Molecular Formula | C11H6Cl2N2 |
Molar Mass | 237.08 |
Density | 1.4052 (rough estimate) |
Melting Point | 152.9℃ |
Boling Point | 378.43°C (rough estimate) |
Water Solubility | 4.8 mg l-1 in water at 25 °C |
Vapor Presure | 1.1 x 10-7 Pa (25 °C) |
Appearance | neat |
Merck | 13,4016 |
BRN | 5433281 |
pKa | 13.63±0.50(Predicted) |
Storage Condition | Room Temprature |
Refractive Index | 1.6400 (estimate) |
Physical and Chemical Properties | The pure chemical properties are white crystals. M. p.152.9 ℃, vapor pressure 420 × 10-9Pa (20 ℃). The solubility in water at 20 ℃ is 2mg/L, and the partition coefficient (n-octanol/water) is 20000. Stable below 250 ℃. At pH 3~9 and 100 ℃, it is stable within 6 hours. The half-life in soil is 150 ~ 250d. |
Use | Use pyrrolidinitrile protective fungicides. For seed treatment, it has special effects on seed-borne pathogens of cereal crops, and also has good control effects on seed-borne and soil-borne pathogens of non-cereal crops. Treating wheat seeds with 0.2g of effective ingredients/kg seeds can effectively prevent barley stripe disease, net spot disease, wheat snow rot, and barley smut; treating rice seeds with the same dose can prevent rice bad seedling disease, Rice blast, rice flax leaf spot, etc.; treating potatoes with 0.05g of effective ingredient/kg potato pieces can prevent potato dry rot, black mole, silver skin disease, black rot, etc. |
Hazard Symbols | Xn - Harmful |
Risk Codes | 20 - Harmful by inhalation |
UN IDs | 3077 |
WGK Germany | 2 |
RTECS | UX9347500 |
Hazard Class | 9 |
Packing Group | III |
Toxicity | LD50 in rats, mice, rabbits (mg/kg): >5000 orally; LD50 dermally in rats: >2000 mg/kg; LC50 (4 hr) in rats: >1502 mg/m3 by inhalation (Nevill) |
Raw Materials | Trifluoroacetic acid Potassium Acetate Pyrrole (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE 2,3-Dichlorobenzaldehyde Methoxyethene |
EPA chemical information | 1H-Pyrrole-3-carbonitrile, 4-(2,3-dichlorophenyl)- (74738-17-3) |
2, 3-dichlorobenzaldehyde reacts with dimethyl ether-based triphenylphosphorus to produce (Z) and (E)-2, 3-dichlorophenyl vinyl methyl ether. Then it is acylated with trifluoroacetic acid, and the acylation product is cyclized with potassium aminoacetate to prepare N-fluoroacyl-4-(2, 3-dichlorophenyl) pyrrole-3-trifluoromethyl, The cyclization product uses lithium aluminum hydride to remove the acyl group to obtain 4-(2, 3-dichlorophenyl) pyrrole-3-trifluoromethyl. Finally, it interacts with ammonia to get seed dressing.