Molecular Formula | C5H11O4PS2 |
Molar Mass | 230.24 |
Physical and Chemical Properties | Chemical properties The pure sulfur phosphate ester is a colorless transparent liquid, m.p.85 ℃/1.3Pa, B. p.125 ~ 132 ℃/53~67Pa, insoluble in water, petroleum ether, soluble in organic solvents such as alcohol, benzene, ketone, etc. Industrial products are light yellow transparent liquid with relative density of 1.29~1.30(20 ℃). |
Use | Uses O,O dimethyl-S-(methoxycarbonylmethyl) dithiophosphate, short for thiophosphate, is an intermediate of The organophosphorus pesticide Dimethoate. |
Raw Materials | Dimethyl sulfide Methyl chloroacetate |
Downstream Products | Dimethoate O,O-DIMETHYL-S-(METHOXY-CARBONYL) THIOPHOSPHATE |
colorless liquid with malodorous odor. Density 1.29g/cm3. Boiling point of 65 degrees C (2kPa).
from chloroacetic acid methyl ester and sulfide ammonium salt (O,0 'dimethyl dithiophosphate ammonium) synthesis. The crude product obtained from the synthesis was distilled under reduced pressure to obtain a finished product.
pesticide intermediates. Mainly used for the preparation of dimethoate, malathion and other organophosphorus pesticides.
This product is toxic. Has a stimulating effect on the skin. Production process should pay attention to prevent material leakage, avoid contact with the human body. Operators should wear protective equipment. Packaged in iron or plastic barrels. Store in a cool, ventilated, dry warehouse. Pay attention to fire prevention, and store and transport toxic substances according to regulations.
The preparation method is to react methyl sulfide ammonium salt with methyl chloroacetate to obtain sulfur phosphate ester.
1100~1200kg of methyl sulfide ammonium salt aqueous solution (content about 38% ~ 42%) and a certain amount of methyl chloroacetate are put into a reaction kettle, stirred, pH = 6~7 is adjusted, then the temperature is raised to 35~38 ℃, the heating is stopped, the temperature is raised by itself, and the temperature is controlled at 55~58 ℃ for 2.5h. After the reaction, cool, add 200kg of water, stir for a moment, and pump the reaction liquid to the water separator to stand and delaminate. After the ester layer is filtered, it is allowed to stand for 30min in a water separator with 200kg of water added in advance, and the waste water is separated. After the ester layer is washed with water and standing, crude sulfur and phosphorus esters are obtained. Crude sulfur and phosphorus esters are desolated by a rising film evaporator, separated by gas and liquid, and cooled to obtain refined sulfur and phosphorus esters.