4-Amino-3-chlorotoluene
2-Chloro-4-methylaniline
CAS: 615-65-6
Molecular Formula: C7H8ClN
4-Amino-3-chlorotoluene - Names and Identifiers
| Name | 2-Chloro-4-methylaniline |
| Synonyms | 2-Chlor-4-toluidin 2-Chloro-p-toluidine 2-CHLORO-4-TOLUIDINE 2-CHLORO-P-TOLUIDINE 4-Amino-3-chlorotoluene 3-CHLORO-4-AMINOTOLUENE 4-AMINO-3-CHLOROTOLUENE 2-Chloro-4-methylaniline 2-CHLORO-4-METHYLANILINE 2-chlor-4-toluidin(czech) 1-AMINO-2-CHLORO-4-METHYLBENZENE |
| CAS | 615-65-6 |
| EINECS | 210-440-7 |
| InChI | InChI=1/C7H8ClN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3 |
4-Amino-3-chlorotoluene - Physico-chemical Properties
| Molecular Formula | C7H8ClN |
| Molar Mass | 141.6 |
| Density | 1.151 g/mL at 25 °C (lit.) |
| Melting Point | 7 °C (lit.) |
| Boling Point | 223-225 °C (lit.) |
| Flash Point | 211°F |
| Solubility | methanol: soluble |
| Vapor Presure | 0.103mmHg at 25°C |
| Appearance | Liquid |
| Color | Clear yellow to pale brown |
| BRN | 774514 |
| pKa | 3.09±0.10(Predicted) |
| Storage Condition | Keep in dark place,Inert atmosphere,Room temperature |
| Refractive Index | n20/D 1.575(lit.) |
| Physical and Chemical Properties | Yellow or brown liquid. Soluble in ethanol or benzene, slightly soluble in hot water, insoluble in cold water. |
4-Amino-3-chlorotoluene - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. R22 - Harmful if swallowed R33 - Danger of cumulative effects |
| Safety Description | S36/37 - Wear suitable protective clothing and gloves. S37/39 - Wear suitable gloves and eye/face protection S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| UN IDs | UN 3429 6.1/PG 3 |
| WGK Germany | 3 |
| RTECS | XU5110000 |
| FLUKA BRAND F CODES | 8-9-23 |
| TSCA | Yes |
| HS Code | 29214200 |
| Hazard Note | Harmful |
| Hazard Class | 6.1 |
| Packing Group | III |
4-Amino-3-chlorotoluene - Reference Information
| Application | 2-chloro-4-methylaniline is an organic intermediate, which can be obtained by reducing nitro. 2-Chloro-4-methylaniline can be used as a material for the preparation of organic electroluminescent elements. |
| preparation | the substrate 3-chloro-4-nitrotoluene is dissolved in MeOH(HPLC grade, 0.1 M). Hydrogenation is carried out in the presence of 0.5 mol%SiliaCat Pd0 at room temperature. The resulting mixture was degassing twice, each time replacing the vacuum with H2. Attach the reaction mixture to a hydrogen balloon. The reaction mixture was stirred for 2 hours. The catalyst is recovered by filtration. Rinse with MeOH and dry under vacuum. The concentrated filtrate was analyzed by GC/MS to obtain the product. |
| chemical properties | yellow or brown liquid. Soluble in ethanol or benzene, slightly soluble in hot water, insoluble in cold water. |
| use | is mainly used for the synthesis of organic pigments, pesticides, medicines and other organic chemicals. |
| NIST chemical information | The information is: webbook.nist.gov provides (external link) |
| EPA chemical information | The information is: ofmpub.epa.gov provides (external link) |
| toxic substance data | The information is: pubchem.ncbi.nlm.nih.gov Provide (external link) |
Last Update：2024-04-09 15:16:37
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