Cyanoferrocene
Cyanoferrocene
CAS: 1273-84-3
Molecular Formula: C6H4N.C5H5.Fe
Cyanoferrocene - Names and Identifiers
| Name | Cyanoferrocene |
| Synonyms | Cyanoferrocene Ferrocenylnitrile Ferrocene, cyano- Ferrocenyl cyanide Cyclopentadienecarbonitrile, cyclopentadienyliron deriv. |
| CAS | 1273-84-3 |
Cyanoferrocene - Physico-chemical Properties
| Molecular Formula | C6H4N.C5H5.Fe |
| Molar Mass | 211.044 |
| Melting Point | 107-108℃ |
| Storage Condition | Room Temprature |
Cyanoferrocene - Introduction
Cyanoferrocene is an organic compound containing a cyano group (CN) and a ferrocene group (CpFe). Its chemical formula is Fe(Cp)(CO)2CN, where Cp represents a cyclopentadienyl group. The following is a description of the nature, use, preparation and safety information of cyanoferrocene:
Nature:
-Cyanoferrocene is a solid, usually purple crystal.
-It has a higher melting point and boiling point, better stability.
-Insoluble in water at room temperature, but soluble in organic solvents such as ether and dimethylformamide.
-Stable in the air, but degraded by heat, light and oxygen.
Use:
-Cyanoferrocene is commonly used as a catalyst in organic synthesis and coordination chemistry.
-It can promote hydrogen addition reaction, carbonylation reaction, reduction reaction and condensation reaction.
-In electrochemistry, cyanoferrocene can be used as an electron transfer medium and an electroactive ligand.
Preparation Method:
-Cyanoferrocene can be formed by linking cyano and ferrocene groups. The commonly used preparation method is cyanidation reaction.
-The specific preparation method comprises reacting ferrocene and cyanoformic acid ketal under alkaline conditions to obtain cyanoferrocene.
Safety Information:
-Cyanoferrocene is a toxic substance, the operation of the need to take strict safety measures.
-Avoid direct contact with skin, eyes and respiratory tract.
-Personal protective equipment such as protective gloves, glasses and respiratory protection should be provided during operation.
-Operate under well-ventilated conditions and properly store and dispose of waste.
Nature:
-Cyanoferrocene is a solid, usually purple crystal.
-It has a higher melting point and boiling point, better stability.
-Insoluble in water at room temperature, but soluble in organic solvents such as ether and dimethylformamide.
-Stable in the air, but degraded by heat, light and oxygen.
Use:
-Cyanoferrocene is commonly used as a catalyst in organic synthesis and coordination chemistry.
-It can promote hydrogen addition reaction, carbonylation reaction, reduction reaction and condensation reaction.
-In electrochemistry, cyanoferrocene can be used as an electron transfer medium and an electroactive ligand.
Preparation Method:
-Cyanoferrocene can be formed by linking cyano and ferrocene groups. The commonly used preparation method is cyanidation reaction.
-The specific preparation method comprises reacting ferrocene and cyanoformic acid ketal under alkaline conditions to obtain cyanoferrocene.
Safety Information:
-Cyanoferrocene is a toxic substance, the operation of the need to take strict safety measures.
-Avoid direct contact with skin, eyes and respiratory tract.
-Personal protective equipment such as protective gloves, glasses and respiratory protection should be provided during operation.
-Operate under well-ventilated conditions and properly store and dispose of waste.
Last Update：2024-04-10 22:29:15
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