 Antioxidant 1024 is a high-efficiency and pollution-free antioxidant with excellent performance. It is soluble in methanol and acetone, slightly soluble in chloroform and ethyl acetate, insoluble in water, and has a hindered phenol and hydrazide The dual structure also has the functions of oxidation resistance and metal deactivation. It is a metal deactivator. It does not produce color stains. It can be used alone or combined with other general antioxidants. It has excellent synergistic effect. It is suitable for polyethylene, polypropylene, polystyrene, polyamide, polyester, especially for antioxidants of phenolic resin, which can effectively prevent the self-oxidation of polymers due to the presence of transition metal ions (such as catalyst residues).
use this product is a low volatility organic synthesis antioxidant inhibitor, which is widely used in the synthesis and processing of various plastics such as polypropylene, polyethylene, ABS, polycarbonate fiber and polyester resin.
Uses An excellent phosphite antioxidant, the appearance of white powder, soluble in benzene, chloroform, cyclohexane and other organic solvents, slightly soluble in ethanol, acetone, insoluble in water, alcohol and other polar solvents, Slightly soluble in esters. Low toxicity, low volatility, high thermal stability, excellent hydrolysis resistance, and can effectively decompose the hydroperoxide produced during the thermal processing of polymeric materials. It has good synergistic effect in 1010 and 1076 with hindered amine antioxidants and can improve the stability of polymeric materials during thermal processing. There are more than a dozen preparations compounded with phenolic antioxidants, which are widely used in polyolefins (such as polyethylene, polypropylene) and olefin copolymers, polyamide, polycarbonate, PS resin, PVC, engineering plastics, rubber and petroleum products, ABS resin and other polymer materials. The compound can also be used for adhesives
Uses are widely used in the synthesis and processing of various plastics such as polypropylene, polyethylene, ABS, polycarbonate fiber and polyester resin