Name | N,N-Diethylhydroxylamine |
Synonyms | DEHA Diethylhydroxyamine N,N-Diethylhydroxyla N-DiethylhydroxylaMine N,N-diethyl hydroxylae N,N-Diethylhydroxylamine N,N-diethylhydroxy-amine N,N-Diethyl hydroxyamine N,N-DiethylhydroxylaMine N,N-Diethyl Hydroxyl Amine N-ethyl-N-hydroxyethanamine DiethylhydroxylaMine (DEHA85) N,N-DIETHYLHYDROXYLAMINE, TECH (D.E.H.A )N.N-DIETHYLHYDROXYLAMINE |
CAS | 3710-84-7 |
EINECS | 223-055-4 |
InChI | InChI=1/C4H11NO.C2H2O4/c1-3-5(6)4-2;3-1(4)2(5)6/h6H,3-4H2,1-2H3;(H,3,4)(H,5,6) |
InChIKey | FVCOIAYSJZGECG-UHFFFAOYSA-N |
Molecular Formula | C4H11NO |
Molar Mass | 89.14 |
Density | 0.902g/mLat 25°C |
Melting Point | −26-−25°C(lit.) |
Boling Point | 125-130°C |
Flash Point | 115°F |
Water Solubility | soluble |
Vapor Presure | 4 mm Hg ( 0 °C) |
Vapor Density | 3.07 (vs air) |
Appearance | Liquid |
Specific Gravity | 0.867 |
Color | Clear |
Exposure Limit | ACGIH: TWA 2 ppm |
BRN | 1731349 |
pKa | 14.19±0.69(Predicted) |
Storage Condition | Store below +30°C. |
Stability | Stable. Hygroscopic. Flammable. Incompatible with strong oxidizing agents, strong acids. |
Sensitive | Hygroscopic |
Explosive Limit | 1.9-10%(V) |
Refractive Index | n20/D 1.420(lit.) |
Physical and Chemical Properties | Character: colorless transparent liquid. Ammonia odor |
Use | High efficiency inhibitor, antioxidant. |
Hazard Symbols | Xn - Harmful |
Risk Codes | R10 - Flammable R21 - Harmful in contact with skin R38 - Irritating to the skin R40 - Limited evidence of a carcinogenic effect R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21 - Harmful by inhalation and in contact with skin. R53 - May cause long-term adverse effects in the aquatic environment R36/38 - Irritating to eyes and skin. |
Safety Description | S36/37 - Wear suitable protective clothing and gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S16 - Keep away from sources of ignition. |
UN IDs | UN 1993 3/PG 3 |
WGK Germany | 1 |
RTECS | NC3500000 |
FLUKA BRAND F CODES | 3 |
TSCA | Yes |
HS Code | 29280090 |
Hazard Class | 3 |
Packing Group | III |
Toxicity | LD50 orally in Rabbit: 2190 mg/kg LD50 dermal Rabbit 1300 mg/kg |
diethylhydroxylamine is liquid at room temperature. Soluble in water, the aqueous solution is weak alkaline. Above 570 deg C due to oxidation and decomposition, decomposition products of acetaldehyde, dialkylamines, iron acetate and acetaldehyde oxime, and a small amount of ammonia, nitrate and nitrite formation. It is highly volatile when exposed to heat.
The secondary amine is oxidized with aqueous hydrogen peroxide in the presence of the catalyst cadmium salt (CdCl2 · 2H2 0) or zinc salt (ZlCl2), or in the presence of a titanium silicalite catalyst, this product can be prepared by oxidizing dialkylamine (RRNH) or triethylamine with hydrogen peroxide aqueous solution.
used as a steam boiler water system of oxygen scavenger, not only suitable for low temperature oxygen removal, but also suitable for high temperature steam condensate circulation system of oxygen removal. Its oxygen scavenging function is superior to hydrazine and carbohydrazide. When a catalyst is present, its oxygen scavenging function is higher. Diethylhydroxylamine is also used as a passivator for metals on the water side of the device. In addition, diethylhydroxylamine can also be used as a polymerization inhibitor, a chain transfer agent, for the determination of aldehydes, and as an antioxidant and a corrosion inhibitor for metal equipment.
This product is non-toxic and non-corrosive.
The use of plastic bags, jacket polypropylene woven bags, hemp bags or drum packaging, each 25kg. Store in a cool, ventilated and dry place. According to the general provisions of the storage and transportation of chemicals.
LogP | 0.5 at 23℃ |
NIST chemical information | information provided by: webbook.nist.gov (external link) |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Application | It is used as an efficient inhibitor for vinyl monomers and conjugated olefins, and is a Terminator for styrene-butadiene emulsion polymerization process, unsaturated oils and other antioxidants efficient polymerization inhibitors, antioxidants. organic synthesis 1. As a vinyl monomer, it is used as an efficient polymerization inhibitor for conjugated olefins. 2, in the liquid phase or gas phase to the existing end of the seed, can be used as a highly efficient end polymerization inhibitor. 3. It is a very excellent Terminator for the styrene-butadiene emulsion polymerization process. 4, is the unsaturated oil and resin antioxidants. 5. It is a good stabilizer for photosensitive resin, photosensitive emulsion and synthetic resin. 6. It is a good inhibitor of photochemical smog in environmental protection. 7, is the boiler water and steam heat exchange equipment corrosion inhibitor. |
toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |