Butyldi-1-adamantylphosphine
Butyldi-1-adamantylphosphine
CAS: 321921-71-5
Molecular Formula: C24H39P
Butyldi-1-adamantylphosphine - Names and Identifiers
| Name | Butyldi-1-adamantylphosphine |
| Synonyms | CATACXIUM A cataCXium(R) A Butyldi-1-adamantylphosphine BUTYLDI-1-ADAMANTYLPHOSPHINE nbutyl-di(1-adamantyl)phosphine Diadamantan-1-yl(butyl)phosphine Di(1-adamantyl)-n-butylphosphine Di(adamantan-1-yl)(butyl)phosphine BUTYLDI-1-ADAMANTYLPHOSPHINE [CATACXIUM A] |
| CAS | 321921-71-5 |
| EINECS | 691-708-4 |
| InChI | InChI=1/C24H39P/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24/h17-22H,2-16H2,1H3 |
| InChIKey | HTJWUNNIRKDDIV-UHFFFAOYSA-N |
Butyldi-1-adamantylphosphine - Physico-chemical Properties
| Molecular Formula | C24H39P |
| Molar Mass | 358.54 |
| Melting Point | 100°C |
| Boling Point | 449.6±12.0 °C(Predicted) |
| Flash Point | 239°C |
| Vapor Presure | 7.51E-08mmHg at 25°C |
| Appearance | Crystalline powder |
| Color | white to yellow |
| BRN | 8726448 |
| Storage Condition | Inert atmosphere,Room Temperature |
| Sensitive | air sensitive |
| MDL | MFCD05861606 |
Butyldi-1-adamantylphosphine - Risk and Safety
| Safety Description | 24/25 - Avoid contact with skin and eyes. |
| WGK Germany | 3 |
| HS Code | 29310095 |
Butyldi-1-adamantylphosphine - Reference Information
| Use | n-butyldi (1-adamantyl) phosphine is a catalyst. n-butyl di (1-adamantyl) phosphine is an electron-rich phosphine ligand used in palladium-catalyzed cross-coupling reactions such as Heck and Suzuki coupling reactions. |
| Application | n-butyl di (1-adamantyl) phosphine is a novel phosphine ligand, which can be made of di (1-adamantyl) phosphine and di-n-butyl ether in one step to prepare hi is obtained. Although palladium (0)/nickel (0) compounds are known as present reaction catalysts, palladium and nickel catalysts for activating and refining halogenated aromatic compounds with are palladium (II) and/or nickel (II) and palladium (0) and/or nickel (0) complexes. |
| preparation | 4.6g(15mmol) di (1-adamantyl) phosphine was placed in 50ml di-n-butyl ether and 20ml of 2.5Mn-BuLi(50mmol) toluene solution was added. The solution was refluxed for 1 hour and cooled, and 2.8g(30mmol) of 1-butyl chloride was added dropwise. The mixture was refluxed for 30 minutes, cooled and washed with a saturated ammonium chloride solution (3x), the organic phase was separated and dried on sodium sulfate and the solvent was distilled off under reduced pressure. The product was purified by spherical tube distillation under high vacuum. Yield: 4.6g(13mmol,85%) n-butyl di (1-adamantyl) phosphine. |
Last Update：2024-04-10 22:29:15
Supplier List
Spot supply
Product Name: Butyldi-1-adamantylphosphine Request for quotationCAS: 321921-71-5
Tel: +86-18721521379
Email: 18721521379@163.com
Mobile: +86-18721521379
Wechat: 18721521379
Spot supply
Product Name: Butyldi-1-adamantylphosphine Request for quotationCAS: 321921-71-5
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Wechat: chemical6666
Product Name: Butyldi-1-adamantylphosphine Request for quotation
CAS: 321921-71-5
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
CAS: 321921-71-5
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Spot supply
Product Name: Butyldi-1-adamantylphosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: +16314854226
Email: info@bocsci.com
Mobile: +16314854226
Linkedin: https://www.linkedin.com/company/boc-sciences
Product List: View Catalog
Spot supply
Product Name: Di(1-adaMantyl)-n-butylphosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185
Wechat: chinaskyrun
Spot supply
Product Name: Butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Spot supply
Product Name: Di(1-adamantyl)-n-butylphosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Di(1-adamantyl)-n-butylphosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Spot supply
Product Name: Di(1-adamantyl)-n-butylphosphine Request for quotationCAS: 321921-71-5
Tel: 15001012717
Email: biz5@infsci.com
Mobile: 15001012717
QQ: 3007471201
Product List: View Catalog
Spot supply
Product Name: Butyldi-1-adamantylphosphine Request for quotationCAS: 321921-71-5
Tel: +86-18721521379
Email: 18721521379@163.com
Mobile: +86-18721521379
Wechat: 18721521379
Spot supply
Product Name: Butyldi-1-adamantylphosphine Request for quotationCAS: 321921-71-5
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Wechat: chemical6666
Product Name: Butyldi-1-adamantylphosphine Request for quotation
CAS: 321921-71-5
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
CAS: 321921-71-5
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Spot supply
Product Name: Butyldi-1-adamantylphosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: +16314854226
Email: info@bocsci.com
Mobile: +16314854226
Linkedin: https://www.linkedin.com/company/boc-sciences
Product List: View Catalog
Spot supply
Product Name: Di(1-adaMantyl)-n-butylphosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185
Wechat: chinaskyrun
Spot supply
Product Name: Butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Spot supply
Product Name: Di(1-adamantyl)-n-butylphosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Di(1-adamantyl)-n-butylphosphine Visit Supplier Webpage Request for quotationCAS: 321921-71-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Spot supply
Product Name: Di(1-adamantyl)-n-butylphosphine Request for quotationCAS: 321921-71-5
Tel: 15001012717
Email: biz5@infsci.com
Mobile: 15001012717
QQ: 3007471201
Product List: View Catalog
View History
Butyldi-1-adamantylphosphine
6-EAPB
[(4-methoxy-2-nitrophenyl)thio]acetic acid
AI3-16502
SINIGRIN WITH HPLC
2-METHYLDIPHENYLAMINE
Dimethyl glutarate
波马利多明杂质2
5-Octenoic acid, 8-(2-furanyl)-8-hydroxy-, 1-methylethyl ester, (5Z)-
2-Fluoro-5-Methoxybenzotrifluoride[4-fluoro-3-trifluoroMethylanisole]
6-EAPB
[(4-methoxy-2-nitrophenyl)thio]acetic acid
AI3-16502
SINIGRIN WITH HPLC
2-METHYLDIPHENYLAMINE
Dimethyl glutarate
波马利多明杂质2
5-Octenoic acid, 8-(2-furanyl)-8-hydroxy-, 1-methylethyl ester, (5Z)-
2-Fluoro-5-Methoxybenzotrifluoride[4-fluoro-3-trifluoroMethylanisole]