Dimethyllithioamine
Lithium dimethylamide
CAS: 3585-33-9
Molecular Formula: C2H6LiN
Dimethyllithioamine - Names and Identifiers
Dimethyllithioamine - Physico-chemical Properties
| Molecular Formula | C2H6LiN |
| Molar Mass | 51.02 |
| Density | 0.68g/mLat 25°C |
| Boling Point | 68-70°C |
| Flash Point | -23°C |
| Water Solubility | Reacts violently with water. |
| Appearance | Slurry |
| Color | White |
| BRN | 3618233 |
| Sensitive | Air & Moisture Sensitive |
Dimethyllithioamine - Risk and Safety
| Risk Codes | R17 - Spontaneously flammable in air R34 - Causes burns R67 - Vapors may cause drowsiness and dizziness R65 - Harmful: May cause lung damage if swallowed R62 - Possible risk of impaired fertility R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R48/20 - R11 - Highly Flammable R36/38 - Irritating to eyes and skin. |
| Safety Description | S9 - Keep container in a well-ventilated place. S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S29 - Do not empty into drains. S33 - Take precautionary measures against static discharges. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. S27 - Take off immediately all contaminated clothing. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S36/37 - Wear suitable protective clothing and gloves. |
| UN IDs | UN 3394 4.2/PG 1 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 1-10 |
| Hazard Class | 4.2 |
| Packing Group | I |
Dimethyllithioamine - Introduction
Lithium dimethylamide(Lithium dimethylamide) is an inorganic compound with the chemical formula LiN(CH3)2. It is a colorless solid that can be dissolved in organic solvents at room temperature, but it will quickly absorb moisture when exposed to air.
Lithium dimethylamide is a strong base with strong reducibility. It can react with water to produce flammable gas methane, and it will emit intense heat. Therefore, strict safety measures need to be taken during handling and storage.
Lithium dimethylamide has a wide range of applications in organic synthesis. It can be used as an alkali promoter, catalyst, and reagent for building organometallic compounds. It can be used for the synthesis of organometallic complexes such as ethyl-based complexes and metal-organic polymers.
The preparation of Lithium dimethylamide is generally obtained by reacting dimethylamine with lithium metal. Depending on the reaction conditions, the corresponding lithium amine hydrides and lithium chloramine salts can also be obtained.
Because Lithium dimethylamide is highly reactive, irritating and corrosive to the skin and eyes, it is necessary to wear protective equipment and avoid contact with the skin during use. At the same time, it is also sensitive to moisture in the air and should be stored in a dry environment, away from fire and oxidants.
Lithium dimethylamide is a strong base with strong reducibility. It can react with water to produce flammable gas methane, and it will emit intense heat. Therefore, strict safety measures need to be taken during handling and storage.
Lithium dimethylamide has a wide range of applications in organic synthesis. It can be used as an alkali promoter, catalyst, and reagent for building organometallic compounds. It can be used for the synthesis of organometallic complexes such as ethyl-based complexes and metal-organic polymers.
The preparation of Lithium dimethylamide is generally obtained by reacting dimethylamine with lithium metal. Depending on the reaction conditions, the corresponding lithium amine hydrides and lithium chloramine salts can also be obtained.
Because Lithium dimethylamide is highly reactive, irritating and corrosive to the skin and eyes, it is necessary to wear protective equipment and avoid contact with the skin during use. At the same time, it is also sensitive to moisture in the air and should be stored in a dry environment, away from fire and oxidants.
Last Update：2024-04-10 22:29:15
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