Molecular Formula | C15H13Cl2N3O2 |
Molar Mass | 338.19 |
Density | 1.43±0.1 g/cm3(Predicted) |
Melting Point | 168-168.5° |
Boling Point | 468.9±55.0 °C(Predicted) |
Physical and Chemical Properties | The pure chemical product is a solid with a strong smell of rust color. M. p.168 ~ 168.5 ℃, relative density 1.4 (20 ℃), vapor pressure 1 × 10-9Pa (25 ℃), solubility in water 12mg/L (pH = 7). The distribution coefficient is 2.7, stable to hydrolysis, and the half-life of light in water is about 12d. |
Use | Uses triazolinone herbicides, protoporphyrinogen oxidase inhibitors. Suitable for Olive, citrus, forest and non-crop and weed-growing sites. Control of many important weeds, such as broad-leaved weeds purslane, Portulaca oleracea, Chenopodium, mustard, senecio, Solanum nigrum, etc.; Gramineae weeds such as green grass, Maldon, Poa pratensis, Humulus, etc. It has special effects on weeds producing antibodies such as triazobenzene, aryloxycarboxylic acid lamps, cyclohexanediones and ALS inhibitors such as sulfonylurea herbicides. Application before the emergence of weeds, the dose of 240g active ingredient/hm2. |
Risk Codes | R61 - May cause harm to the unborn child R48/22 - Harmful danger of serious damage to health by prolonged exposure if swallowed. R62 - Possible risk of impaired fertility R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
Safety Description | S53 - Avoid exposure - obtain special instructions before use. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
acidity coefficient (pKa) | 2.45±0.20(Predicted) |
EPA chemical information | Azafeniden (68049-83-2) |
Toxicity
acute oral LD50>5000mg/kg in rats, acute percutaneous LD50>2000mg/kg in rabbits, and acute inhalation of LC50 in rats was 5.3mg/L. No irritation to rabbit eyes and skin. Ames test negative, no mutagenicity. The LC50 was 48mg/L (96h) for the big sunfish, 33mg/L (96h) for the rainbow trout and 38mg/L (48h) for the Daphnia.
production method
2, 4-dichlorophenol is made by etherification, nitration, and reduction to obtain the corresponding intermediate, and then diazotization and reduction to obtain the corresponding substituted phenylhydrazine; cyanoprene carbamate reacts with acetic anhydride to obtain the corresponding intermediate. The two intermediate products react and then heat the ring to prepare zolidinone.
Toxicity
LD50 in rats, mice, bobwhite quail, mallard duck (mg/kg): >5000, >5000, >2500, >2500 orally; in rabbits (mg/kg): >2000 dermally.; LC50 in rats, rainbow trout, blue gill sunfish (mg/l): >5.3, 33, 48 (Amuti)