60-09-3
p-Aminoazobenzene
CAS: 60-09-3
Molecular Formula: C12H11N3
60-09-3 - Names and Identifiers
| Name | p-Aminoazobenzene |
| Synonyms | C.I. 11000 Aniline Yellow Oil Yellow AAB Phenylazoaniline Solvent Yellow 1 p-Aminoazobenzene 4-Aminoazobenzene 4-phenylazoaniline 4-Benzeneazoaniline Azobenzene, 4-amino- C.I. Solvent Yellow 1 (1E)-1-phenyltriaz-1-ene 4-(phenyldiazenyl)aniline C.I. Solvent Yellow 1 (8CI) 4-[(E)-phenyldiazenyl]aniline 4-[(Z)-phenyldiazenyl]aniline |
| CAS | 60-09-3 |
| EINECS | 200-453-6 |
| InChI | InChI=1/C12H11N3/c13-10-6-8-12(9-7-10)15-14-11-4-2-1-3-5-11/h1-9H,13H2 |
60-09-3 - Physico-chemical Properties
| Molecular Formula | C12H11N3 |
| Molar Mass | 197.24 |
| Density | 1.127g/cm3 |
| Melting Point | 123-126 °C(lit.) |
| Boling Point | 360.658°C at 760 mmHg |
| Flash Point | 171.92°C |
| Water Solubility | 29.59mg/L(25 ºC) |
| Solubility | Slightly soluble in hot water, soluble in hot alcohol, ether, benzene, chloroform. |
| Vapor Presure | 0mmHg at 25°C |
| Appearance | Form neat, color yellow crystals or orange needles with blue case from EtOH |
| pKa | 2.82(at 25℃) |
| Storage Condition | 2-8 ℃, dark |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| Sensitive | Sensitive to light |
| Refractive Index | 1.611 |
| MDL | MFCD00007854 |
| Physical and Chemical Properties | Chemical yellow to light brown, slightly gray or light blue crystal or powder. Melting point 126 ℃, boiling point> 360 ℃, slightly soluble in water, soluble in ethanol, ether, chloroform, benzene and oils. |
| Use | For the system of azo dyes and oxazine dyes, and used as alcohol soluble yellow and pH indicator |
60-09-3 - Risk and Safety
| Risk Codes | R45 - May cause cancer R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R46 - May cause heritable genetic damage |
| Safety Description | S53 - Avoid exposure - obtain special instructions before use. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S22 - Do not breathe dust. |
| UN IDs | UN 3077 9/PG 3 |
| WGK Germany | 3 |
| RTECS | BY8225000 |
| HS Code | 29270000 |
| Hazard Class | IRRITANT |
| Packing Group | III |
| Toxicity | LD50 intraperitoneal in mouse: 200mg/kg |
60-09-3 - Upstream Downstream Industry
60-09-3 - Introduction
Easily soluble in ethanol, benzene, chloroform, etc., slightly soluble in water. The maximum absorption wavelength is 386nm. Median lethal dose (mice, abdominal cavity) 200mg/kg. There have been positive reports of carcinogenic tests in experimental animals.
Last Update：2022-10-16 17:26:54
60-09-3 - Nature
| color index | 11000 |
| Merck | 14,419 |
| BRN | 1913042 |
| (IARC) Carcinogen Classification | 2B (Vol. 8, Sup 7) 1987 |
| NIST chemical information | Benzenamine, 4-(phenylazo)-(60-09-3) |
| EPA chemical information | 4-Aminoazobenzene (60-09-3) |
Last Update：2024-09-05 11:00:12
60-09-3 - Uses and synthesis methods
use
1. dye intermediates. Used to synthesize azo dyes, disperse dyes, oxazine dyes; also used to make paints and pigments, as well as alcohol-soluble yellow and pH indicators.
2. Used to produce azo dyes and oxazine dyes, etc., and used as alcohol-soluble yellow and pH indicator
3, acid-base indicator and nitrite test. Organic synthesis.
production method
Starting from aniline, it is obtained by condensation with aniline after diazotization and translocation rearrangement. Put aniline and sodium nitrite solution into the reaction pot, stir at 30-40 ℃, add 30% hydrochloric acid within 2.5-3h, and then raise the temperature to 50-55 ℃ for indexing.
Last Update：2024-09-05 11:01:39
60-09-3 - Security information
| toxic substance data | 60-09-3(Hazardous Substances Data) |
Last Update：2024-04-10 22:29:15
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Spot supply
Product Name: p-Aminoazobenzene Request for quotationCAS: 60-09-3
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3787852685
Spot supply
Product Name: p-Aminoazobenzene Request for quotationCAS: 60-09-3
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Spot supply
Product Name: p-Aminoazobenzene Request for quotationCAS: 60-09-3
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Wechat: 17505222756
Spot supply
Product Name: Phenacetin Impurity 26 Visit Supplier Webpage Request for quotationCAS: 60-09-3
Tel: 0714-3999186
Email: 2853786052@qq.com
Mobile: 86+15671228036
QQ: 2853786052
Wechat: 15671228036
Multiple Specifications
Product Name: p-Aminoazobenzene Visit Supplier Webpage Request for quotationCAS: 60-09-3
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
View History
Raw Materials for 60-09-3
Downstream Products for 60-09-3
photochromic azobenzene polymer
SUDAN RED 7B
4-[4-(PHENYLAZO)PHENYLAZO]-O-CRESOL
4-Amino-5-hydroxy-3-[(4-nitrophenyl)azo]-6-[[4-(phenylazo)phenyl]azo]naphthalene-2,7-disulfonic acid disodium salt
SOLVENT RED 30
Benzenamine, 4-(phenylazo)-, reaction products with aniline and aniline hydrochloride, (Z)-9-octadecenoate
Solvent Orange 14
Acid Red 73
Solvent Red 23
SUDAN RED 7B
4-[4-(PHENYLAZO)PHENYLAZO]-O-CRESOL
4-Amino-5-hydroxy-3-[(4-nitrophenyl)azo]-6-[[4-(phenylazo)phenyl]azo]naphthalene-2,7-disulfonic acid disodium salt
SOLVENT RED 30
Benzenamine, 4-(phenylazo)-, reaction products with aniline and aniline hydrochloride, (Z)-9-octadecenoate
Solvent Orange 14
Acid Red 73
Solvent Red 23