BTFFH - Names and Identifiers
Name | Bis(tetramethylene)fluoroformamidinium hexafluorophosphate
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Synonyms | BTFFH btffh FLUORO-N,N,N',N'-BIS(TETRAMETHYLENE)- FLUORO-DIPYRROLIDINOCARBENIUM HEXAFLUOROPHOSPHATE fluorobis(tetramethylene)formamidinium hexafluorophosphate Bis(tetramethylene)fluoroformamidinium hexafluorophosphate BTFFH, Fluoro-dipyrrolidinocarbenium hexafluorophosphate BIS(TETRAMETHYLENE)FLUOROFORMAMIDINIUM HEXAFLUOROPHOSPHATE BTFFH~Fluorobis(tetramethylene)formamidinium hexafluorophosphate Fluoro-N,N,N,N-bis(tetramethylene)formamidinium hexafluorophosphate FLUORO-N,N,N'N'-BIS(TETRAMETHYLENE) FORMAMIDINIUM HEXAFLUOROPHOSPHATE 1-[fluoro(pyrrolidin-1-yl)methylidene]pyrrolidinium hexafluorophosphate
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CAS | 164298-25-3
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EINECS | 628-489-1 |
InChI | InChI=1/C9H16FN2.F6P/c10-9(11-5-1-2-6-11)12-7-3-4-8-12;1-7(2,3,4,5)6/h1-8H2;/q+1;-1 |
InChIKey | MNJUGQKOHJQOCK-UHFFFAOYSA-N |
BTFFH - Physico-chemical Properties
Molecular Formula | C9H16F7N2P
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Molar Mass | 316.2 |
Melting Point | 154-160°C |
Appearance | Powder or Crystalline Powder |
Color | White to off-white |
Storage Condition | 2-8°C |
Sensitive | Moisture Sensitive |
MDL | MFCD02683430 |
BTFFH - Risk and Safety
Hazard Symbols | Xi - Irritant
![Irritant](//res.chembk.com/assets/images/hs/Xi.gif)
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Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
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UN IDs | 3261 |
WGK Germany | 3 |
FLUKA BRAND F CODES | 3-10-21 |
HS Code | 29339900 |
Hazard Class | 8 |
Packing Group | III |
BTFFH - Introduction
Bis (tetraethylene) fluoroformamidinium hexafluorophosphate is an organic compound with the chemical formula [(CF3)2P(O)]2NMCF3 (where N is a nitrogen atom). The following is an introduction to some of its properties, uses, methods and safety information:
Nature:
Bis(tetramethylene)fluoroformamidinium hexafluorophosphate is a colorless liquid with high thermal and chemical stability. It has low volatility and high boiling point, insoluble in water, but soluble in many organic solvents such as ethanol, acetone, etc.
Use:
Bis(tetramethylene)fluoroformamidinium hexafluorophosphate is an important organic synthesis intermediate, which has a wide range of applications in the field of organic synthesis. It can be used as initiator, Catalyst, heavy nitrogen source, active hydroxyl protecting agent, etc. In addition, it can be used to prepare Hexafluorophosphate-containing compounds, such as hexafluorophosphate-containing ionic liquids.
Method:
Bis(tetramethylene)fluoroformamidinium hexafluorophosphate has many preparation methods. A typical method is to react formamide with dimethyimine in the presence of boron trifluoride to give the imidamide, which is then acidified with trifluoroboric acid to give the imidoyl fluoride. It is then reacted with tetramethylenephosphine fluoride ((CF3)2PF) to produce Bis(tetramethylene) fluoroformidinium hexafluorophosphate.
Safety Information:
Bis(tetramethylene)fluoroformamidinium hexafluorophosphate has low acute toxicity, but should be handled with care. It has a stimulating effect on the skin, eyes and mucous membranes, and protective measures should be taken to avoid direct contact. When in use, wear appropriate protective equipment such as chemical protective gloves, goggles and protective clothing. During storage and transportation, avoid contact with oxidants, organic impurities, etc., and avoid fire and high temperature. When disposing of waste, it should be properly disposed of in accordance with relevant regulations. Seek medical help in case of accidental ingestion or accidental exposure.
Last Update:2024-04-10 22:29:15