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4-Hydroxydiphenylketone

4-Hydroxybenzophenone

CAS: 1137-42-4

Molecular Formula: C13H10O2

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4-Hydroxydiphenylketone - Names and Identifiers

Name 4-Hydroxybenzophenone
Synonyms POB
benzoylphenol
P-BENZOYLPHENOL
Photoinitiator-4HBP
4-Hydroxybenzophenone
4-hydroxy-benzophenon
4-Hydroxydiphenylketone
Benzophenone, 4-hydroxy-
4-Hydroxyphenylphenylketone
(4-hydroxyphenyl)phenyl-methanon
(4-Hydroxyphenyl)phenyl-methanone
CAS 1137-42-4
EINECS 214-507-1
InChI InChI=1/C13H10O2/c14-12-8-6-11(7-9-12)13(15)10-4-2-1-3-5-10/h1-9,14H

4-Hydroxydiphenylketone - Physico-chemical Properties

Molecular FormulaC13H10O2
Molar Mass198.22
Density1.194g/cm3
Melting Point132-135℃
Boling Point367.3°C at 760 mmHg
Flash Point156.7°C
Water SolubilityInsoluble in water.
Vapor Presure6.5E-06mmHg at 25°C
AppearanceMorphological Powder color, white to beige to brown
pKa8.14±0.13(Predicted)
Storage ConditionStore below +30°C.
Refractive Index1.615
MDLMFCD00002355
Physical and Chemical PropertiesMelting Point 132-135°C
UseUse 1. It is used in organic synthesis and is an intermediate of anti-infertility drug clomiphene. 2, used as pharmaceutical intermediates. 3, 4-hydroxybenzophenone for drug synthesis and UV resistance.

4-Hydroxydiphenylketone - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk CodesR36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS24/25 - Avoid contact with skin and eyes.
WGK Germany2
RTECSPC4959775
TSCAYes
HS Code29145000

4-Hydroxydiphenylketone - Upstream Downstream Industry

Raw MaterialsAluminum chloride
Phenyl benzoate
Imidodicarbonic acid, 2-benzoyl-, 1,3-bis(1,1-dimethylethyl) ester
4-BENZYLOXYBENZOPHENONE
4-Methoxybenzophenone
Benzoyl chloride, 4-hydroxy- (9CI)
4-BROMOBENZOPHENONE
4-BENZYLPHENOL
4-Hydroxyphenylboronic acid
4-Chlorobenzophenone
Phenylboronic acid
p-Hydroxybenzaldehyde
4-Cyanophenol
Anisole
Downstream Productsalpha-[4-[2-(diethylamino)ethoxy]phenyl]-alpha-phenylphenethyl alcohol
4-[2-(diethylamino)ethoxy]benzophenone
Clomiphene Citrate
4-Benzoylphenyl Methacrylate
3,4-Dihydroxybenzophenone

4-Hydroxydiphenylketone - Introduction

Insoluble in water. It is irritating to eyes, respiratory system and skin.
Last Update：2022-10-16 17:12:19

4-Hydroxydiphenylketone - Security information

Hazard Note Irritant
Last Update：2024-04-10 22:29:15

4-Hydroxydiphenylketone - Production method

It is obtained by heating and rearranging phenyl benzoate. The phenyl benzoate is heated to 70 DEG C to melt, stirring, the anhydrous aluminum trichloride is quickly put in, the reaction escapes hydrogen chloride, and the temperature is raised by itself, and the reaction is 15min at 130 DEG C. Cool and add dilute hydrochloric acid. Filter and wash to neutral. The filter cake was recrystallized with benzene to obtain 4-hydroxybenzophenone with 62% yield.

Last Update：2024-04-10 22:29:15

4-Hydroxydiphenylketone - Nature

BRN 777776
NIST chemical information Methanone, (4-hydroxyphenyl)phenyl-(1137-42-4)
EPA chemical information Methanone, (4-hydroxyphenyl)phenyl- (1137-42-4)
Last Update：2024-04-09 20:52:54
4-Hydroxydiphenylketone
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Nantong Reform Petro-Chemical CO., LTD.
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Product Name: 4-Hydroxybenzophenone Request for quotation
CAS: 1137-42-4
Tel: +86-17551318830
Email: r@reformchem.com­
Mobile: +86-17551318830
QQ: 3785839865 Click to send a QQ messageSend QQ message
Jiangsu Pules Biotechnology Co.,Ltd.
Product Name: 4-Hydroxybenzophenone Request for quotation
CAS: 1137-42-4
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Wechat: 17505222756
Guangzhou Yuanda New Material Co.,Ltd
Product Name: 4-Hydroxybenzophenone Request for quotation
CAS: 1137-42-4
Tel: +86 19849939632
Email: 2470479589@qq.com
Mobile: +86 19849939632
QQ: 2470479589 Click to send a QQ message
Wechat: +86 19849939632
Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: 4-Hydroxybenzophenone Request for quotation
CAS: 1137-42-4
Tel: 0086-551-65418684
Email: sales@tnjchem.com
　　　　 info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Wuhan Xingzhongcheng Chemical limited company
Spot supply
Product Name: 4-Hydroxybenzophenone Request for quotation
CAS: 1137-42-4
Tel: 86+027-83389957
Email: 1024042217@qq.com
Mobile: 86+18627766980
QQ: 1024042217 Click to send a QQ message
Wechat: 18627766980
Shanghai Yuanye Bio-Technology Co., Ltd.
Spot supply
Product Name: 4-Hydroxybenzophenone Visit Supplier Webpage Request for quotation
CAS: 1137-42-4
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409 Click to send a QQ message
Wechat: 18301782025
Shanghai Worldyang Chemical Co.,Ltd.
Product Name: 4-Hydroxybenzophenone Request for quotation
CAS: 1137-42-4
Tel: +86-21-56795779
Email: charles7788@worldyachem.com
Mobile: +86-13651600618
QQ: 2850607228 Click to send a QQ message
Wechat: 13651600618
WhatsApp: +8613651600618
Zouping Mingxing Chemical Co., Ltd.
Product Name: 4-Hydroxy benzophenone Request for quotation
CAS: 1137-42-4
Tel: 0086-13605431940
Email: xuli678323@126.com
Mobile: +86-13605431940
QQ: 56860987 Click to send a QQ message
Wechat: 13605431940
WhatsApp: 13605431940
View History
4-Hydroxydiphenylketone
Raw Materials for 4-Hydroxydiphenylketone
Aluminum chloride
Phenyl benzoate
Imidodicarbonic acid, 2-benzoyl-, 1,3-bis(1,1-dimethylethyl) ester
4-BENZYLOXYBENZOPHENONE
4-Methoxybenzophenone
Benzoyl chloride, 4-hydroxy- (9CI)
4-BENZYLPHENOL
Anisole
Downstream Products for 4-Hydroxydiphenylketone
alpha-[4-[2-(diethylamino)ethoxy]phenyl]-alpha-phenylphenethyl alcohol
4-[2-(diethylamino)ethoxy]benzophenone
Clomiphene Citrate
4-Benzoylphenyl Methacrylate
3,4-Dihydroxybenzophenone
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