CHLOROCYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
CAS: 32993-05-8
Molecular Formula: C41H35ClP2Ru
CHLOROCYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) - Names and Identifiers
| Name | Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II) |
| Synonyms | bis(triphenyL RU(CP)(PPH3)2C [ClRu(PPh3)2Cp] Chlorocyclopentadieny phosphine)ruthenium(II) λ2-chloranidylrutheniumbis(ylium) CHLOROCYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Chlorocyclopentadienylbis(Triphenylphosphine)Ruthenium(Ii) Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II) |
| CAS | 32993-05-8 |
| InChI | InChI=1/2C18H15P.C5H5.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h2*1-15H;1-5H;1H;/q;;;;-1/p+1/rC41H37ClP2Ru/c42-45(41-33-19-20-34-41,43(35-21-7-1-8-22-35,36-23-9-2-10-24-36)37-25-11-3-12-26-37)44(38-27-13-4-14-28-38,39-29-15-5-16-30-39)40-31-17-6-18-32-40/h1-34,41,43-44H |
CHLOROCYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) - Physico-chemical Properties
| Molecular Formula | C41H35ClP2Ru |
| Molar Mass | 726.19 |
| Melting Point | 135 °C (dec.) (lit.) |
| Water Solubility | soluble |
| Appearance | crystal |
| Color | orange |
| Storage Condition | Inert atmosphere,Room Temperature |
| Sensitive | Air & Moisture Sensitive |
| MDL | MFCD00075004 |
CHLOROCYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 - Wear suitable gloves and eye/face protection S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S22 - Do not breathe dust. |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
CHLOROCYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) - Introduction
Chloro(cyclopentadienyl)bis (triphenylphosphate) ruthenium(II) is an organometallic compound with the chemical formula [RuCl(cod)(PPh3)2], where cod represents a cyclopentadienyl group. The following is an introduction to some of its properties, uses, methods and safety information:
Nature:
-Appearance: Chlorine (cyclopentadienyl)bis(triphenyl phosphate) ruthenium(II) is an orange crystalline powder.
-Melting point: about 170-172 ° C
-Solubility: Soluble in organic solvents such as dimethyl sulfoxide, chloroform and dichloromethane.
Use:
-Catalyst: Chlorine (cyclopentadienyl)bis (triphenylephine) ruthenium(II) is commonly used as a coordination catalyst and is widely used in organic synthesis reactions, especially hydrogenation, siliconization and carbon-carbon coupling reactions.
-diffusion layer: Chlorine (cyclopentadienyl)bis(triphenyl phosphate) ruthenium(II) can also be used as an electron transport material of organometallic compounds and is widely used in the preparation of solar cell diffusion layers.
Method:
The preparation of chlorine (cyclopentadienyl)bis (triphenylphosphate) ruthenium(II) is usually carried out by the following steps:
1. Ruthenium chloride (II) is reacted with triphenylphosphine in a suitable solvent, usually ethanol. The reaction may be carried out at ambient temperature and continued for a period of time after the addition of triphenylphosphine.
2. A filtering agent is added to the reaction solution to filter out the by-products and the catalyst.
3. The solvent was evaporated from the filtered product to give the pure product of chlorine (cyclopentadienyl)bis(triphenylphosphine)ruthenium(II).
Safety Information:
-chlorine (cyclopentadienyl)bis(triphenyl phosphate) ruthenium(II) is relatively safe for human health under general conditions.
-During use, pay attention to prevent inhalation of aerosols or dust, and avoid contact with skin and eyes.
-Pay attention to follow the laboratory's safe operating procedures during operation, and use appropriate personal protective equipment, such as laboratory gloves and goggles.
Nature:
-Appearance: Chlorine (cyclopentadienyl)bis(triphenyl phosphate) ruthenium(II) is an orange crystalline powder.
-Melting point: about 170-172 ° C
-Solubility: Soluble in organic solvents such as dimethyl sulfoxide, chloroform and dichloromethane.
Use:
-Catalyst: Chlorine (cyclopentadienyl)bis (triphenylephine) ruthenium(II) is commonly used as a coordination catalyst and is widely used in organic synthesis reactions, especially hydrogenation, siliconization and carbon-carbon coupling reactions.
-diffusion layer: Chlorine (cyclopentadienyl)bis(triphenyl phosphate) ruthenium(II) can also be used as an electron transport material of organometallic compounds and is widely used in the preparation of solar cell diffusion layers.
Method:
The preparation of chlorine (cyclopentadienyl)bis (triphenylphosphate) ruthenium(II) is usually carried out by the following steps:
1. Ruthenium chloride (II) is reacted with triphenylphosphine in a suitable solvent, usually ethanol. The reaction may be carried out at ambient temperature and continued for a period of time after the addition of triphenylphosphine.
2. A filtering agent is added to the reaction solution to filter out the by-products and the catalyst.
3. The solvent was evaporated from the filtered product to give the pure product of chlorine (cyclopentadienyl)bis(triphenylphosphine)ruthenium(II).
Safety Information:
-chlorine (cyclopentadienyl)bis(triphenyl phosphate) ruthenium(II) is relatively safe for human health under general conditions.
-During use, pay attention to prevent inhalation of aerosols or dust, and avoid contact with skin and eyes.
-Pay attention to follow the laboratory's safe operating procedures during operation, and use appropriate personal protective equipment, such as laboratory gloves and goggles.
Last Update：2024-04-10 22:29:15
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CAS: 32993-05-8
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