MU-CHLOROBIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM
tebbe
CAS: 67719-69-1
Molecular Formula: C13H4AlClTi
MU-CHLOROBIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM - Names and Identifiers
| Name | tebbe |
| Synonyms | tebbe TEBBE REAGENT Tebbe reagent Tebbe's reagent Chlorobishetacyclopentadienyldimethylammoniummumethyle MU-CHLOROBIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM BIS(CYCLOPENTADIENYL)-MU-CHLORO(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM MU-CHLOROBIS(ETA5-CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM Bis(cyclopentadienyl-micron-chloro(dimethylaluminum-micron-methylenetitanium μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum solution, 0.5M in toluene |
| CAS | 67719-69-1 |
| InChI | InChI=1/2C5H5.2CH3.CH2.Al.ClH.Ti/c2*1-2-4-5-3-1;;;;;;/h2*1-5H;2*1H3;1H2;;1H;/rC13H19AlClTi/c1-14(2)11-16(15-14,12-7-3-4-8-12)13-9-5-6-10-13/h3-10,12-13,15H,11H2,1-2H3 |
| InChIKey | QEJAQNUJXFLWSP-UHFFFAOYSA-M |
MU-CHLOROBIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM - Physico-chemical Properties
| Molecular Formula | C13H4AlClTi |
| Molar Mass | 270.47 |
| Density | 0.96g/mLat 20°C |
| Flash Point | 34°F |
| Water Solubility | Soluble in toluene, benzene, dichloromethane. Insoluble in water. |
| Appearance | Solution |
| Color | Dark red to purple |
| Exposure Limit | ACGIH: TWA 20 ppmOSHA: Ceiling 300 ppm; TWA 200 ppmNIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) |
| Merck | 9091 |
| Storage Condition | Refrigerator |
| Sensitive | Air & Moisture Sensitive |
MU-CHLOROBIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM - Risk and Safety
| Risk Codes | R11 - Highly Flammable R34 - Causes burns R48/20 - R63 - Possible risk of harm to the unborn child R65 - Harmful: May cause lung damage if swallowed R67 - Vapors may cause drowsiness and dizziness |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. S16 - Keep away from sources of ignition. |
| UN IDs | UN 2924 3/PG 2 |
| WGK Germany | 2 |
| FLUKA BRAND F CODES | 1-10 |
| HS Code | 29310099 |
| Hazard Class | 4.3 |
| Packing Group | II |
MU-CHLOROBIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM - Reference Information
| Use | The Tebbe reagent can be used for the allylation of aldehydes. |
Last Update：2024-04-10 22:29:15
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