Name | O-(trimethylsilyl)hydroxylamine |
Synonyms | AKOS MSC-0140 AMINOXYTRIMETHYLSILANE Aminoxytrimethylsilane (aminooxy)(trimethyl)silane O-trimethylsilylhydroxylamine 0-Trimethylsilylhydroxylamine O-(TRIMETHYLSILYL)HYDROXYLAMINE O-(trimethylsilyl)hydroxylamine O-(TRIMETHYLSILYL)HYDROXYLAMINE,PRACT |
CAS | 22737-36-6 |
InChI | InChI=1/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3 |
InChIKey | AEKHNNJSMVVESS-UHFFFAOYSA-N |
Molecular Formula | C3H11NOSi |
Molar Mass | 105.21 |
Density | 0.86g/mLat 25°C(lit.) |
Boling Point | 98-100°C(lit.) |
Flash Point | 48°F |
Vapor Presure | 39mmHg at 25°C |
Appearance | Liquid |
Specific Gravity | 0.860 |
Color | Clear colorless |
BRN | 2035893 |
pKa | 3.28±0.70(Predicted) |
Storage Condition | 2-8°C |
Sensitive | 7: reacts slowly with moisture/water |
Refractive Index | n20/D 1.405(lit.) |
Risk Codes | R11 - Highly Flammable R34 - Causes burns |
Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
UN IDs | UN 2733 3/PG 2 |
WGK Germany | 3 |
FLUKA BRAND F CODES | 10-21 |
TSCA | No |
HS Code | 29310099 |
Hazard Class | 3.1 |
Packing Group | II |
use | O-(trimethylsilyl) hydroxylamine is an organosilicon compound and can be used as an organic reagent. |
Preparation | The reaction of chlorosilane with hydroxylamine is the most commonly used method for preparing silazane. Amine can be used as an absorbent of HCl released in the reaction. The stereosteric hindrance of hydroxyl groups and substituents on silicon has a significant impact on the difficulty of the reaction and the distribution of the product. The target compound O-(trimethylsilane) hydroxylamine was prepared with trimethylchlorosilane and hydroxylamine as starting materials. The synthesis reaction formula is as follows: |