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Borate(1-),tetrafluoro-,lithium

Lithium tetrafluoroborate

CAS: 14283-07-9

Molecular Formula: BF4Li

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Borate(1-),tetrafluoro-,lithium - Names and Identifiers

Name Lithium tetrafluoroborate
Synonyms lithiumfluoborate
LITHIUM BOROFLUORIDE
Lithium tetrafluoroborate
LITHIUM TETRAFLUOROBORATE
Lithiumfluoborate,monohydrate
Borate(1-),tetrafluoro-,lithium
lithiumtetrafluoroborate,anhydrous
LITHIUM TETRAFLUOROBORATE FOR SYNTHESIS
CAS 14283-07-9
EINECS 238-178-9
InChI InChI=1/BFO2.2Li/c2-1(3)4;;/q-2;2*+1

Borate(1-),tetrafluoro-,lithium - Physico-chemical Properties

Molecular FormulaBF4Li
Molar Mass93.75
Density0.852 g/mL at 25 °C
Melting Point293-300 °C (dec.) (lit.)
Flash Point6°C
Water SolubilitySOLUBLE
Vapor Presure10Pa at 20℃
AppearanceWhite to light brown powder
Specific Gravity0.852
ColorWhite to off-white
Exposure LimitACGIH: TWA 2.5 mg/m3NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
Merck14,5543
PH2.88
Storage ConditionStore below +30°C.
StabilityStable. Incompatible with glass, acids, strong bases. Contact with acids releases toxic gas. Moisture-sensitive.
SensitiveHygroscopic
MDLMFCD00011087
Physical and Chemical PropertiesLithium tetrafluoroborate is white powder, density: 0.852g/cm3, melting point 293-300 ℃, and humid air or water contact will decompose.

Borate(1-),tetrafluoro-,lithium - Risk and Safety

Risk CodesR20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R31 - Contact with acids liberates toxic gas
R34 - Causes burns
R36/37/38 - Irritating to eyes, respiratory system and skin.
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R11 - Highly Flammable
R36/38 - Irritating to eyes and skin.
Safety DescriptionS22 - Do not breathe dust.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27 - Take off immediately all contaminated clothing.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S25 - Avoid contact with eyes.
S16 - Keep away from sources of ignition.
S36/37 - Wear suitable protective clothing and gloves.
UN IDsUN 3260 8/PG 2
WGK Germany3
FLUKA BRAND F CODES3-10
TSCAYes
HS Code28269090
Hazard NoteCorrosive/Hygroscopic
Hazard Class8
Packing GroupIII
ToxicityLD50 orally in Rabbit: 1638 mg/kg LD50 dermal Rat > 2000 mg/kg

Borate(1-),tetrafluoro-,lithium - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
application lithium tetrafluoroborate (LiBF4) has good chemical stability and thermal stability, is sensitive to environmental moisture distribution, and is mainly used as electrolyte lithium salt for lithium ion battery electrolyte.
use mild Lewis acid for Diels-Alder reaction; Ethylene oxide ammonolysis catalyst.
Last Update:2024-04-10 22:29:15
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Borate(1-),tetrafluoro-,lithium
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