494227-37-1
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene
CAS: 494227-37-1
Molecular Formula: C64H74FeN2O4P210*
494227-37-1 - Names and Identifiers
| Name | (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene |
| Synonyms | MANDYPHOS SL-M004-1 (SP,SμP)-1,1μ-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene (αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene (S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-dimethyl-4-methoxyphenyl)phosphino)ferrocene (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE |
| CAS | 494227-37-1 |
494227-37-1 - Physico-chemical Properties
| Molecular Formula | C64H74FeN2O4P210* |
| Molar Mass | 1053.08 |
| Specific Rotation(α) | -61.5° (c 1.0, CHCl3) |
| Appearance | solid |
| Color | yellow to orange-red |
| Storage Condition | Room Temprature |
| Stability | store cold |
494227-37-1 - Risk and Safety
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| WGK Germany | 3 |
| HS Code | 29319090 |
494227-37-1 - Introduction
(S,S)-(-)-2,2 '-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3, 3) phosphino]ferrocene is a chiral organic compound with the chemical formula (C44H50FeNOP2)2.
Nature:
-Appearance: solid, common yellow crystalline powder.
-Solubility: Soluble in organic solvents such as ether and dichloromethane.
-Melting point: about 120-125 ℃.
Use:
-as a chiral ligand: can be used for catalytic peptide synthesis, metal-catalyzed asymmetric reactions and asymmetric catalytic reactions.
-As a catalyst: Due to its chiral structure, this compound can be used as a catalyst for metal-catalyzed reactions, such as carbene reaction, Henry reaction of imine and hydrogenation reaction of allyl alcohol.
-widely used in the field of drug synthesis, such as for the synthesis of piperazine drugs.
Preparation Method:
(S,S)-(-)-2,2 '-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,) phosphino]ferrocene can be synthesized by a chemical synthesis method. The specific preparation process is somewhat complex and requires detailed chemical synthesis techniques.
Safety Information: The toxicity and safety information of
- (S,S)-(-)-2,2 '-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,) phosphino]ferrocene has not been reported in detail at present, so it is necessary to follow the laboratory's safe operation specifications when using and operating.
-Wear appropriate protective equipment such as gloves, laboratory glasses and protective clothing when handling the compound.
-This compound may be potentially harmful to human health and should therefore be avoided by inhalation, ingestion or skin contact.
-If you come into contact with this compound, rinse immediately with plenty of water and seek medical help.
Nature:
-Appearance: solid, common yellow crystalline powder.
-Solubility: Soluble in organic solvents such as ether and dichloromethane.
-Melting point: about 120-125 ℃.
Use:
-as a chiral ligand: can be used for catalytic peptide synthesis, metal-catalyzed asymmetric reactions and asymmetric catalytic reactions.
-As a catalyst: Due to its chiral structure, this compound can be used as a catalyst for metal-catalyzed reactions, such as carbene reaction, Henry reaction of imine and hydrogenation reaction of allyl alcohol.
-widely used in the field of drug synthesis, such as for the synthesis of piperazine drugs.
Preparation Method:
(S,S)-(-)-2,2 '-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,) phosphino]ferrocene can be synthesized by a chemical synthesis method. The specific preparation process is somewhat complex and requires detailed chemical synthesis techniques.
Safety Information: The toxicity and safety information of
- (S,S)-(-)-2,2 '-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,) phosphino]ferrocene has not been reported in detail at present, so it is necessary to follow the laboratory's safe operation specifications when using and operating.
-Wear appropriate protective equipment such as gloves, laboratory glasses and protective clothing when handling the compound.
-This compound may be potentially harmful to human health and should therefore be avoided by inhalation, ingestion or skin contact.
-If you come into contact with this compound, rinse immediately with plenty of water and seek medical help.
Last Update：2024-04-09 21:04:16
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