Antimony(III)fluoride(SbF3)
antimony trifluoride
CAS: 7783-56-4
Molecular Formula: F3Sb
Antimony(III)fluoride(SbF3) - Names and Identifiers
| Name | antimony trifluoride |
| Synonyms | trifluoro-stibin trifluorostibane trifluorostibine Antimonyfluoride1 ANTIMONY FLUORIDE Antimony(Ⅲ)fluoride ANTIMONY TRIFLUORIDE antimony trifluoride ANTIMONY(III) FLUORIDE ANTIMONY FLUORIDE, TRI Antimony(III) fluoride Antimony (III) fluoride Antimony(III)fluoride(SbF3) AntimonyfluorideAntimonytrifluoride antimony(+3) trihydride cation trifluoride |
| CAS | 7783-56-4 |
| EINECS | 232-009-2 |
| InChI | InChI=1/3FH.Sb.3H/h3*1H;;;;/q;;;+3;;;/p-3/r3FH.H3Sb/h3*1H;1H3/q;;;+3/p-3 |
Antimony(III)fluoride(SbF3) - Physico-chemical Properties
| Molecular Formula | F3Sb |
| Molar Mass | 178.76 |
| Density | 4.38g/mLat 25°C(lit.) |
| Melting Point | 292 °C |
| Boling Point | 376 °C |
| Flash Point | 376°C |
| Water Solubility | 385 g/100 mL (20 ºC) |
| Solubility | 4430g/l Hydrolysis |
| Vapor Presure | 26.34kPa at 292℃ |
| Appearance | powder |
| Specific Gravity | 4.379 |
| Color | White to gray |
| Exposure Limit | ACGIH: TWA 0.5 mg/m3; TWA 2.5 mg/m3NIOSH: IDLH 50 mg/m3; IDLH 250 mg/m3; TWA 0.5 mg/m3 |
| Merck | 14,709 |
| Storage Condition | Store below +30°C. |
| Sensitive | Moisture Sensitive |
| Use | Used as analytical reagents and mordant for cotton fabrics |
Antimony(III)fluoride(SbF3) - Risk and Safety
| Risk Codes | R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S7 - Keep container tightly closed. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | UN 3260 8/PG 2 |
| WGK Germany | 3 |
| RTECS | CC5150000 |
| FLUKA BRAND F CODES | 10 |
| TSCA | Yes |
| HS Code | 2826 19 90 |
| Hazard Note | Corrosive/Highly Toxic |
| Hazard Class | 8 |
| Packing Group | III |
Antimony(III)fluoride(SbF3) - Reference Information
| sublimation point | 376°C |
| LogP | 0.72 at 25℃ |
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| solubility in water (g/100ml) | grams dissolved per 100ml of water at different temperatures (℃): 385g/0 ℃;444g/20 ℃;562g/30 ℃; Hydrolysis/40 ℃ |
| Use | as an analytical reagent and mordant for cotton fabrics fluorination catalyst, preparation of chlorofluoro compounds. Mordant for cotton fabrics. |
| production method | take 25% G of hydrofluoric acid into a polyethylene beaker and heat it to 50 ℃, 100g of antimony trioxide was added thereto. It was dissolved with stirring, and insoluble matters were removed by filtration. The filtrate was charged into a polyethylene bottle and heated to about 70 ° C. While introducing dry air through a polyethylene tube, concentrated, and then solidified. About 120g of antimony trifluoride was obtained by pulverizing the crystal block and dehydrating it in a sufficiently dried air. 80g of the obtained antimony trifluoride was placed in a thick-walled test tube (25mm in diameter and 260mm in length) and sublimed under reduced pressure at 99% ° C. And 2mmHg for 4H to obtain approximately 72g of antimony trifluoride having a purity. The purification may be carried out by recrystallization in dry methanol or by distillation in a copper vessel. Alternatively, it may be dissolved in an aqueous hydrogen fluoride solution, and the solution may be slowly concentrated in a desiccator containing sodium hydroxide and purified. |
| category | toxic substances |
| toxicity grade | high toxicity |
| Acute toxicity | subcutaneous-mouse LDL0: 22.9 mg/kg; Oral-mouse LD50: 804 mg/kg |
| flammability hazard characteristics | non-combustible; Hydrogen fluoride gas corrosive to water or acid; toxic fluoride and antimony-containing fumes generated by heat |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; It is stored separately from acids and food additives |
| Occupational Standards | TWA 0.5 mg (antimony)/m3; Tel 2.5 mg (fluoride)/M3 |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-10 22:29:15
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