Name | 4,4'-Diaminodiphenylamine sulfate |
Synonyms | 4,4-Diaminophenylamine sulfate 4,4-Iminodianiline sulfate salt 4.4'-DIAMINODIPHENYLAMINESULFATE 4,4'-Diaminodiphenylamine sulfate N-(4-aminophenyl)benzene-1,4-diamine |
CAS | 53760-27-3 |
EINECS | 258-748-0 |
InChI | InChI=1/C12H13N3.H2O4S/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12;1-5(2,3)4/h1-8,15H,13-14H2;(H2,1,2,3,4)/p-2 |
Molecular Formula | C12H13N3·H2O4S |
Molar Mass | 297 |
Melting Point | 300℃ |
Appearance | Form Solid, color Off-White |
Storage Condition | Inert atmosphere,Room Temperature |
MDL | MFCD00013113 |
Physical and Chemical Properties | Yellow flake, melting point 158 ℃. Soluble in ethanol and ether, insoluble in water. |
Use | Ice dye color base, namely black base B. Black salt ANS can be prepared and can be used for the synthesis of other dyes. |
Safety Description | S24/25 - Avoid contact with skin and eyes. |
UN IDs | UN 2811 6.1/PG 3 |
Raw Materials | 4,4'-DINITRODIPHENYLAMINE |
Downstream Products | fast black salt G Azoic Diazo Component 45 |
The sodium salt of 2-chloro-5-nitrobenzenesulfonic acid was prepared using soda ash. The sodium salt and p-amino-N-acetanilide at 110 °c, 0. Condensation under 08MPa to generate 4-nitro_4,_n-acetylaminodiphenylene-2 sodium sulfonate, which is acidified with hydrochloric acid, then reduced with iron powder, and hydrolyzed with sulfuric acid to remove sulfonic acid group and acetyl group, the finished product may be obtained.