Name | Methacrylamide |
Synonyms | Methacrylamide Mhoromer bm801 Methylacrylamide 2-Methylacrylamide Methylacrylic amide methacrylicacidamide 2-methyl-2-propenamid 2-methyl-2-Propenamide 2-Propenamide, 2-methyl- |
CAS | 79-39-0 |
EINECS | 201-202-3 |
InChI | InChI=1/C4H7NO/c1-3(2)4(5)6/h1H2,2H3,(H2,5,6) |
Molecular Formula | C4H7NO |
Molar Mass | 85.1 |
Density | 1,115 g/cm3 |
Melting Point | 106-110 °C (lit.) |
Boling Point | 215 °C |
Flash Point | 215°C |
Water Solubility | 202 g/L (20 ºC) |
Solubility | 202g/l |
Vapor Presure | 0.0015 hPa (20 °C) |
Appearance | Crystals |
Color | White to very slightly yellow |
BRN | 605397 |
pKa | 15.46±0.50(Predicted) |
PH | 7.1 (100g/l, H2O, 20℃) |
Storage Condition | Store below +30°C. |
Sensitive | Easily absorbing moisture |
Explosive Limit | 2-15%(V) |
Refractive Index | 1.3992 (estimate) |
MDL | MFCD00008018 |
Physical and Chemical Properties | White crystals, industrial products are yellowish. |
Use | For the preparation of methyl methacrylate |
Hazard Symbols | Xn - Harmful |
Risk Codes | R22 - Harmful if swallowed R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 - Wear suitable protective clothing and gloves. |
UN IDs | 3263 |
WGK Germany | 1 |
RTECS | UC6475000 |
TSCA | Yes |
HS Code | 2924 19 00 |
Hazard Class | 6.1(b) |
Packing Group | III |
Toxicity | LD50 orally in Rabbit: 1815 mg/kg LD50 dermal Rat > 5000 mg/kg |
NIST chemical information | information provided by: webbook.nist.gov (external link) |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Use | methacrylamide is a weight gain improver after silk degumming and before dyeing and finishing. Because the pigment, fat, wax and other impurities are removed from the raw silk during degumming, there is a weight loss of 20-30% of the degumming amount, it can not only make up for the weight loss of white factory silk caused by degumming, but also can obviously improve the appearance of white factory silk and improve the application effect of silk fabric. Graft polymerization of methacrylamide in elastic exterior wall coatings and raw silk industry. methacrylamide is an intermediate for the production of methyl methacrylate. organic synthesis. Synthesis of polymer compounds. |
production method | sodium cyanide is used as raw material to react with sulfuric acid to prepare hydrocyanic acid, which reacts with acetone to generate acetone cyanohydrin, it is reacted with concentrated sulfuric acid to form methacrylamide sulfate, and then neutralized with ammonia water to obtain finished methacrylamide. Hydrogen cyanide was prepared by the reaction of sodium cyanide with sulfuric acid. Methacrylamide sulfate is prepared from hydrocyanic acid, and the production method is the same as that of methacrylic acid. The obtained methacrylamide sulfate is neutralized with ammonia, extracted, crystallized, filtered and dried at low temperature to obtain a finished product. Production of methacrylamide with sodium cyanide as raw material, consumption of 821kg of sodium cyanide, acetone (≥ 98.5%)883kg, sulfuric acid 3440kg, liquid ammonia 650kg per ton of product. |
autoignition temperature | 510°C |
pure white crystals, industrial products are yellowish, melting point of 110~111. Soluble in ethanol, slightly soluble in ether.
sodium cyanide reacts with sulfuric acid to generate cyanohydric acid, acetone reacts with cyanohydric acid to generate acetone cyanohydrin, is dehydrated under the action of sulfuric acid, and amides to obtain methacrylamide sulfate, and then neutralizes, extracts, crystallizes, filtering, low temperature drying to obtain the finished product.
is an intermediate for the production of methyl methacrylate.